{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,16]],"date-time":"2026-09-16T01:35:51Z","timestamp":1789522551237,"version":"build-2803163510"},"reference-count":33,"publisher":"MDPI AG","issue":"14","license":[{"start":{"date-parts":[[2023,7,21]],"date-time":"2023-07-21T00:00:00Z","timestamp":1689897600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Changzhou Sci &amp; Tech Program","award":["CJ20220246"],"award-info":[{"award-number":["CJ20220246"]}]},{"name":"Changzhou Sci &amp; Tech Program","award":["E339kf0401"],"award-info":[{"award-number":["E339kf0401"]}]},{"name":"Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development","award":["CJ20220246"],"award-info":[{"award-number":["CJ20220246"]}]},{"name":"Guangdong Provincial Key Laboratory of New and Renewable Energy Research and Development","award":["E339kf0401"],"award-info":[{"award-number":["E339kf0401"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>It is important to clarify the distribution of pyrolysis products from lignocellulosic biomass for its thermal transformation to produce high-quality bio-oil. Influences of the reaction temperature and catalysts on the pyrolysis product distribution from aspen wood (AW) and rice husk (RH) were studied by pyrolysis-gas chromatography\/mass spectrometry (Py-GC\/MS). The difference in components from the lignocellulosic biomass results in different pyrolysis characteristics of the biomass raw materials. The reaction temperature significantly influences the product distribution from AW and RH pyrolysis. In all AW catalysis experiments, acids (8.35%), ketones (3.79%), phenols (4.73%), and esters (1.50%) have the lowest content while carbohydrates (48.75%) demonstrate the highest content when taking zinc chloride (ZnCl2) as the catalyst; the HZSM-5 molecular sieve (HZSM-5) promotes the generation of esters (7.97%) and N-compounds (22.43%) while inhibiting production of aldehydes (2.41%); addition of an MCM-41 molecular sieve (MCM-41) is conducive to increasing the contents of aldehydes (21.29%), furans (5.88%), ketones (22.30%), acids (20.46%), and hydrocarbons (4.85%), while reducing the contents of alcohols (0) and carbohydrates (0). In all RH catalysis experiments, the addition of ZnCl2 helps increase the content of carbohydrates (39.16%) and decrease the contents of ketones (3.89%), phenols (5.20%), alcohols (2.34%), esters (1.13%), and N-compounds (3.09%); when applying HZSM-5 as the catalyst, hydrocarbons (18.28%) and alcohols (6.66%) reach their highest content while acids (13.21%) have the lowest content; MCM-41 promotes the generation of aldehydes (25.33%) and furans (5.55%) while inhibiting that of carbohydrates (1.42%).<\/jats:p>","DOI":"10.3390\/polym15143104","type":"journal-article","created":{"date-parts":[[2023,7,21]],"date-time":"2023-07-21T01:58:38Z","timestamp":1689904718000},"page":"3104","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Influences of the Reaction Temperature and Catalysts on the Pyrolysis Product Distribution of Lignocellulosic Biomass (Aspen Wood and Rice Husk)"],"prefix":"10.3390","volume":"15","author":[{"given":"Tanglei","family":"Sun","sequence":"first","affiliation":[{"name":"Institute of Urban & Rural Mining, Changzhou University, Changzhou 213164, China"},{"name":"Changzhou Key Laboratory of Biomass Green, Safe & High Value Utilization Technology, Changzhou 213164, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zhuo","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Management and Economics, North China University of Water Resources and Electric Power, Zhengzhou 450046, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ruisi","family":"Wang","sequence":"additional","affiliation":[{"name":"Institute of Urban & Rural Mining, Changzhou University, Changzhou 213164, China"},{"name":"Changzhou Key Laboratory of Biomass Green, Safe & High Value Utilization Technology, Changzhou 213164, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yantao","family":"Yang","sequence":"additional","affiliation":[{"name":"Institute of Urban & Rural Mining, Changzhou University, Changzhou 213164, China"},{"name":"Changzhou Key Laboratory of Biomass Green, Safe & High Value Utilization Technology, Changzhou 213164, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Lu","family":"Zhang","sequence":"additional","affiliation":[{"name":"Institute of Urban & Rural Mining, Changzhou University, Changzhou 213164, China"},{"name":"Changzhou Key Laboratory of Biomass Green, Safe & High Value Utilization Technology, Changzhou 213164, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yanling","family":"Li","sequence":"additional","affiliation":[{"name":"Institute of Urban & Rural Mining, Changzhou University, Changzhou 213164, China"},{"name":"Changzhou Key Laboratory of Biomass Green, Safe & High Value Utilization Technology, Changzhou 213164, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Peng","family":"Liu","sequence":"additional","affiliation":[{"name":"Institute of Urban & Rural Mining, Changzhou University, Changzhou 213164, China"},{"name":"Changzhou