{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,14]],"date-time":"2026-03-14T20:03:11Z","timestamp":1773518591858,"version":"3.50.1"},"reference-count":34,"publisher":"MDPI AG","issue":"14","license":[{"start":{"date-parts":[[2024,7,21]],"date-time":"2024-07-21T00:00:00Z","timestamp":1721520000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Ministry of Science and Higher Education of the Russian Federation","award":["075-15-2022-300"],"award-info":[{"award-number":["075-15-2022-300"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>This research is aimed at analyzing existing plugging compositions and developing a new plugging composition based on phenol-formaldehyde resin. This paper presents the results of studies of a hardening composition based on phenol-formaldehyde resin for repair and insulation work in wells. The plugging composition consists of two parts: Component \u201cA\u201d (resin and additives) and Component \u201cB\u201d (hardener). A resol-type water-soluble phenol-formaldehyde resin was selected for testing. The resin was additionally modified with special additives to improve performance properties. A mixture of acids was chosen as a hardener. Concentrations of resin and hardener were selected to ensure optimal loss of fluidity of the composition for different temperatures. The main physicochemical properties of the plugging composition were determined. The elastic-strength characteristics of the developed composition after curing at various temperatures (Poisson\u2019s ratio, Young\u2019s modulus, and compressive strength) were assessed. It has been experimentally proven that samples based on phenol-formaldehyde resin do not collapse completely under load but undergo longitudinal and transverse deformations. As the amount of hardener in the system increases, the compressive strength decreases. The presence of the elastic-strength properties of cementing compositions based on synthetic resins distinguishes them favorably from hardening compositions based on cement and microcement.<\/jats:p>","DOI":"10.3390\/polym16142077","type":"journal-article","created":{"date-parts":[[2024,7,22]],"date-time":"2024-07-22T08:24:59Z","timestamp":1721636699000},"page":"2077","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Study of Plugging Compositions Based on Synthetic Resins for Repair and Insulation Work in Wells"],"prefix":"10.3390","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0009-0005-7840-4085","authenticated-orcid":false,"given":"Svetlana V.","family":"Aksenova","sequence":"first","affiliation":[{"name":"Department of Technology of Chemical Substances for the Oil and Gas Industry, Gubkin University, 119991 Moscow, Russia"},{"name":"World-Class Research Center \u00abEfficient Development of the Global Liquid Hydrocarbon Reserves\u00bb, National University of Oil and Gas (Gubkin University), 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Lyubov A.","family":"Magadova","sequence":"additional","affiliation":[{"name":"Department of Technology of Chemical Substances for the Oil and Gas Industry, Gubkin University, 119991 Moscow, Russia"},{"name":"World-Class Research Center \u00abEfficient Development of the Global Liquid Hydrocarbon Reserves\u00bb, National University of Oil and Gas (Gubkin University), 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Sergey I.","family":"Kudryashov","sequence":"additional","affiliation":[{"name":"Department of Technology of Chemical Substances for the Oil and Gas Industry, Gubkin University, 119991 Moscow, Russia"},{"name":"Zarubezhneft JSC, 101000 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Mikhail A.","family":"Silin","sequence":"additional","affiliation":[{"name":"Department of Technology of Chemical Substances for the Oil and Gas Industry, Gubkin University, 119991 Moscow, Russia"},{"name":"World-Class