{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,14]],"date-time":"2026-05-14T17:12:38Z","timestamp":1778778758803,"version":"3.51.4"},"reference-count":66,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2022,12,27]],"date-time":"2022-12-27T00:00:00Z","timestamp":1672099200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"National Natural Science Foundation of China","award":["31901276"],"award-info":[{"award-number":["31901276"]}]},{"name":"National Natural Science Foundation of China","award":["212101510005"],"award-info":[{"award-number":["212101510005"]}]},{"name":"Central Plain Scholar Funding Project of Henan Province","award":["31901276"],"award-info":[{"award-number":["31901276"]}]},{"name":"Central Plain Scholar Funding Project of Henan Province","award":["212101510005"],"award-info":[{"award-number":["212101510005"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>Biomass energy has attracted widespread attention due to its renewable, storage, huge production and clean and pollution-free advantages. Using Robinia pseudoacacia bark (RPB) as raw material, biogas and bio-oil produced by pyrolysis of RPB were detected and analyzed by TG-DTG, TG-FTIR and PY-GC-MS under the action of nanocatalysis. TG results showed that CH4 and CO flammable gases were produced by pyrolysis. PY-GC-MS results showed that RPB was rapidly pyrolyzed to obtain alcohols, ketones, aldehydes and acids bio-oil. The content of phenolic substances was the highest, accounting for 32.18% of all substances.Nanocatalysis has a certain effect on RPB, accelerating the precipitation of pyrolysis products and improving the over-oxidation of bio-oil. In addition, the extracts of RPB were identified and analyzed by FTIR, NMR, GC-MS and LC-Q-TOF-MS, and more than 100 active ingredients, such as Betaine, Epicathin and \u03b2-sitosterol, were detected. Their applications as additive energy in other fields were explored. Therefore, Robinia pseudoacacia bark constitutes a fine biofeedstock for biofuels and biochemicals.<\/jats:p>","DOI":"10.3390\/polym15010114","type":"journal-article","created":{"date-parts":[[2022,12,28]],"date-time":"2022-12-28T05:28:24Z","timestamp":1672205304000},"page":"114","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Nano Ag\/Co3O4 Catalyzed Rapid Decomposition of Robinia pseudoacacia Bark for Production Biofuels and Biochemicals"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0438-2918","authenticated-orcid":false,"given":"Xiaochen","family":"Yue","sequence":"first","affiliation":[{"name":"Henan Province Engineering Research Center for Forest Biomass Value-Added Products, School of Forestry, Henan Agricultural University, Zhengzhou 450002, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Xiangmeng","family":"Chen","sequence":"additional","affiliation":[{"name":"Henan Province Engineering Research Center for Forest Biomass Value-Added Products, School of Forestry, Henan Agricultural University, Zhengzhou 450002, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Hanyin","family":"Li","sequence":"additional","affiliation":[{"name":"Henan Province Engineering Research Center for Forest Biomass Value-Added Products, School of Forestry, Henan Agricultural University, Zhengzhou 450002, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6666-8423","authenticated-orcid":false,"given":"Shengbo","family":"Ge","sequence":"additional","affiliation":[{"name":"Jiangsu Co-Innovation Center of Efficient Processing and Utilization of Forest Resources, International Innovation Center for Forest Chemicals and Materials, College of Materials Science and Engineering, Nanjing Forestry University, Nanjing 210037, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Yafeng","family":"Yang","sequence":"additional","affiliation":[{"name":"Henan Province Engineering Research Center for Forest Biomass Value-Added Products, School of Forestry, Henan Agricultural University, Zhengzhou 450002, China"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Wanxi","family":"Peng","sequence":"additional","affiliation":[{"name":"Henan Province Engineering Research Center for Forest Biomass Value-Added Products, School of Forestry, Henan Agricultural University, Zhengzhou 450002, China"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2022,12,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2411","DOI":"10.1021\/cr050989d","article-title":"Chemical routes for the transformation of biomass into chemicals","volume":"107","author":"Corma","year":"2007","journal-title":"Chem. 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