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However, a huge challenge of smart fibers as wearable materials is their stretching capability for seamless integration with the human body. Herein, stretchable thermochromic fluorescent fibers are prepared based on self-crystallinity phase change, using elastic polyurethane (PU) as the fiber matrix, to meet the dynamic requirements of the human body. The switching fluorescence-emitting characteristic of the fibers is derived from the reversible conversion of the dispersion\/aggregation state of the fluorophore coumarin 6 (C6) and the quencher methylene blue (MB) in the phase-change material hexadecanoic acid (HcA) during heating\/cooling processes. Considering the important role of phase-change materials, thermochromic fluorescent dye is encapsuled in the solid state via the piercing\u2013solidifying method to avoid the dissolution of HcA by the organic solvent of the PU spinning solution and maintain excellent thermochromic behavior in the fibers. The fibers obtained by wet spinning exhibit good fluorescent emission contrast and reversibility, as well as high elasticity of 800% elongation. This work presents a strategy for constructing stretchable smart luminescence fibers for human\u2013machine interaction and communications.<\/jats:p>","DOI":"10.3390\/polym16243575","type":"journal-article","created":{"date-parts":[[2024,12,23]],"date-time":"2024-12-23T08:16:07Z","timestamp":1734941767000},"page":"3575","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Stretchable Thermochromic Fluorescent Fibers Based on Self-Crystallinity Phase Change for Smart Wearable Displays"],"prefix":"10.3390","volume":"16","author":[{"given":"Yongmei","family":"Guo","sequence":"first","affiliation":[{"name":"Fujian Key Laboratory of Novel Functional Textile Fibers and Materials, Clothing and Design Faculty, Minjiang University, Fuzhou 350108, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Zixi","family":"Hu","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Technical Textiles, Ministry of Education, College of Textiles, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luyao","family":"Zhan","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Technical Textiles, Ministry of Education, College of Textiles, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Yongkun","family":"Liu","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Technical Textiles, Ministry of Education, College of Textiles, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Luping","family":"Sun","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Technical Textiles, Ministry of Education, College of Textiles, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6504-2629","authenticated-orcid":false,"given":"Ying","family":"Ma","sequence":"additional","affiliation":[{"name":"Engineering Research Center of Technical Textiles, Ministry of Education, College of Textiles, Donghua University, Shanghai 201620, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2024,12,21]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"622","DOI":"10.1007\/s42765-024-00386-9","article-title":"Advanced Design of Fibrous Flexible Actuators for Smart Wearable Applications","volume":"6","author":"Fang","year":"2024","journal-title":"Adv. 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