Research Center \u00abEfficient Development of the Global Liquid Hydrocarbon Reserves\u00bb, National University of Oil and Gas (Gubkin University), 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Aleksandr N.","family":"Kulikov","sequence":"additional","affiliation":[{"name":"Department of Technology of Chemical Substances for the Oil and Gas Industry, Gubkin University, 119991 Moscow, Russia"},{"name":"World-Class Research Center \u00abEfficient Development of the Global Liquid Hydrocarbon Reserves\u00bb, National University of Oil and Gas (Gubkin University), 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Artem V.","family":"Gevorkian","sequence":"additional","affiliation":[{"name":"Department of Technology of Chemical Substances for the Oil and Gas Industry, Gubkin University, 119991 Moscow, Russia"},{"name":"World-Class Research Center \u00abEfficient Development of the Global Liquid Hydrocarbon Reserves\u00bb, National University of Oil and Gas (Gubkin University), 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Denis D.","family":"Polyakov","sequence":"additional","affiliation":[{"name":"Department of Technology of Chemical Substances for the Oil and Gas Industry, Gubkin University, 119991 Moscow, Russia"},{"name":"World-Class Research Center \u00abEfficient Development of the Global Liquid Hydrocarbon Reserves\u00bb, National University of Oil and Gas (Gubkin University), 119991 Moscow, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]}],"member":"1968","published-online":{"date-parts":[[2024,7,21]]},"reference":[{"key":"ref_1","unstructured":"Demakhin, S.A. (2011). Himicheskie Metody Ogranicheniya Vodopritoka v Neftyanye Skvazhiny, Nedra."},{"key":"ref_2","unstructured":"Magadova, L.A., Efimov, N.N., Kozlov, A.N., Shidginov, Z.A., and Efimov, M.N. (2012). K Voprosu Povysheniya Kachestva Remontno-Izolyacionnyh Rabot v Nizkopronicaemyh Kollektorah Neftyanyh i Gazovyh Skvazhin. Territoriya Neftegaz."},{"key":"ref_3","unstructured":"(2019). Cementy Tamponazhnye (Standard No. GOST 34532-2019)."},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Nguyen, H., Zatar, W., and Mutsuyoshi, H. (2017). Mechanical Properties of Hybrid Polymer Composite. Hybrid Polymer Composite Materials, Elsevier.","DOI":"10.1016\/B978-0-08-100787-7.00004-4"},{"key":"ref_5","unstructured":"Goraev, I.M., and Ibragimov, A.A. (2019). Phenol-Formaldehyde Resins, Vestnik Magistratury."},{"key":"ref_6","first-page":"15","article-title":"Technology of preparation and properties of phenol-formaldehyde resins and compositions based on them","volume":"2","author":"Vitkalova","year":"2017","journal-title":"Sci. Rev. Tech. Sci."},{"key":"ref_7","first-page":"29","article-title":"Thermal Conditions of Oil and Gas Deposits in the Northern Part of the West Siberian Plate","volume":"5","author":"Gorbunov","year":"2018","journal-title":"Oil Gas Geol. Geol. Neft. Gaza"},{"key":"ref_8","unstructured":"Akutin, M.S., Brodskij, G.S., Raevskaya, V.I., Sokolov, A.D., Stal\u2019nova, M.A., Timofeev, A.V., Fajdel\u2019, I.Y.A., Sharshkova, E.S., and Yakobson, B.V. (1972). Sposob Otverzhdeniya Novolachnyh Fenolformal\u2019degidnyh Smol. (USSR Patent SU 336334 A1)."},{"key":"ref_9","unstructured":"Mejer, N., and Fulon, R. (1983). Otverditel\u2019 Dlya Rezol\u2019nyh Fenolformal\u2019degidnyh Smol. (USSR Patent SU 1011054 A3)."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"48","DOI":"10.17213\/0321-2653-2019-2-48-54","article-title":"Study of the kinetics of the process of the curing of reshonic phenolomomedehide resin modified by metal salts","volume":"2","author":"Eroshenko","year":"2019","journal-title":"Univ. News North-Cauc. Reg. Tech. Sci. Ser."