{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,10]],"date-time":"2026-04-10T21:41:50Z","timestamp":1775857310162,"version":"3.50.1"},"reference-count":71,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2023,6,12]],"date-time":"2023-06-12T00:00:00Z","timestamp":1686528000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>Renewable energy-based technologies and increasing IoT (Internet of Things) objects population necessarily require proper energy storage devices to exist. In the view of customized and portable devices, Additive Manufacturing (AM) techniques offer the possibility to fabricate 2D to 3D features for functional applications. Among the different AM techniques extensively explored to produce energy storage devices, direct ink writing is one of the most investigated, despite the poor achievable resolution. Herein, we present the development and characterization of an innovative resin which can be employed in a micrometric precision stereolithography (SL) 3D printing process for the fabrication of a supercapacitor (SC). Poly(3,4-ethylenedioxythiophene) (PEDOT), a conductive polymer, was mixed with poly(ethylene glycol) diacrylate (PEGDA), to get a printable and UV curable conductive composite material. The 3D printed electrodes were electrically and electrochemically investigated in an interdigitated device architecture. The electrical conductivity of the resin falls within the range of conductive polymers with 200 mS\/cm and the 0.68 \u00b5Wh\/cm2 printed device energy density falls within the literature range.<\/jats:p>","DOI":"10.3390\/polym15122657","type":"journal-article","created":{"date-parts":[[2023,6,13]],"date-time":"2023-06-13T02:00:45Z","timestamp":1686621645000},"page":"2657","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["3D Printed Supercapacitor Exploiting PEDOT-Based Resin and Polymer Gel Electrolyte"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5585-9398","authenticated-orcid":false,"given":"Valentina","family":"Bertana","sequence":"first","affiliation":[{"name":"Department of Applied Science and Technology (DISAT), Polytechnic of Turin, Corso Duca degli Abruzzi 24, 10129 Torino, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Giorgio","family":"Scordo","sequence":"additional","affiliation":[{"name":"Department of Biotechnology and Biomedicine Nanofabrication, Technical University of Denmark (DTU), \u00d8rsteds Plads, 344, 2800 Kgs. Lyngby, Denmark"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Elena","family":"Camilli","sequence":"additional","affiliation":[{"name":"Department of Applied Science and Technology (DISAT), Polytechnic of Turin, Corso Duca degli Abruzzi 24, 10129 Torino, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Limeng","family":"Ge","sequence":"additional","affiliation":[{"name":"Department of Applied Science and Technology (DISAT), Polytechnic of Turin, Corso Duca degli Abruzzi 24, 10129 Torino, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0031-5531","authenticated-orcid":false,"given":"Pietro","family":"Zaccagnini","sequence":"additional","affiliation":[{"name":"Department of Applied Science and Technology (DISAT), Polytechnic of Turin, Corso Duca degli Abruzzi 24, 10129 Torino, Italy"},{"name":"Center for Sustainable and Future Technologies, Istituto Italiano di Tecnologia (IIT), Via Livorno 60, 10144 Torino, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4100-9661","authenticated-orcid":false,"given":"Andrea","family":"Lamberti","sequence":"additional","affiliation":[{"name":"Department of Applied Science and Technology (DISAT), Polytechnic of Turin, Corso Duca degli Abruzzi 24, 10129 Torino, Italy"},{"name":"Center for Sustainable and Future Technologies, Istituto Italiano di Tecnologia (IIT), Via Livorno 60, 10144 Torino, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4570-2674","authenticated-orcid":false,"given":"Simone Luigi","family":"Marasso","sequence":"additional","affiliation":[{"name":"Department of Applied Science and Technology (DISAT), Polytechnic of Turin, Corso Duca degli Abruzzi 24, 10129 