{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,28]],"date-time":"2025-10-28T15:17:44Z","timestamp":1761664664215,"version":"build-2065373602"},"reference-count":42,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2024,2,21]],"date-time":"2024-02-21T00:00:00Z","timestamp":1708473600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100012190","name":"State Task of the FRC CP RAS","doi-asserted-by":"publisher","award":["122040400099-5"],"award-info":[{"award-number":["122040400099-5"]}],"id":[{"id":"10.13039\/501100012190","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>The pull-out method was used to study the adhesive strength \u03c4 of \u201cfiber\u2013thermoset\u201d systems with wide variations in area. Studied binders were based on resins that had different chemical natures (epoxy, epoxy phenol, orthophthalic, polyphenylsiloxane, and phenol\u2013formaldehyde). Shear adhesive strength was determined for systems with two fiber types (glass and steel fibers). It was shown that strength \u03c4 depended on scale (area). Formation of \u03c4 occurred during the curing process and the system\u2019s subsequent cooling to the measurement temperature T. It was found that interface strength depended on measurement temperature across a wide temperature range that covered the highly elastic and the glassy state of the adhesive. The influence of residual stresses \u03c4res, acting at the \u201cbinder\u2013fiber\u201d interface, on the nature of the curves describing the dependence of the adhesive strength on the studied factor was experimentally shown. A qualitative explanation of the observed regularities is proposed.<\/jats:p>","DOI":"10.3390\/polym16050582","type":"journal-article","created":{"date-parts":[[2024,2,21]],"date-time":"2024-02-21T04:23:10Z","timestamp":1708489390000},"page":"582","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["The Influence of Residual Stresses on the Curve Shape\u2014Describing Interface Behavior in \u201cPolymer\u2013Fiber\u201d Systems"],"prefix":"10.3390","volume":"16","author":[{"given":"Yulia A.","family":"Gorbatkina","sequence":"first","affiliation":[{"name":"N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0003-8374-7248","authenticated-orcid":false,"given":"Viktoria G.","family":"Ivanova-Mumzhieva","sequence":"additional","affiliation":[{"name":"N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8982-3959","authenticated-orcid":false,"given":"Olga V.","family":"Alexeeva","sequence":"additional","affiliation":[{"name":"N.M. Emanuel Institute of Biochemical Physics, Russian Academy of Sciences, 119334 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1030-5794","authenticated-orcid":false,"given":"Mariya A.","family":"Vyatkina","sequence":"additional","affiliation":[{"name":"N.N. Semenov Federal Research Center for Chemical Physics, Russian Academy of Sciences, 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,2,21]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Bryce, D., Thomason, J., and Yang, L. (2020, January 7\u201310). Micromechanical and spectroscopic characterisation of the curing perfomance of epoxy resins in the microbond test. Proceedings of the IOP Confeence Series: Materials Science and Engineering, Roskilde, Denmark.","DOI":"10.1088\/1757-899X\/942\/1\/012019"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"107303","DOI":"10.1016\/j.compositesa.2022.107303","article-title":"The dependence of interfacial shear strength on temperature and matrix chemistry in glass fibre epoxy composites","volume":"164","author":"Minty","year":"2023","journal-title":"Compos. Part A Appl. Sci. Manuf."},{"key":"ref_3","unstructured":"Kerber, M.L., Vinogradov, V.M., Golovkin, G.S., Gorbatkina, Y.A., Krizhanovskiy, V.K., Kuperman, A.M., Simonov-Emelyanov, I.D., Haliulin, V.I., and Bunakov, V.A. (2018). Polymer Composite Materials: Structure, Properties, Technology, Profession."},{"key":"ref_4","unstructured":"Mihailin, Y.A. (2009). Special Polymer Composite Materials, Science bases and technologies. (In Russian)."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"126148","DOI":"10.1016\/j.polymer.2023.126148","article-title":"Length-scale discrepancy in the properties of epoxy resin specimens","volume":"283","author":"Laurikainen","year":"2023","journal-title":"Polymer"},{"key":"ref_6","unstructured":"Gorbatkina, J.Y.A. (1992). Adhesive Strength of Fibre-Polymer Systems, Ellis Horwood."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1016\/j.compositesb.2017.08.020","article-title":"A review of extending perfomance of epoxy resins using carbon nanomaterials","volume":"136","author":"Liu","year":"2018","journal-title":"Comp. Part B"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"439","DOI":"10.1134\/S0965545X19040096","article-title":"Effect of carbon nonefillers on the mechanical and interfacial properties of epoxy based nanocomposites. A review","volume":"61","author":"Shukla","year":"2019","journal-title":"Polym. Sci. Ser. A"},{"key":"ref_9","doi-asserted-by":"crossref","unstructured":"Matykiewicz, D. (2020). Hybrid Epoxy Composites with Both Powder and Fiber Filler: A Review of Mechanical and Thermomechanical Properties. Materials, 13.","DOI":"10.3390\/ma13081802"},{"key":"ref_10","unstructured":"Mavinkere, S., Jyotishkumar, R., Siengchin, P.S., and Tomas, S. (2022). Handbook of Epoxy\/Fiber Composites, Springer Nature."