},{"key":"ref_11","doi-asserted-by":"crossref","unstructured":"Alsaihati, Z.A., Al-Yami, A.S., Wagle, V., BinAli, A., Mukherjee, T.S., Al-Kubaisi, A., Halim, A.H., Khalil, M., and Alsafran, A. (2017, January 24\u201327). An Overview of Polymer Resin Systems Deployed for Remedial Operations in Saudi Arabia. Proceedings of the SPE Kingdom of Saudi Arabia Annual Technical Symposium and Exhibition, Dammam, Saudi Arabia.","DOI":"10.2118\/188122-MS"},{"key":"ref_12","doi-asserted-by":"crossref","unstructured":"Jones, P.J., London, B.A., Tennison, L.B., and Karcher, J.D. (2013, January 20\u201322). Unconventional Remediation in the Utica Shale Using Advanced Resin Technologies. Proceedings of the SPE Eastern Regional Meeting, Pittsburgh, PA, USA.","DOI":"10.2118\/165699-MS"},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Elyas, O., Alyami, A., Wagle, V., and Alhareth, N. (2018, January 23\u201326). Use of Polymer Resins for Surface Annulus Isolation Enhancement. Proceedings of the SPE Kingdom of Saudi Arabia Annual Technical Symposium and Exhibition, Dammam, Saudi Arabia.","DOI":"10.2118\/192266-MS"},{"key":"ref_14","doi-asserted-by":"crossref","unstructured":"Urdaneta, J.A., Arroyave, J.M., Jones, P., Amaya, J.L., Coral, A., and Hernandez, H. (2014, January 21\u201323). Novel Gas Shutoff Resin System for Well Abandonment Applications in Colombia: A Case History. Proceedings of the SPE Latin America and Caribbean Petroleum Engineering Conference, Maracaibo, Venezuela.","DOI":"10.2118\/169400-MS"},{"key":"ref_15","doi-asserted-by":"crossref","unstructured":"Knudsen, K., Leon, G.A., Sanabria, A.E., Ansari, A., and Pino, R.M. (2015, January 9\u201312). First Application of Thermal Activated Resin as Unconventional LCM in the Middle East. Proceedings of the Abu Dhabi International Petroleum Exhibition and Conference, Abu Dhabi, United Arab Emirates.","DOI":"10.2523\/IPTC-18151-MS"},{"key":"ref_16","doi-asserted-by":"crossref","unstructured":"Beharie, C., Francis, S., and \u00d8vestad, K.H. (2015, January 22). Resin: An Alternative Barrier Solution Material. Proceedings of the SPE Bergen One Day Seminar, Bergen, Norway.","DOI":"10.2118\/173852-MS"},{"key":"ref_17","first-page":"38","article-title":"Development of Grouting Materials with High Impact Strength","volume":"9","author":"Ishbaev","year":"2015","journal-title":"Burenie i Neft\u2019"},{"key":"ref_18","first-page":"54","article-title":"The results of the research in the field of loss prevention the tightness of the annulus of the wells in the result static and dynamic loads","volume":"3","author":"Gnibidin","year":"2017","journal-title":"Bulatovskie Chteniya"},{"key":"ref_19","first-page":"2019","article-title":"Evaluation of the Degree of the Effect of Hardening Time and the Influence of the Clay Acid Reagent on the Elastic-Strength Properties of Cement Stone","volume":"4","author":"Korobov","year":"2019","journal-title":"Actual Probl. Oil Gas"},{"key":"ref_20","first-page":"115","article-title":"Analysis and selection of a grouting mixture, resistant to dynamic loads, in order to improve the support tightness quality in the annulus","volume":"333","author":"Blinov","year":"2022","journal-title":"Bull. Tomsk. Polytech. Univ. Geo Assets Eng."},{"key":"ref_21","doi-asserted-by":"crossref","unstructured":"Wasnik, A., Mete, S., and Ghosh, B. (2005, January 1\u20133). Application of Resin System for Sand Consolidation, Mud-Loss Control, and Channel Repairing. Proceedings of the SPE International Thermal Operations and Heavy Oil Symposium, Calgary, AB, Canada.","DOI":"10.2523\/97771-MS"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"120520","DOI":"10.1016\/j.jclepro.2020.120520","article-title":"Barriers and Incentives for the Use of Lignin-Based Resins: Results of a Comparative Importance Performance Analysis","volume":"256","author":"Lettner","year":"2020","journal-title":"J. Clean. Prod."