Torino, Italy"},{"name":"CNR IMEM, Parco Area delle Scienze, 37 A, 43124 Parma, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3012-8059","authenticated-orcid":false,"given":"Luciano","family":"Scaltrito","sequence":"additional","affiliation":[{"name":"Department of Applied Science and Technology (DISAT), Polytechnic of Turin, Corso Duca degli Abruzzi 24, 10129 Torino, Italy"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2023,6,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"19304","DOI":"10.1039\/D2TA02381D","article-title":"Low-Temperature Resistant Gel Polymer Electrolytes for Zinc\u2013Air Batteries","volume":"10","author":"Wu","year":"2022","journal-title":"J. Mater. Chem. A Mater."},{"key":"ref_2","first-page":"7","article-title":"Microsupercapacitors as Miniaturized Energy-Storage Components for on-Chip Electronics","volume":"12","author":"Brousse","year":"2016","journal-title":"Nat. Publ. Group"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"2200245","DOI":"10.1002\/solr.202200245","article-title":"High-Voltage Energy Harvesting and Storage System for Internet of Things Indoor Application","volume":"6","author":"Speranza","year":"2022","journal-title":"Sol. RRL"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"3689","DOI":"10.1038\/s41467-022-31383-4","article-title":"Quasi-Solid-State Zn-Air Batteries with an Atomically Dispersed Cobalt Electrocatalyst and Organohydrogel Electrolyte","volume":"13","author":"Wang","year":"2022","journal-title":"Nat. Commun."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"2100228","DOI":"10.1002\/adsu.202100228","article-title":"Boosting Electric Double Layer Capacitance in Laser-Induced Graphene-Based Supercapacitors","volume":"6","author":"Reina","year":"2022","journal-title":"Adv. Sustain. Syst."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"838","DOI":"10.1002\/adma.201503333","article-title":"High-Performance Pseudocapacitive Microsupercapacitors from Laser-Induced Graphene","volume":"28","author":"Li","year":"2016","journal-title":"Adv. Mater."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"15315","DOI":"10.1021\/acsami.1c01339","article-title":"Fe-Based Coordination Polymers as Battery-Type Electrodes in Semi-Solid-State Battery-Supercapacitor Hybrid Devices","volume":"13","author":"Wang","year":"2021","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"1600539","DOI":"10.1002\/advs.201600539","article-title":"Battery-Supercapacitor Hybrid Devices: Recent Progress and Future Prospects","volume":"4","author":"Zuo","year":"2017","journal-title":"Adv. Sci."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"801","DOI":"10.1016\/j.est.2019.01.010","article-title":"Review of Supercapacitors: Materials and Devices","volume":"21","author":"Poonam","year":"2019","journal-title":"J. Energy Storage"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"7975","DOI":"10.1021\/nn403068d","article-title":"Fabrication of a Stretchable Solid-State Micro-Supercapacitor Array","volume":"7","author":"Kim","year":"2013","journal-title":"ACS Nano"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1038\/s41528-020-00093-6","article-title":"Recent Developments of Advanced Micro-Supercapacitors: Design, Fabrication and Applications","volume":"4","author":"Bu","year":"2020","journal-title":"npj Flex. Electron."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"2104909","DOI":"10.1002\/adfm.202104909","article-title":"3D Printed Micro-Electrochemical Energy Storage Devices: From Design to Integration","volume":"31","author":"Zhang","year":"2021","journal-title":"Adv. Funct. Mater."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"1900083","DOI":"10.1002\/admt.201900083","article-title":"Recent Advances in Electrode Fabrication for Flexible Energy-Storage Devices","volume":"4","author":"Wang","year":"2019","journal-title":"Adv. Mater. Technol."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"108797","DOI":"10.1016\/j.matdes.2020.108797","article-title":"Perspective on 3D-Designed Micro-Supercapacitors","volume":"193","author":"Park","year":"2020","journal-title":"Mater. Des."