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"103182","DOI":"10.1016\/j.ijadhadh.2022.103182","article-title":"Effect of cooling rate on surface properties of ZnMgAl coating and adhesion to epoxy adhesive","volume":"117","author":"Ha","year":"2022","journal-title":"Int. J. Adhes. Adhes."},{"key":"ref_12","unstructured":"Mavinkere, S., Jyotishkumar, R., Siengchin, P.S., and Tomas, S. (2022). Handbook of Epoxy\/Fiber Composites, Springer Nature."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"5","DOI":"10.1186\/s40563-019-0121-z","article-title":"Microbond fibre bundle pullout technique to evaluate the interfacial adhesion of polyethylene and polypropylene self reinforced composites","volume":"7","author":"Chandran","year":"2019","journal-title":"Appl. Adhes. Sci."},{"key":"ref_14","first-page":"26","article-title":"Influence of temperature on mechanical properties and machining of fibre reinforced polymer composites: A review","volume":"16","author":"Shahabaz","year":"2021","journal-title":"Eng. Sci."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"247","DOI":"10.1016\/j.matpr.2022.01.082","article-title":"Estimation of fiber\/polymer bond strength from maximum load values recorded in the micro-bond tests","volume":"53","author":"Zernadji","year":"2022","journal-title":"Mater. Today Proc."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"101180","DOI":"10.1016\/j.coco.2022.101180","article-title":"Effects of cryo-thermal cycling on interlaminar shear strength and thermal expansion coefficient of carbon fiber\/graphene oxide-modified epoxy composites","volume":"32","author":"Qu","year":"2022","journal-title":"Compos. Commun."},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Feng, Y., Nie, Z., Deng, P., Luo, L., Hu, X., Su, J., Li, H., Fan, X., and Qi, S. (2022). An effective approach to improve the thermal conductivity, strength and stress relaxation of carbon nanotubes\/epoxy composites based on Vitrimer chemistry. Int. J. Mol. Sci., 23.","DOI":"10.3390\/ijms23168833"},{"key":"ref_18","doi-asserted-by":"crossref","unstructured":"Luo, X., Li, Y., Li, S., and Liu, X. (2022). Enhancement of mechanical properties and bonding properties of flake-zinc-powder-modified epoxy resin composites. Polymers, 14.","DOI":"10.3390\/polym14235323"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"2708","DOI":"10.1002\/pol.20230264","article-title":"Pull-out behavior of polymer fibers in concrete","volume":"61","author":"Pirskawetz","year":"2023","journal-title":"J. Polym. Sci."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"713","DOI":"10.1007\/s11029-023-10126-6","article-title":"Evaluating the local strength and crack resistance of an glass fiber epoxy composite in the interlayer tension and shear using a finite-element model and experimentally determined parameters of the cohesive zone","volume":"59","author":"Babaevsky","year":"2023","journal-title":"Mech. Compos. Mater."},{"key":"ref_21","doi-asserted-by":"crossref","unstructured":"Lan, Z., Deng, J., Xu, Z., Ye, Z., and Nie, Y. (2023). Study of heat treatment effect on mechanical properties of epoxy resin reinforced with fiber glass. Polymers, 15.","DOI":"10.3390\/polym15122734"},{"key":"ref_22","doi-asserted-by":"crossref","unstructured":"Yang, G., Cheng, F., Zuo, S., Zhang, J., Xu, Y., and Hu, X. (2023). Crowing carbon nanotubes in situ surrounding carbon fiber surface via chemical vapor deposition to reinfoce flexural strength of carbon fiber composites. Polymers, 15.","DOI":"10.3390\/polym15102309"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"37410","DOI":"10.1016\/j.ceramint.2022.09.096","article-title":"Composite materials based on a ceramic matrix of polycarbosilane and iron-containing nanoparticles","volume":"48","author":"Yurkov","year":"2022","journal-title":"Ceram. Int."},{"key":"ref_24","doi-asserted-by":"crossref","unstructured":"Petrova, T.V., Tretyakov, I.V., Kireynov, A.V., Shapagin, A.V., Budylin, N.Y., Alexeeva, O.V., Beshtoev, B.Z., Solodilov, V.I., Yurkov, G.Y., and Berlin, A.A. (2022). Structure and properties of epoxy polysulfone systems modified with an active diluent. Polymers, 14.","DOI":"10.3390\/polym14235320"},{"key":"ref_25","doi-asserted-by":"crossref","unstructured":"Tarasov, I.V., Borisov, A.V.O.R.S., Kireev, V.V., and Sirotin, I.S. (2022). Phozphazene-containg epoxy resins based on bisphenol F with enhanced heat resistance and mechanical properties: Sysnthesis anf properties. Polymers, 14.","DOI":"10.3390\/polym14214547"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"743","DOI":"10.1007\/s11029-023-10128-4","article-title":"Influence of polyethersulfone on the fracture toughness of epoxy matrices and reinforced plastics on their basis","volume":"59","author":"Solidlov","year":"2023","journal-title":"Mech. Compos. Mater."