{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T12:01:08Z","timestamp":1789992068203,"version":"4.0.1"},"reference-count":96,"publisher":"MDPI AG","issue":"18","license":[{"start":{"date-parts":[[2026,9,17]],"date-time":"2026-09-17T00:00:00Z","timestamp":1789603200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Petroleum-Gas University of Ploiesti, Romania","award":["30757\/11.12.2024-DBD"],"award-info":[{"award-number":["30757\/11.12.2024-DBD"]}],"id":[{"id":"https:\/\/ror.org\/00abdnc40","id-type":"ROR","asserted-by":"crossref"}]},{"award":["30757\/11.12.2024-DBD"],"award-info":[{"award-number":["30757\/11.12.2024-DBD"]}],"id":[{"id":"https:\/\/ror.org\/00abdnc40","id-type":"ROR","asserted-by":"publisher"}]},{"name":"Ministry of Education and Research, CCCDI\u2014UEFISCDI","award":["PN-IV-P6-6.1-CoEx-2024-0120"],"award-info":[{"award-number":["PN-IV-P6-6.1-CoEx-2024-0120"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>The increasing environmental concerns associated with petroleum-based packaging materials have accelerated the development of biodegradable alternatives, with starch-based films emerging as promising candidates. This study investigates the influence of grape seed oil (5\u201315 wt.%) and storage time (up to 5 months) on the mechanical, thermal, structural, and surface properties of potato-starch-based films for biodegradable packaging applications. Oil incorporation improved the initial film performance, increasing tensile strength (1.27\u20133.11 MPa), enhancing thermal stability (melting temperature up to ~118 \u00b0C), and promoting higher surface hydrophobicity (contact angle up to ~87\u00b0). The differential scanning calorimetry (DSC) analysis indicated time-dependent changes in the thermal transitions associated with the reorganization of ordered starch domains with oil addition, from 39.96% for samples with 5% oil to 36.40% for samples with 15% oil. After three months, all oil-containing samples exhibited a substantial reduction in ultimate tensile strength, with normalized stress values decreasing to 0.74\u20131.18 depending on oil content. However, after 5 months, the evaluated properties had values close to or above the reference. Statistical evaluation confirmed that storage time is the dominant factor governing property evolution, exceeding the influence of oil concentration.<\/jats:p>","DOI":"10.3390\/polym18182279","type":"journal-article","created":{"date-parts":[[2026,9,21]],"date-time":"2026-09-21T11:05:53Z","timestamp":1789988753000},"page":"2279","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Evaluation of the Storage Stability of Starch-Based Films Containing Grape Seed Oil"],"prefix":"10.3390","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5226-0125","authenticated-orcid":false,"given":"Elena-Emilia","family":"Sirbu","sequence":"first","affiliation":[{"name":"Chemistry Department, Petroleum-Gas University of Ploie\u0219ti, Bucharest Blvd. 39, 100680 Ploie\u0219ti, Romania"},{"name":"National Institute for Research & Development in Chemistry and Petrochemistry ICECHIM, 060021 Bucharest, Romania"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"conceptualization","vocabulary":"credit"},{"role":"writing-review-editing","vocabulary":"credit"},{"role":"methodology","vocabulary":"credit"},{"role":"investigation","vocabulary":"credit"},{"role":"software","vocabulary":"credit"},{"role":"visualization","vocabulary":"credit"},{"role":"supervision","vocabulary":"credit"},{"role":"project-administration","vocabulary":"credit"},{"role":"writing-original-draft","vocabulary":"credit"}]},{"given":"Bianca Ana-Maria","family":"Burdusel","sequence":"additional","affiliation":[{"name":"Chemistry Department, Petroleum-Gas University of Ploie\u0219ti, Bucharest Blvd. 39, 100680 Ploie\u0219ti, Romania"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"writing-original-draft","vocabulary":"credit"},{"role":"writing-review-editing","vocabulary":"credit"},{"role":"investigation","vocabulary":"credit"},{"role":"methodology","vocabulary":"credit"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5563-6554","authenticated-orcid":false,"given":"Maria","family":"T\u0103nase","sequence":"additional","affiliation":[{"name":"Mechanical Engineering Department, Petroleum-Gas University of Ploie\u0219ti, 100680 Ploiesti, Romania"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"methodology","vocabulary":"credit"},{"role":"investigation","vocabulary":"credit"},{"role":"writing-original-draft","vocabulary":"credit"},{"role":"writing-review-editing","vocabulary":"credit"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9562-7564","authenticated-orcid":false,"given":"Gheorghe","family":"Branoiu","sequence":"additional","affiliation":[{"name":"Petroleum Geology and Reservoir Engineering Department, Petroleum-Gas University of Ploie\u0219ti, 100680 Ploiesti, Romania"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"methodology","vocabulary":"credit"},{"role":"investigation","vocabulary":"credit"},{"role":"writing-review-editing","vocabulary":"credit"},{"role":"writing-original-draft","vocabulary":"credit"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1563-2804","authenticated-orcid":false,"given":"Ionut","family":"Banu","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biochemical Engineering, National University of Science and Technology POLITEHNICA Bucharest, 1-7 Gh. Polizu, 011061 Bucharest, Romania"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"formal-analysis","vocabulary":"credit"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0422-387X","authenticated-orcid":false,"given":"Catalina","family":"Calin","sequence":"additional","affiliation":[{"name":"Chemistry Department, Petroleum-Gas University of Ploie\u0219ti, Bucharest Blvd. 39, 100680 Ploie\u0219ti, Romania"}],"role":[{"vocabulary":"crossref","role":"author"},{"role":"methodology","vocabulary":"credit"},{"role":"investigation","vocabulary":"credit"},{"role":"writing-review-editing","vocabulary":"credit"},{"role":"writing-original-draft","vocabulary":"credit"},{"role":"software","vocabulary":"credit"},{"role":"formal-analysis","vocabulary":"credit"}]}],"member":"1968","published-online":{"date-parts":[[2026,9,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Lin, J., Jaiswal, A.K., and Jaiswal, S. (2025). 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