Key Laboratory of Biomass Green, Safe & High Value Utilization Technology, Changzhou 213164, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Tingzhou","family":"Lei","sequence":"additional","affiliation":[{"name":"Institute of Urban & Rural Mining, Changzhou University, Changzhou 213164, China"},{"name":"Changzhou Key Laboratory of Biomass Green, Safe & High Value Utilization Technology, Changzhou 213164, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,7,21]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"122234","DOI":"10.1016\/j.energy.2021.122234","article-title":"Thermochemical Behaviors, Kinetics and Bio-Oils Investigation During Co-Pyrolysis of Biomass Components and Polyethylene Based on Simplex-Lattice Mixture Design","volume":"239","author":"Fan","year":"2022","journal-title":"Energy"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"135200","DOI":"10.1016\/j.cej.2022.135200","article-title":"A Sustainable Strategy for the Production of 1,4:3,6-Dianhydro-A-D-Glucopyranose through Oxalic Acid-Assisted Fast Pyrolysis of Cellulose","volume":"436","author":"Hu","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"83","DOI":"10.1016\/j.apenergy.2017.01.071","article-title":"Life Cycle Environmental Impacts of Cornstalk Briquette Fuel in China","volume":"192","author":"Wang","year":"2017","journal-title":"Appl. Energy"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"116012","DOI":"10.1016\/j.indcrop.2022.116012","article-title":"Effects of Reaction Temperature and Molecular Sieve Catalyst on the Distribution of Pyrolysis Products of Biomass Components","volume":"191","author":"Sun","year":"2023","journal-title":"Ind. Crops Prod."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"100899","DOI":"10.1016\/j.pecs.2020.100899","article-title":"Co-Pyrolysis of Waste Plastic and Solid Biomass for Synergistic Production of Biofuels and Chemicals-a Review","volume":"84","author":"Wang","year":"2021","journal-title":"Prog. Energy Combust. Sci."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"122739","DOI":"10.1016\/j.biortech.2020.122739","article-title":"Fast Corn Stalk Pyrolysis and the Influence of Catalysts on Product Distribution","volume":"301","author":"Sun","year":"2020","journal-title":"Bioresour. Technol."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"125292","DOI":"10.1016\/j.fuel.2022.125292","article-title":"Optimized Catalytic Pyrolysis of Refinery Waste Sludge to Yield Clean High Quality Oil Products","volume":"328","author":"Kamali","year":"2022","journal-title":"Fuel"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"107775","DOI":"10.1016\/j.fuproc.2023.107775","article-title":"Biomass Catalytic Pyrolysis over CaO Microspheres: Relationship Between the Production of Bio-oil Components and CO2 Capture","volume":"247","author":"Zhang","year":"2023","journal-title":"Fuel Process. Technol."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"104728","DOI":"10.1016\/j.jaap.2019.104728","article-title":"Influence of Lonic Liquid Type on Porous Carbon Formation During the Ionothermal Pyrolysis of Cellulose","volume":"145","author":"Huang","year":"2020","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"124699","DOI":"10.1016\/j.fuel.2022.124699","article-title":"Insight into the Synergistic Reaction Mechanism of Biomass Pseudo Components and Low-Density Polyethylene for the Production of Light Aromatics through Co-Catalytic Fast Pyrolysis over Hierarchical HZSM-5","volume":"324","author":"Huang","year":"2022","journal-title":"Fuel"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"115501","DOI":"10.1016\/j.indcrop.2022.115501","article-title":"Non-Isothermal Pyrolysis of Xylan, Cellulose and Lignin: A Hybrid Simulated Annealing Algorithm and Pattern Search Method to Regulate Distributed Activation Energies","volume":"187","author":"Zou","year":"2022","journal-title":"Ind. Crops Prod."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"107360","DOI":"10.1016\/j.fuproc.2022.107360","article-title":"Influence of Interaction between Biomass Inorganic Components and Volatiles on Corncob Pyrolysis and Char Structure","volume":"235","author":"Chen","year":"2022","journal-title":"Fuel Process. Technol."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"178","DOI":"10.1016\/j.jaap.2018.10.007","article-title":"Production of Aromatic Hydrocarbons by Catalytic Co-Pyrolysis of Microalgae and Polypropylene Using HZSM-5","volume":"136","author":"Qi","year":"2018","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_14","first-page":"47","article-title":"Study of Thermal Transformations of Cellulose under Curie-point Pyrolysis-GC-MS Conditions","volume":"29","author":"Liu","year":"2009","journal-title":"Chem. Ind. For. Prod."},{"key":"ref_15","first-page":"5","article-title":"Study on Curie-point Pyrolysis of Xylan under CP-GC-MS Conditions","volume":"30","author":"Liu","year":"2010","journal-title":"Chem. Ind. For. Prod."},{"key":"ref_16","first-page":"1","article-title":"Study on Thermal Transformations of Lignin under Curie-point Pyrolysis-GC-MS Conditions","volume":"29","author":"Liu","year":"2009","journal-title":"Chem. Ind. For. Prod."