{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,9,15]],"date-time":"2026-09-15T18:03:21Z","timestamp":1789495401288,"version":"build-2803163510"},"reference-count":66,"publisher":"MDPI AG","issue":"19","license":[{"start":{"date-parts":[[2023,9,28]],"date-time":"2023-09-28T00:00:00Z","timestamp":1695859200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100012166","name":"National Key Research and Development Program of China","doi-asserted-by":"publisher","award":["2021YFC2103300"],"award-info":[{"award-number":["2021YFC2103300"]}],"id":[{"id":"10.13039\/501100012166","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Sensors"],"abstract":"<jats:p>Phenolic compounds are one of the main organic pollutants in the environment that can seriously affect ecosystems, even at very low concentrations. Due to the resistance of phenolic compounds to microorganisms, conventional biological treatment methods face challenges in effectively addressing this pollution problem. In this study, a novel laccase mimic (Tris-Cu nanozyme) is prepared using a simple and rapid synthesis strategy based on the coordination of copper ions and amino groups in Tris(hydroxymethyl)aminomethane (Tris). It is found that the Tris-Cu nanozyme exhibits good catalytic activity against a variety of phenolic compounds, the Km, Vmax and Kcat are determined to be 0.18 mM, 15.62 \u03bcM\u00b7min\u22121 and 1.57 \u00d7 107 min\u22121 using 2,4-dichlorophenol (2,4-DP) as the substrate, respectively. Then, based on the laccase-like activity of the Tris-Cu nanozyme, a novel colorimetric method for 2,4-DP (the limit of detection (LOD) = 2.4 \u03bcM, S\/N = 3) detection in the range of 10\u2013400 \u03bcM was established, and its accuracy was verified by analyzing tap and lake water samples. In addition, the Tris-Cu nanozyme shows excellent removal abilities for six phenolic compounds in experiments. The removal percentages for 2,4-DP, 2-chlorophenol (2-CP), phenol, resorcinol, 2,6-dimethoxyphenol (2,6-DOP), and bisphenol A (BPA) are 100%, 100%, 100%, 100%, 87%, and 81% at 1 h, respectively. In the simulated effluent, the Tris-Cu nanozyme maintains its efficient catalytic activity towards 2,4-DP, with a degradation percentage of 76.36% at 7 min and a reaction rate constant (k0) of 0.2304 min\u22121. Therefore, this metal\u2013organic complex shows promise for applications in the monitoring and degrading of environmental pollutants.<\/jats:p>","DOI":"10.3390\/s23198137","type":"journal-article","created":{"date-parts":[[2023,9,28]],"date-time":"2023-09-28T07:50:26Z","timestamp":1695887426000},"page":"8137","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":46,"title":["Tris-Copper Nanozyme as a Novel Laccase Mimic for the Detection and Degradation of Phenolic Compounds"],"prefix":"10.3390","volume":"23","author":[{"given":"Tong-Qing","family":"Chai","sequence":"first","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Jia-Li","family":"Wang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Guo-Ying","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"given":"Ling-Xiao","family":"Chen","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China"}],"role":[{"vocabulary":"crossref","role":"author"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9300-5710","authenticated-orcid":false,"given":"Feng-Qing","family":"Yang","sequence":"additional","affiliation":[{"name":"School of Chemistry and Chemical Engineering, Chongqing University, Chongqing 401331, China"}],"role":[{"vocabulary":"crossref","role":"author"}]}],"member":"1968","published-online":{"date-parts":[[2023,9,28]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"135824","DOI":"10.1016\/j.chemosphere.2022.135824","article-title":"Recent advances in the utilization of immobilized laccase for the degradation of phenolic compounds in aqueous solutions: A review","volume":"307","author":"Chen","year":"2022","journal-title":"Chemosphere"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"158771","DOI":"10.1016\/j.scitotenv.2022.158771","article-title":"Nanozyme-based pollutant sensing and environmental treatment: Trends, challenges, and perspectives","volume":"854","author":"Singh","year":"2022","journal-title":"Sci. Total Environ."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"2024","DOI":"10.1016\/j.jece.2017.04.003","article-title":"High efficient treatment of the petrochemical phenolic effluent using spent catalyst: Experimental and optimization","volume":"5","author":"Vosoughi","year":"2017","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"387","DOI":"10.1007\/s11157-014-9342-6","article-title":"A comprehensive overview of bacteria and fungi used for pentachlorophenol biodegradation","volume":"13","author":"Bosso","year":"2014","journal-title":"Rev. Environ. Sci. Bio-Technol."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"2876","DOI":"10.1016\/j.envpol.2011.04.047","article-title":"Comparison of competitive and synergetic adsorption of three phenolic compounds on river sediment","volume":"159","author":"Gao","year":"2011","journal-title":"Environ. Pollut."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"1113","DOI":"10.1001\/2012.jama.11461","article-title":"Association between urinary bisphenol A concentration and obesity prevalence in children and adolescents","volume":"308","author":"Trasande","year":"2012","journal-title":"JAMA J. Am. Med. Assoc."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"157","DOI":"10.1007\/s40726-016-0035-3","article-title":"A short review of techniques for phenol removal from wastewater","volume":"2","author":"Villegas","year":"2016","journal-title":"Curr. Pollut. Rep."