{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,24]],"date-time":"2026-08-24T09:21:18Z","timestamp":1787563278813,"version":"build-2736575974"},"reference-count":76,"publisher":"MDPI AG","issue":"11","license":[{"start":{"date-parts":[[2023,5,29]],"date-time":"2023-05-29T00:00:00Z","timestamp":1685318400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100008871","name":"Department of Science and Technology of Yunnan Province","doi-asserted-by":"publisher","award":["202002AB080002"],"award-info":[{"award-number":["202002AB080002"]}],"id":[{"id":"10.13039\/501100008871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100008871","name":"Department of Science and Technology of Yunnan Province","doi-asserted-by":"publisher","award":["LGG19E030007"],"award-info":[{"award-number":["LGG19E030007"]}],"id":[{"id":"10.13039\/501100008871","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Department of Science and Technology of Zhejiang Province","award":["202002AB080002"],"award-info":[{"award-number":["202002AB080002"]}]},{"name":"Department of Science and Technology of Zhejiang Province","award":["LGG19E030007"],"award-info":[{"award-number":["LGG19E030007"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>In this work, a durable superhydrophobic fabric was fabricated by using a facile UV-induced surface covalent modification strategy. 2-isocyanatoethylmethacrylate (IEM) containing isocyanate groups can react with the pre-treated hydroxylated fabric, producing IEM molecules covalently grafted onto the fabric\u2019s surface, and the double bonds of IEM and dodecafluoroheptyl methacrylate (DFMA) underwent a photo-initiated coupling reaction under UV light radiation, resulting in the DFMA molecules further grafting onto the fabric\u2019s surface. The Fourier transform infrared, X-ray photoelectron spectroscopy and scanning electron microscopy results revealed that both IEM and DFMA were covalently grafted onto the fabric\u2019s surface. The formed rough structure and grafted low-surface-energy substance contributed to the excellent superhydrophobicity (water contact angle of ~162\u00b0) of the resultant modified fabric. Notably, such a superhydrophobic fabric can be used for efficient oil\u2013water separation, for example a high separation efficiency of over 98%. More importantly, the modified fabric exhibited excellent durable superhydrophobicity in harsh conditions such as immersion in organic solvents for 72 h, an acidic or alkali solution (pH = 1\u201312) for 48 h, undergoing laundry washing for 3 h, exposure to extreme temperatures (from \u2212196\u00b0 to 120\u00b0), as well as damage such as 100 cycles of tape-peeling and a 100-cycle abrasion test; the water contact angle only slightly decreased from ~162\u00b0 to 155\u00b0. This was attributed to the IEM and DFMA molecules grated onto the fabric through stable covalent interactions, which could be accomplished using the facile strategy, where the alcoholysis of isocyanate and the grafting of DFMA via click coupling chemistry were integrated into one-step. Therefore, this work provides a facile one-step surface modification strategy for preparing durable superhydrophobic fabric, which is promising for efficient oil\u2013water separation.<\/jats:p>","DOI":"10.3390\/polym15112505","type":"journal-article","created":{"date-parts":[[2023,5,30]],"date-time":"2023-05-30T02:04:21Z","timestamp":1685412261000},"page":"2505","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Facile UV-Induced Surface Covalent Modification to Fabricate Durable Superhydrophobic Fabric for Efficient Oil\u2013Water Separation"],"prefix":"10.3390","volume":"15","author":[{"given":"Mengmeng","family":"Zhou","sequence":"first","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaohui","family":"Liu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Fengjiao","family":"Xu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3006-1317","authenticated-orcid":false,"given":"Yongbing","family":"Pei","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3403-2142","authenticated-orcid":false,"given":"Lianbin","family":"Wu","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2382-8850","authenticated-orcid":false,"given":"Long-Cheng","family":"Tang","sequence":"additional","affiliation":[{"name":"Key Laboratory of Organosilicon Chemistry and Material Technology of Ministry of Education, College of Material, Chemistry and Chemical Engineering, Hangzhou Normal University, Hangzhou 311121, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,5,29]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2082","DOI":"10.1126\/science.1084282","article-title":"Long-term ecosystem response to the Exxon Valdez oil spill","volume":"302","author":"Peterson","year":"2003","journal-title":"Science"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"301","DOI":"10.1038\/nature06599","article-title":"Science and technology for water purification in the coming decades","volume":"452","author":"Shannon","year":"2008","journal-title":"Nature"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"10459","DOI":"10.1002\/adma.201601812","article-title":"Advanced Sorbents for Oil-Spill Cleanup: Recent Advances and Future Perspectives","volume":"28","author":"Ge","year":"2016","journal-title":"Adv. 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