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"424","DOI":"10.1002\/cey2.114","article-title":"3D Printing-Enabled Advanced Electrode Architecture Design","volume":"3","author":"Chu","year":"2021","journal-title":"Carbon Energy"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"101220","DOI":"10.1016\/j.apmt.2021.101220","article-title":"Additively Manufactured Electrodes for Supercapacitors: A Review","volume":"26","author":"Jha","year":"2022","journal-title":"Appl. Mater. Today"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"7399","DOI":"10.1038\/s41598-018-25861-3","article-title":"Three-Dimensional Printed Electrode and Its Novel Applications in Electronic Devices","volume":"8","author":"Foo","year":"2018","journal-title":"Sci. Rep."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"1900691","DOI":"10.1002\/admt.201900691","article-title":"Direct Ink Writing of Wearable Thermoresponsive Supercapacitors with RGO\/CNT Composite Electrodes","volume":"4","author":"Jiang","year":"2019","journal-title":"Adv. Mater. Technol."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"1795","DOI":"10.1038\/s41467-019-09398-1","article-title":"Additive-Free MXene Inks and Direct Printing of Micro-Supercapacitors","volume":"10","author":"Zhang","year":"2019","journal-title":"Nat. Commun."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"640","DOI":"10.1021\/acsnano.9b07325","article-title":"3D Printing of Additive-Free 2D Ti 3 C 2 T x (MXene) Ink for Fabrication of Micro-Supercapacitors with Ultra-High Energy Densities","volume":"14","author":"Orangi","year":"2020","journal-title":"ACS Nano"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"34487","DOI":"10.1021\/acsami.0c07689","article-title":"Inkjet-Printing Technology for Supercapacitor Application: Current State and Perspectives","volume":"12","author":"Rahmanian","year":"2020","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"477","DOI":"10.1016\/j.jmsy.2022.01.002","article-title":"Comprehensive Review on Various Additive Manufacturing Techniques and Its Implementation in Electronic Devices","volume":"62","author":"Divakaran","year":"2022","journal-title":"J. Manuf. Syst."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"427","DOI":"10.1002\/eem2.12175","article-title":"3D Printing of Next-Generation Electrochemical Energy Storage Devices: From Multiscale to Multimaterial","volume":"5","author":"Xu","year":"2022","journal-title":"Energy Environ. Mater."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"2000556","DOI":"10.1002\/adma.202000556","article-title":"Evolution of 3D Printing Methods and Materials for Electrochemical Energy Storage","volume":"32","author":"Egorov","year":"2020","journal-title":"Adv. Mater."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1808","DOI":"10.1021\/acsanm.1c03251","article-title":"Stereolithography-Derived Three-Dimensional Pyrolytic Carbon\/Mn 3 O 4 Nanostructures for Free-Standing Hybrid Supercapacitor Electrodes","volume":"5","author":"Rezaei","year":"2022","journal-title":"ACS Appl. Nano Mater."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"13646","DOI":"10.1039\/D0TA04460A","article-title":"A 3D-Printed Stretchable Structural Supercapacitor with Active Stretchability\/Flexibility and Remarkable Volumetric Capacitance","volume":"8","author":"Chang","year":"2020","journal-title":"J. Mater. Chem. A Mater."},{"key":"ref_27","first-page":"46","article-title":"Stereolithographic 3D Printing-Based Hierarchically Cellular Lattices for High-Performance Quasi-Solid Supercapacitor","volume":"11","author":"Xue","year":"2019","journal-title":"Nanomicro Lett."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"103","DOI":"10.1080\/17452759.2015.1097054","article-title":"3D Printing of Smart Materials: A Review on Recent Progresses in 4D Printing","volume":"10","author":"Khoo","year":"2015","journal-title":"Virtual Phys. Prototyp."