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/j.jaap.2018.02.004","article-title":"Catalytic Fast Pyrolysis of Cellulose for Increasing Contents of Furans and Aromatics in Biofuel Production","volume":"131","author":"Wang","year":"2018","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"107323","DOI":"10.1016\/j.fuproc.2022.107323","article-title":"Catalytic Pyrolysis of Cellulose with Sulfonated Carbon Catalyst to Produce Levoglucosenone","volume":"234","author":"Yang","year":"2022","journal-title":"Fuel Process. Technol."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"105663","DOI":"10.1016\/j.jaap.2022.105663","article-title":"Municipal Sludge Derived Solid Acids for Levoglucosenone Production via Cellulose Fast Pyrolysis","volume":"167","author":"Yuan","year":"2022","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"119038","DOI":"10.1016\/j.fuel.2020.119038","article-title":"Catalytic Pyrolysis of Microcrystalline Cellulose Extracted from Rice Straw for High Yield of Hydrocarbon over Alkali Modified Zsm-5","volume":"285","author":"Nishu","year":"2021","journal-title":"Fuel"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"123805","DOI":"10.1016\/j.biortech.2020.123805","article-title":"Calcium Formate Assisted Catalytic Pyrolysis of Pine for Enhanced Production of Monocyclic Aromatic Hydrocarbons over Bimetal-Modified HZSM-5","volume":"315","author":"Li","year":"2020","journal-title":"Bioresour. Technol."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"966","DOI":"10.1016\/j.enconman.2017.04.033","article-title":"Catalytic Co-Pyrolysis of Torrefied Yellow Poplar and High-Density Polyethylene Using Microporous HZSM-5 and Mesoporous Al-MCM-41 Catalysts","volume":"149","author":"Kim","year":"2017","journal-title":"Energy Convers. Manag."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1016\/j.fuel.2019.04.006","article-title":"Effects of KCl and CaCl2 on the Evolution of Anhydro Sugars in Reaction Intermediates During Cellulose Fast Pyrolysis","volume":"251","author":"Leng","year":"2019","journal-title":"Fuel"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"273","DOI":"10.1016\/j.jaap.2011.03.002","article-title":"Selective Fast Pyrolysis of Biomass Impregnated with ZnCl2: Furfural Production Together with Acetic Acid and Activated Carbon as by-Products","volume":"91","author":"Lu","year":"2011","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"113843","DOI":"10.1016\/j.indcrop.2021.113843","article-title":"Catalytic Co-Pyrolysis of Corn Stalk and Polypropylene over Zn-Al Modified MCM-41 Catalysts for Aromatic Hydrocarbon-Rich Oil Production","volume":"171","author":"Sun","year":"2021","journal-title":"Ind. Crops Prod."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"96","DOI":"10.1016\/j.jaap.2019.01.014","article-title":"Study on Catalytic Pyrolysis of Eucalyptus to Produce Aromatic Hydrocarbons by Zn-Fe Co-Modified HZSM-5 Catalysts","volume":"139","author":"Xu","year":"2019","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1016\/j.jaap.2008.09.016","article-title":"Screening Heterogeneous Catalysts for the Pyrolysis of Lignin","volume":"85","author":"Jackson","year":"2009","journal-title":"J. Anal. Appl. Pyrolysis"},{"key":"ref_28","unstructured":"(2012). Proximate Analysis of Solid Biofuels (Standard No. GB\/T 28731-2012)."},{"key":"ref_29","unstructured":"(2012). Determination Method of Carbon and Hydrogen in Solid Biofuels (Standard No. GB\/T28734-2012)."},{"key":"ref_30","unstructured":"(2014). Determination Method of Nitrogen in Solid Biofuels (Standard No. GB\/T30728-2014)."},{"key":"ref_31","unstructured":"(2012). Determination Method of Sulfur in Solid Biofuels (Standard No. GB\/T28732-2012)."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"125279","DOI":"10.1016\/j.fuel.2022.125279","article-title":"The Mechanism for Catalytic Fast Pyrolysis of Levoglucosan, Furfural and Furan over HZSM-5: An Experimental and Theoretical Investigation","volume":"328","author":"Osatiashtiani","year":"2022","journal-title":"Fuel"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"115474","DOI":"10.1016\/j.indcrop.2022.115474","article-title":"Synergistic Enhancement of Bio-Oil Quality through Hydrochloric or Acetic Acid-Washing Pretreatment and Catalytic Fast Pyrolysis of Biomass","volume":"187","author":"Li","year":"2022","journal-title":"Ind. Crops Prod."}],"container-title":["Polymers"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-4360\/15\/14\/3104\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T20:16:10Z","timestamp":1760127370000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-4360\/15\/14\/3104"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,7,21]]},"references-count":33,"journal-issue":{"issue":"14","published-online":{"date-parts":[[2023,7]]}},"alternative-id":["polym15143104"],"URL":"https:\/\/doi.org\/10.3390\/polym15143104","relation":{},"ISSN":["2073-4360"],"issn-type":[{"value":"2073-4360","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,7,21]]}}}