},{"key":"ref_23","doi-asserted-by":"crossref","unstructured":"Abanum, A.M., and Appah, D. (2013, January 5\u20137). Laboratory Studies of Chemicals for Sand Consolidation (Scon) in the Niger Delta Fields. Proceedings of the SPE Nigeria Annual International Conference and Exhibition, Lagos, Nigeria.","DOI":"10.2118\/167516-MS"},{"key":"ref_24","doi-asserted-by":"crossref","unstructured":"Hashmi, A.A., Al-Yami, A.S., Dahmoush, A.A., Wagle, V., Alanqari, A., Alshaikh, Y., Gumsani, A.M., Aramco, S., Ali, W., and Al-Turki, A. (2020, January 9\u201312). Epoxy Resins-Cement Slurries for Primary Cementing Application. Proceedings of the Abu Dhabi International Petroleum Exhibition & Conference, Abu Dhabi, United Arab Emirates.","DOI":"10.2118\/202748-MS"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"336","DOI":"10.21285\/2686-9993-2019-42-3-336-348","article-title":"Developing Hardenable Foam Compositions for Well Tamping","volume":"42","author":"Zalivin","year":"2019","journal-title":"Earth Sci. Subsoil Use"},{"key":"ref_26","doi-asserted-by":"crossref","unstructured":"Kabir, A.H. (2001, January 8\u20139). Chemical Water & Gas Shutoff Technology\u2014An Overview. Proceedings of the SPE Asia Pacific Improved Oil Recovery Conference, Kuala Lumpur, Malaysia.","DOI":"10.2523\/72119-MS"},{"key":"ref_27","doi-asserted-by":"crossref","unstructured":"Yami, A., Buwaidi, H., Al-Herz, A., Mukherjee, T.S., Bedford, D., Viso, R., and Hugentobler, K. (2017, January 4\u20136). Application of Heavy Weight Cement-Resin Blend System to Prevent CCA Pressure in Saudi Arabia Deep Gas Fields. Proceedings of the SPE Oil and Gas India Conference and Exhibition, Mumbai, India.","DOI":"10.2118\/185337-MS"},{"key":"ref_28","doi-asserted-by":"crossref","unstructured":"Hakiki, F., Salam, D.D., Akbari, A., Nuraeni, N., Aditya, W., and Siregar, S. (2015, January 20\u201322). Is Epoxy-Based Polymer Suitable for Water Shut-Off Application?. Proceedings of the SPE\/IATMI Asia Pacific Oil & Gas Conference and Exhibition, Bali, Indonesia.","DOI":"10.2118\/176457-MS"},{"key":"ref_29","unstructured":"(2024). Petroleum and Related Products from Natural or Synthetic Sources\u2014Determination of Pour Point. Standard No. GOST 20287-2023 (ISO 3016:2019)."},{"key":"ref_30","first-page":"1043","article-title":"Oksimetil\u2019nye Proizvodnye Fenolov v Kachestve Otverditelej Novolachnyh Smol","volume":"37","author":"Sergeev","year":"1995","journal-title":"VMS. Seriya B"},{"key":"ref_31","first-page":"113","article-title":"Modification of Phenol-Formaldehyde Resin by the Products of Sulfite and Pulp Production","volume":"1","author":"Rusakov","year":"2016","journal-title":"Syst. Methods Technol."},{"key":"ref_32","first-page":"38","article-title":"Vliyanie Otverditelej Na Kinetiku Otverzhdeniya Rezol\u2019nyh Fenolkardanolformal\u2019degidnyh Smol","volume":"15","author":"Shishlov","year":"2012","journal-title":"Vestn. Kazan. Tekhnologicheskogo Univ."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"166","DOI":"10.1016\/j.ijadhadh.2018.03.006","article-title":"Properties of Phenol Formaldehyde Resin Modified with Silane Coupling Agent (KH550)","volume":"84","author":"Wei","year":"2018","journal-title":"Int. J. Adhes. Adhes."},{"key":"ref_34","unstructured":"Shutilov, V.A. (1980). Fundamentals of Ultrasound Physics: Tutorial, CRC Press."}],"container-title":["Polymers"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-4360\/16\/14\/2077\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T15:20:32Z","timestamp":1760109632000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-4360\/16\/14\/2077"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,7,21]]},"references-count":34,"journal-issue":{"issue":"14","published-online":{"date-parts":[[2024,7]]}},"alternative-id":["polym16142077"],"URL":"https:\/\/doi.org\/10.3390\/polym16142077","relation":{},"ISSN":["2073-4360"],"issn-type":[{"value":"2073-4360","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,7,21]]}}}