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"6490","DOI":"10.1039\/D1CY01104A","article-title":"Design and Fabrication of Integral Carbon Monoliths Combining 3D Printing and Sol\u2013Gel Polymerization: Effects of the Channel Morphology on the CO-PROX Reaction","volume":"11","year":"2021","journal-title":"Catal. Sci. Technol."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"e1802793","DOI":"10.1002\/adma.201802793","article-title":"Engineering 2D Architectures toward High-Performance Micro-Supercapacitors","volume":"31","author":"Da","year":"2019","journal-title":"Adv. Mater."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"12653","DOI":"10.1039\/C7TA00863E","article-title":"Carbon-Based Composite Materials for Supercapacitor Electrodes: A Review","volume":"5","author":"Borenstein","year":"2017","journal-title":"J. Mater. Chem. A Mater."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"126352","DOI":"10.1016\/j.cej.2020.126352","article-title":"0D to 3D Carbon-Based Networks Combined with Pseudocapacitive Electrode Material for High Energy Density Supercapacitor: A Review","volume":"403","author":"Kumar","year":"2021","journal-title":"Chem. Eng. J."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"7406","DOI":"10.1039\/C6TA00683C","article-title":"Flexible-Wire Shaped All-Solid-State Supercapacitors Based on Facile Electropolymerization of Polythiophene with Ultra-High Energy Density","volume":"4","author":"Ambade","year":"2016","journal-title":"J. Mater. Chem. A Mater."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"86","DOI":"10.1016\/j.jpowsour.2017.02.054","article-title":"Polyaniline Supercapacitors","volume":"347","author":"Eftekhari","year":"2017","journal-title":"J. Power Sources"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"1707013","DOI":"10.1002\/adfm.201707013","article-title":"Microporous Polypyrrole-Coated Graphene Foam for High-Performance Multifunctional Sensors and Flexible Supercapacitors","volume":"28","author":"Park","year":"2018","journal-title":"Adv. Funct. Mater."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"2","DOI":"10.1002\/ese3.50","article-title":"Conducting Polymer-Based Flexible Supercapacitor","volume":"3","author":"Shown","year":"2015","journal-title":"Energy Sci. Eng."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"19649","DOI":"10.1039\/D1TA02617H","article-title":"3D-Printed Highly Stretchable Conducting Polymer Electrodes for Flexible Supercapacitors","volume":"9","author":"Yang","year":"2021","journal-title":"J. Mater. Chem. A"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"10437","DOI":"10.1021\/acsami.7b19635","article-title":"Three-Dimensional Printing of Polyaniline\/Reduced Graphene Oxide Composite for High-Performance Planar Supercapacitor","volume":"10","author":"Wang","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.coelec.2020.02.009","article-title":"Additive Manufacturing for Energy Storage: Methods, Designs and Material Selection for Customizable 3D Printed Batteries and Supercapacitors","volume":"20","author":"Gulzar","year":"2020","journal-title":"Curr. Opin. Electrochem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"104973","DOI":"10.1016\/j.microc.2020.104973","article-title":"Greenly Synthesized Silver Nanoparticles for Supercapacitor and Electrochemical Sensing Applications in a 3D Printed Microfluidic Platform","volume":"157","author":"Salve","year":"2020","journal-title":"Microchem. J."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"146","DOI":"10.1016\/j.ensm.2021.04.021","article-title":"3D Printing of Reduced Graphene Oxide Aerogels for Energy Storage Devices: A Paradigm from Materials and Technologies to Applications","volume":"39","author":"Guo","year":"2021","journal-title":"Energy Storage Mater."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"435","DOI":"10.1007\/s10118-020-2373-2","article-title":"PEDOT: Fundamentals and Its Nanocomposites for Energy Storage","volume":"38","author":"Chen","year":"2019","journal-title":"Chin. J. Polym. Sci."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"112109","DOI":"10.1016\/j.optmat.2022.112109","article-title":"Post Treated PEDOT-PSS Films with Excellent Conductivity and Optical Properties as Multifunctional Flexible Electrodes for Possible Optoelectronic and Energy Storage Applications","volume":"125","author":"Khasim","year":"2022","journal-title":"Opt. Mater."