{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,19]],"date-time":"2026-02-19T08:33:13Z","timestamp":1771489993806,"version":"3.50.1"},"reference-count":31,"publisher":"MDPI AG","issue":"20","license":[{"start":{"date-parts":[[2024,10,12]],"date-time":"2024-10-12T00:00:00Z","timestamp":1728691200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>This study outlines a method for preparing a complex involving glycoluril and melamine (GU-ME). The structure of the resultant complex was analyzed using IR and NMR spectroscopy. In the subsequent phase, the polymer GUMEFA was derived from the resultant complex, employing hydroxyethylidene diphosphonic acid (HEDP) as a sustainable plasticizer, with a proposed chemical mechanism for its formation. The molecular weight of the resulting GUMEFA was analyzed, and the formation chemistry was proposed. GUMEFA was characterized, and its free formaldehyde and methylol group contents were investigated. It was observed that GUMEFA prepared with HEDP contained approximately 1.15\u20131.34 wt.% free formaldehyde and 1.56\u20130.54 wt.% methylol groups. These findings provide valuable insights for developing resins of different compositions and applications, thereby paving the way for producing composite materials with tailored properties.<\/jats:p>","DOI":"10.3390\/polym16202877","type":"journal-article","created":{"date-parts":[[2024,10,14]],"date-time":"2024-10-14T06:46:33Z","timestamp":1728888393000},"page":"2877","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["The Synthesis of a New Glycoluryl\u2013Melamine\u2013Formaldehyde Polymer under the Action of HEDP and the Investigation of the Content of Methylol Groups and Free Formaldehyde"],"prefix":"10.3390","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0009-0006-5272-6526","authenticated-orcid":false,"given":"Nurdana","family":"Kanasheva","sequence":"first","affiliation":[{"name":"Department of Chemistry, L.N. Gumilyov Eurasian National University, Astana 010008, Kazakhstan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7125-7290","authenticated-orcid":false,"given":"Arthur","family":"Ukhov","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry, National Research Tomsk State University, 634028 Tomsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4532-2882","authenticated-orcid":false,"given":"Victor S.","family":"Malkov","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry, National Research Tomsk State University, 634028 Tomsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0009-0000-5080-4523","authenticated-orcid":false,"given":"Alexander","family":"Gubankov","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry, National Research Tomsk State University, 634028 Tomsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9764-6729","authenticated-orcid":false,"given":"Samal","family":"Sergazina","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Biotechnology, Sh. Ualikhanov University, Kokshetau 020000, Kazakhstan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Manar A.","family":"Issabayeva","sequence":"additional","affiliation":[{"name":"Department of Chemistry and Chemical Technologies, Toraighyrov University, Pavlodar 140008, Kazakhstan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Togzhan","family":"Mashan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, L.N. Gumilyov Eurasian National University, Astana 010008, Kazakhstan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Ainagul","family":"Kolpek","sequence":"additional","affiliation":[{"name":"Department of Chemistry, L.N. Gumilyov Eurasian National University, Astana 010008, Kazakhstan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Roza","family":"Ryskaliyeva","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry and Chemical Technology, Department of General and Inorganic Chemistry, Al-Farabi Kazakh National University, Almaty 050000, Kazakhstan"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3335-3166","authenticated-orcid":false,"given":"Abdigali","family":"Bakibaev","sequence":"additional","affiliation":[{"name":"Faculty of Chemistry, National Research Tomsk State University, 634028 Tomsk, Russia"}],"role":[{"role":"author","vocabulary":"crossref"}]},{"given":"Rakhmetulla","family":"Yerkassov","sequence":"additional","affiliation":[{"name":"Department of Chemistry, L.N. 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