{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,3]],"date-time":"2025-11-03T09:23:45Z","timestamp":1762161825990,"version":"build-2065373602"},"reference-count":60,"publisher":"MDPI AG","issue":"8","license":[{"start":{"date-parts":[[2023,4,21]],"date-time":"2023-04-21T00:00:00Z","timestamp":1682035200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>The radical statistical copolymerization of N\u2013vinyl pyrrolidone (NVP) and 2\u2013chloroethyl vinyl ether (CEVE) was conducted using the Reversible Addition\u2013Fragmentation chain Transfer (RAFT) polymerization technique, employing [(O\u2013ethylxanthyl)methyl]benzene (CTA-1) and O\u2013ethyl S\u2013(phthalimidylmethyl) xanthate (CTA-2) as the Chain Transfer Agents (CTAs), leading to P(NVP\u2013stat\u2013CEVE) products. After optimizing copolymerization conditions, monomer reactivity ratios were estimated using various linear graphical methods, as well as the COPOINT program, which was applied in the framework of the terminal model. Structural parameters of the copolymers were obtained by calculating the dyad sequence fractions and the monomers\u2019 mean sequence lengths. Thermal properties of the copolymers were studied by Differential Scanning Calorimetry (DSC) and kinetics of their thermal degradation by Thermogravimetric Analysis (TGA) and Differential Thermogravimetry (DTG), applying the isoconversional methodologies of Ozawa\u2013Flynn\u2013Wall (OFW) and Kissinger\u2013Akahira\u2013Sunose (KAS).<\/jats:p>","DOI":"10.3390\/polym15081970","type":"journal-article","created":{"date-parts":[[2023,4,21]],"date-time":"2023-04-21T10:11:25Z","timestamp":1682071885000},"page":"1970","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Statistical Copolymers of N\u2013Vinylpyrrolidone and 2\u2013Chloroethyl Vinyl Ether via Radical RAFT Polymerization: Monomer Reactivity Ratios, Thermal Properties, and Kinetics of Thermal Decomposition of the Statistical Copolymers"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-3959-5832","authenticated-orcid":false,"given":"Nikolaos V.","family":"Plachouras","sequence":"first","affiliation":[{"name":"Industrial Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis Zografou, 15771 Athens, Greece"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Marinos","family":"Pitsikalis","sequence":"additional","affiliation":[{"name":"Industrial Chemistry Laboratory, Department of Chemistry, National and Kapodistrian University of Athens, Panepistimiopolis Zografou, 15771 Athens, Greece"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2023,4,21]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"923","DOI":"10.1080\/03602559.2014.979506","article-title":"Poly(vinylpyrrolidone)\u2014A Versatile Polymer for Biomedical and beyond Medical Applications","volume":"549","author":"Teodorescu","year":"2015","journal-title":"Polym. 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