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"3882","DOI":"10.1038\/s41467-020-17708-1","article-title":"Energy Storing Bricks for Stationary PEDOT Supercapacitors","volume":"11","author":"Wang","year":"2020","journal-title":"Nat. Commun."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"116442","DOI":"10.1016\/j.carbpol.2020.116442","article-title":"Design and Fabrication of High Performance Supercapacitor with Cellulosic Paper Electrode and Plant-Derived Redox Active Molecules","volume":"244","author":"Chang","year":"2020","journal-title":"Carbohydr. Polym."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1016\/j.aca.2004.08.019","article-title":"Determination of Hydroxyl Radicals in Advanced Oxidation Processes with Dimethyl Sulfoxide Trapping and Liquid Chromatography","volume":"527","author":"Tai","year":"2004","journal-title":"Anal. Chim. Acta"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"9283","DOI":"10.1021\/acsaem.1c01517","article-title":"PEDOT-Based Stackable Paper Electrodes for Metal-Free Supercapacitors","volume":"4","author":"Sappia","year":"2021","journal-title":"ACS Appl. Energy Mater"},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"9313","DOI":"10.1002\/adma.201602541","article-title":"Breathable and Wearable Energy Storage Based on Highly Flexible Paper Electrodes","volume":"28","author":"Dong","year":"2016","journal-title":"Adv. Mater."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"12","DOI":"10.1016\/j.mtcomm.2018.12.017","article-title":"A Novel Highly Electrically Conductive Composite Resin for Stereolithography","volume":"19","author":"Scordo","year":"2019","journal-title":"Mater. Today Commun."},{"key":"ref_50","doi-asserted-by":"crossref","unstructured":"Bertana, V., De Pasquale, G., Ferrero, S., Scaltrito, L., Catania, F., Nicosia, C., Marasso, S.L., Cocuzza, M., and Perrucci, F. (2019). 3D Printing with the Commercial UV-Curable Standard Blend Resin: Optimized Process Parameters towards the Fabrication of Tiny Functional Parts. Polymers, 11.","DOI":"10.3390\/polym11020292"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"13335","DOI":"10.1038\/s41598-020-70365-8","article-title":"Rapid Prototyping of 3D Organic Electrochemical Transistors by Composite Photocurable Resin","volume":"10","author":"Bertana","year":"2020","journal-title":"Sci. Rep."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"2208034","DOI":"10.1002\/adfm.202208034","article-title":"3D Printed Supercapacitor: Techniques, Materials, Designs, and Applications","volume":"33","author":"Li","year":"2022","journal-title":"Adv. Funct. Mater."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"1800408","DOI":"10.1002\/aenm.201800408","article-title":"3D Printing Quasi-Solid-State Asymmetric Micro-Supercapacitors with Ultrahigh Areal Energy Density","volume":"8","author":"Shen","year":"2018","journal-title":"Adv. Energy Mater."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"16281","DOI":"10.1039\/C7TA02041D","article-title":"Printing Assembly and Structural Regulation of Graphene towards Three-Dimensional Flexible Micro-Supercapacitors","volume":"5","author":"Li","year":"2017","journal-title":"J. Mater. Chem. A"},{"key":"ref_55","doi-asserted-by":"crossref","unstructured":"Scordo, G., Bertana, V., Ballesio, A., Carcione, R., Marasso, S.L., Cocuzza, M., Pirri, C.F., Manachino, M., Gomez, M.G., and Vitale, A. (2021). Effect of Volatile Organic Compounds Adsorption on 3D-Printed Pegda:Pedot for Long-Term Monitoring Devices. Nanomaterials, 11.","DOI":"10.3390\/nano11010094"},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"11629","DOI":"10.1021\/acsami.6b00317","article-title":"PEDOT:PSS Films with Metallic Conductivity through a Treatment with Common Organic Solutions of Organic Salts and Their Application as a Transparent Electrode of Polymer Solar Cells","volume":"8","author":"Yu","year":"2016","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"3462","DOI":"10.1021\/acs.chemmater.6b01035","article-title":"Structure and Dopant Engineering in PEDOT Thin Films: Practical Tools for a Dramatic Conductivity Enhancement","volume":"28","author":"Gueye","year":"2016","journal-title":"Chem. Mater."