{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,8,18]],"date-time":"2026-08-18T05:03:52Z","timestamp":1787029432206,"version":"build-2736575974"},"reference-count":40,"publisher":"MDPI AG","issue":"13","license":[{"start":{"date-parts":[[2024,6,27]],"date-time":"2024-06-27T00:00:00Z","timestamp":1719446400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>In this study, we used a self-neutralizing system to counteract too acidic a pH, unsuitable for wood adhesives, and tested it on MUF resins augmented by the addition of citric acid or other organic acids, based on the addition of small percentages of hexamine or another suitable organic base to form an acid\u2013base buffer. In this manner, the pH of the adhesive was maintained above the minimum allowed value of 4, and the strength results of wood particleboard and plywood bonded with this adhesive system increased due to the additional cross-linking imparted by the citric acid. Thus, the wood constituents at the wood\/adhesive interface were not damaged\/degraded by too low a pH, thus avoiding longer-term service failure of the bonded joints. The addition of the buffering system increased the strength of the bondline in both the plywood and particleboard, both when dry and after hot water and boiling water tests. The IB strength of the particleboard was then increased by 15\u201317% when dry but by 82% after boiling. For the plywood, the shear strengths when dry and after 3 h in hot water at 63 \u00b0C were, respectively, 37% and 90% higher than for the control. The improvement in the bonded panel strength is ascribed to multiple reasons: (i) the slower, more regular cross-linking rate due to the action of the buffer; (ii) the shift in the polycondensation\u2013degradation equilibrium to the left induced by the higher pH and the long-term stability of the organic buffer; (iii) the additional cross-linking by citric acid of some of the MUF resin amine groups; (iv) the already known direct linking of citric acid with the carbohydrates and lignin constituents at the interface of the wood substrate; and (v) the likely covalent linking to the interfacial wood constituents of the prelinked MUF\u2013citric acid resin by some of the unreacted citric acid carboxyl groups.<\/jats:p>","DOI":"10.3390\/polym16131819","type":"journal-article","created":{"date-parts":[[2024,6,27]],"date-time":"2024-06-27T04:19:26Z","timestamp":1719461966000},"page":"1819","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Self-Neutralizing Melamine\u2013Urea\u2013Formaldehyde\u2013Citric Acid Resins for Wood Panel Adhesives"],"prefix":"10.3390","volume":"16","author":[{"given":"Xuedong","family":"Xi","sequence":"first","affiliation":[{"name":"Yunnan Key Laboratory of Wood Adhesives and Glued Products, College of Material Science and Engineering, Southwest Forestry University, Kunming 650224, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9749-7185","authenticated-orcid":false,"given":"Antonio","family":"Pizzi","sequence":"additional","affiliation":[{"name":"LERMAB-ENSTIB, University of Lorraine, 88000 Epinal, France"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Hong","family":"Lei","sequence":"additional","affiliation":[{"name":"College of Chemistry and Material Engineering, Zhejiang A&F University, Hangzhou 311300, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Xiaojian","family":"Zhou","sequence":"additional","affiliation":[{"name":"Yunnan Key Laboratory of Wood Adhesives and Glued Products, College of Material Science and Engineering, Southwest Forestry University, Kunming 650224, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guanben","family":"Du","sequence":"additional","affiliation":[{"name":"Yunnan Key Laboratory of Wood Adhesives and Glued Products, College of Material Science and Engineering, Southwest Forestry University, Kunming 650224, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,6,27]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1991","DOI":"10.1002\/app.34708","article-title":"Application of citric acid as natural adhesive for wood","volume":"123","author":"Umemura","year":"2012","journal-title":"J. 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