},{"key":"ref_27","doi-asserted-by":"crossref","unstructured":"Tretyakov, I.V., Petrova, T.V., Kireinov, A.V., Korokhin, R.A., Platonova, E.O., Alexeeva, O.V., Gorbatkina, Y.A., Solodilov, V.I., Yurkov, G.Y., and Berlin, A.A. (2023). Fracture of epoxy matrixes modified with thermo-plastic polymers and widning glass fibers reinforced plastics on their base under low-viscosity impact condition. Polymers, 15.","DOI":"10.3390\/polym15132958"},{"key":"ref_28","first-page":"63","article-title":"Resin-Glass Bond Characterisation","volume":"235","author":"McGarry","year":"1959","journal-title":"ASTM Bull."},{"key":"ref_29","first-page":"42","article-title":"Adhesion determination method of resins to glass fiber surface","volume":"4","author":"Shiryaeva","year":"1962","journal-title":"Plast. Massy"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"242","DOI":"10.1002\/pc.750060409","article-title":"The interface between glass and carbon fibers and thermosetting polymers","volume":"6","author":"Piggott","year":"1985","journal-title":"Polym. Compos."},{"key":"ref_31","first-page":"17","article-title":"A microbond method for detremination of the shear strength of a fiber\/resin interface","volume":"28","author":"Miller","year":"1989","journal-title":"Pomsopite Sci. Technol."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"6","DOI":"10.1007\/BF00619412","article-title":"Determination of adhesive strength in a thermoplastic-resin-thin-fiber system","volume":"26","author":"Dovgyalo","year":"1990","journal-title":"Mech. Compos. Mater."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"205","DOI":"10.1163\/156856101743418","article-title":"Investigation of load transfer between the fiber and the matrix in pull-out tests with fibers having different diameters","volume":"15","author":"Zhandarov","year":"2001","journal-title":"J. Adhes. Sci. Technol."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"1171","DOI":"10.1163\/156856102320256837","article-title":"Indirect estimation of fiber\/polymer bond strength and interfacial friction form maximum load values recorded in microbond and pull-out tests. Part I: Local bond strength","volume":"16","author":"Zhandarov","year":"2002","journal-title":"J. Adhes. Sci. Technol."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1134\/S1995421210020012","article-title":"Contact-layer method in adhesion mechanics: Picking fiber from a matrix","volume":"3","author":"Turusov","year":"2010","journal-title":"Polym. Sci. Ser. D"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1016\/j.ijadhadh.2014.07.006","article-title":"An alternative method of determing the local interfacial shear strength from force\u2014Displacement curves in the pull-out and microbond tests","volume":"55","author":"Zhandarov","year":"2014","journal-title":"Int. J. Adhes. Adhes."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"6038","DOI":"10.1021\/acsapm.2c00855","article-title":"Effects of Chemistry of Silicon Surfaces on the Curing Process and Adhesive Strength for Epoxy Resin","volume":"4","author":"Yamamoto","year":"2022","journal-title":"ACS Appl. Polym. Mater."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"107591","DOI":"10.1016\/j.polymertesting.2022.107591","article-title":"An overview of some sclaing issues un the sample preparation and data interpretation of the microbond test for fibre\u2014Matrix interface characterization","volume":"11","author":"Thomason","year":"2022","journal-title":"Polym. Test."},{"key":"ref_39","unstructured":"Gorbatkina, Y.A., and Ivanova-Mumzhieva, V.G. (2022). The Adhesion of Modified Epoxides to Fibers, Cambridge Scholars Publishing."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"72","DOI":"10.1088\/0508-3443\/3\/3\/302","article-title":"The elasticity and strength of paper and other fibrous materials","volume":"3","author":"Cox","year":"1952","journal-title":"Br. J. Appl. Phys."},{"key":"ref_41","unstructured":"Kelly, A., and Macmillan, N.H. (1986). Strong Solids, Charendon Press. [3rd ed.]."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"857","DOI":"10.1007\/s11029-023-10074-1","article-title":"Effect of Oligomeric Copoluimides on the properties of Epoxy Binders","volume":"58","author":"Vyatkina","year":"2023","journal-title":"Mech. Compos. Mater."}],"container-title":["Polymers"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-4360\/16\/5\/582\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T14:02:11Z","timestamp":1760104931000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-4360\/16\/5\/582"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,2,21]]},"references-count":42,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2024,3]]}},"alternative-id":["polym16050582"],"URL":"https:\/\/doi.org\/10.3390\/polym16050582","relation":{},"ISSN":["2073-4360"],"issn-type":[{"type":"electronic","value":"2073-4360"}],"subject":[],"published":{"date-parts":[[2024,2,21]]}}}