},{"key":"ref_58","unstructured":"Kiebooms, R., Menon, R., and Lee, K. (2001). Handbook of Advanced Electronic and Photonic Materials and Devices, Academic Press."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"462","DOI":"10.37624\/IJERT\/13.3.2020.462-469","article-title":"3D Printed Active Objects Based on the Promising PEDOT: PSS Resin: Investigation of Their Integration inside an Electronic Circuit","volume":"13","author":"Bertana","year":"2020","journal-title":"Int. J. Eng. Res. Technol."},{"key":"ref_60","doi-asserted-by":"crossref","unstructured":"Conway, B.E. (1999). Electrochemical Supercapacitors, Springer US.","DOI":"10.1007\/978-1-4757-3058-6"},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"949","DOI":"10.1109\/JMEMS.2017.2723018","article-title":"A Review of On-Chip Micro Supercapacitors for Integrated Self-Powering Systems","volume":"26","author":"Shen","year":"2017","journal-title":"J. Microelectromechanical Syst."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"20","DOI":"10.1016\/j.elecom.2014.01.013","article-title":"Three Dimensional (3D) Printed Electrodes for Interdigitated Supercapacitors","volume":"41","author":"Zhao","year":"2014","journal-title":"Electrochem. Commun."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"240","DOI":"10.1016\/j.jpowsour.2012.10.020","article-title":"Micro-Supercapacitors from Carbide Derived Carbon (CDC) Films on Silicon Chips","volume":"225","author":"Huang","year":"2013","journal-title":"J. Power Sources"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"15864","DOI":"10.1021\/acsami.8b02660","article-title":"Flexible Array of Microsupercapacitor for Additive Energy Storage Performance Over a Large Area","volume":"10","author":"Boruah","year":"2018","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"4597","DOI":"10.1021\/acsami.6b13904","article-title":"3D Printing of Carbon Nanotubes-Based Microsupercapacitors","volume":"9","author":"Yu","year":"2017","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"16016","DOI":"10.1021\/acsami.6b03504","article-title":"Encapsulated, High-Performance, Stretchable Array of Stacked Planar Micro-Supercapacitors as Waterproof Wearable Energy Storage Devices","volume":"8","author":"Kim","year":"2016","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"163901","DOI":"10.1063\/1.4704187","article-title":"Silicon Carbide Coated Silicon Nanowires as Robust Electrode Material for Aqueous Micro-Supercapacitor","volume":"100","author":"Alper","year":"2012","journal-title":"Appl. Phys. Lett."},{"key":"ref_68","doi-asserted-by":"crossref","unstructured":"Luo, G., Teh, K.S., Zang, X., Wu, D., Wen, Z., and Lin, L. (2016, January 24\u201328). High Aspect-Ratio 3D Microstructures via near-Field Electrospinning for Energy Storage Applications. Proceedings of the 2016 IEEE 29th International Conference on Micro Electro Mechanical Systems (MEMS), Shanghai, China.","DOI":"10.1109\/MEMSYS.2016.7421549"},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"4111","DOI":"10.1002\/adfm.201203771","article-title":"Superior Micro-Supercapacitors Based on Graphene Quantum Dots","volume":"23","author":"Liu","year":"2013","journal-title":"Adv. Funct. Mater."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"10897","DOI":"10.1021\/acs.langmuir.8b02404","article-title":"Hierarchically Designed Electron Paths in 3D Printed Energy Storage Devices","volume":"34","author":"Park","year":"2018","journal-title":"Langmuir"},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"112104","DOI":"10.1063\/1.3638468","article-title":"Graphitization of N-Type Polycrystalline Silicon Carbide for on-Chip Supercapacitor Application","volume":"99","author":"Liu","year":"2011","journal-title":"Appl. Phys. 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