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"125211","DOI":"10.1016\/j.jhazmat.2021.125211","article-title":"\u2018Laccase-like\u2019 properties of coral-like silver citrate micro-structures for the degradation and determination of phenolic pollutants and adrenaline","volume":"412","author":"Koyappayil","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"4833","DOI":"10.1080\/10408398.2021.1879003","article-title":"Food safety and quality assessment: Comprehensive review and recent trends in the applications of ion mobility spectrometry (IMS)","volume":"62","author":"Alikord","year":"2022","journal-title":"Crit. Rev. Food Sci. Nutr."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"122775","DOI":"10.1016\/j.talanta.2021.122775","article-title":"A novel selective detection method for sulfide in food systems based on the GMP-Cu nanozyme with laccase activity","volume":"235","author":"Huang","year":"2021","journal-title":"Talanta"},{"key":"ref_11","doi-asserted-by":"crossref","unstructured":"Davoodi-Rad, K., Shokrollahi, A., Shahdost-Fard, F., and Azadkish, K. (2023). Copper-guanosine nanorods (Cu-Guo NRs) as a laccase mimicking nanozyme for colorimetric detection of rutin. Biosensors, 13.","DOI":"10.3390\/bios13030374"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1109","DOI":"10.1016\/j.jclepro.2017.02.188","article-title":"The relative performance of microwave regenerated activated carbons on the removal of phenolic pollutants","volume":"149","author":"Yagmur","year":"2017","journal-title":"J. Clean. Prod."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"116136","DOI":"10.1016\/j.watres.2020.116136","article-title":"A novel peroxymonosulfate (PMS)-enhanced iron coagulation process for simultaneous removal of trace organic pollutants in water","volume":"185","author":"Wang","year":"2020","journal-title":"Water Res."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"116310","DOI":"10.1016\/j.seppur.2019.116310","article-title":"Removal of phenolic pollutants from wastewater streams using ionic liquids","volume":"236","author":"Sas","year":"2020","journal-title":"Sep. Purif. Technol."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"126930","DOI":"10.1016\/j.biortech.2022.126930","article-title":"Bioremediation of phenolic pollutants by algae-current status and challenges","volume":"350","author":"Wu","year":"2022","journal-title":"Bioresour. Technol."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"1525","DOI":"10.1039\/D0EN00120A","article-title":"Novel photocatalytic performance of nanocage-like MIL-125-NH2 induced by adsorption of phenolic pollutants","volume":"7","author":"Shen","year":"2020","journal-title":"Environ. Sci. Nano"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"45","DOI":"10.1016\/j.aca.2019.08.024","article-title":"Graphene nanoplatelet supported CeO2 nanocomposites towards electrocatalytic oxidation of multiple phenolic pollutants","volume":"1088","author":"Li","year":"2019","journal-title":"Anal. Chim. Acta"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"3541","DOI":"10.1039\/D1NJ05658A","article-title":"Current research progress on laccase-like nanomaterials","volume":"46","author":"Lei","year":"2022","journal-title":"New J. Chem."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"167","DOI":"10.1016\/j.cjche.2020.04.012","article-title":"Efficient elimination and detection of phenolic compounds in juice using laccase mimicking nanozymes","volume":"29","author":"Huang","year":"2021","journal-title":"Chin. J. Chem. Eng."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"128404","DOI":"10.1016\/j.jhazmat.2022.128404","article-title":"Construction of biomimetic nanozyme with high laccase- and catecholase-like activity for oxidation and detection of phenolic compounds","volume":"429","author":"Wang","year":"2022","journal-title":"J. Hazard. Mater."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"1506","DOI":"10.1038\/s41596-018-0001-1","article-title":"Standardized assays for determining the catalytic activity and kinetics of peroxidase-like nanozymes","volume":"13","author":"Jiang","year":"2018","journal-title":"Nat. Protoc."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"2841","DOI":"10.1002\/elps.200700869","article-title":"Critical evaluation of buffering solutions for pKa determination by capillary electrophoresis","volume":"29","author":"Fuguet","year":"2008","journal-title":"Electrophoresis"},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"5882","DOI":"10.1039\/c3ra00063j","article-title":"Interplay of ion specificity, pH and buffers: Insights from electrophoretic mobility and pH measurements of lysozyme solutions","volume":"3","author":"Cugia","year":"2013","journal-title":"RSC Adv."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"113","DOI":"10.1016\/j.chroma.2006.05.008","article-title":"Background electrolytes in 50% methanol\/water for the determination of acidity constants of basic drugs by capillary zone electrophoresis","volume":"1123","author":"Ruiz","year":"2006","journal-title":"J. Chromatogr. A"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"935","DOI":"10.1016\/j.jcis.2022.07.167","article-title":"Cu-boosted one-pot nanoarchitectonics for synthesis of polydopamine membranes as reusable laccase mimic","volume":"628","author":"Gao","year":"2022","journal-title":"J. Colloid Interface Sci."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"452","DOI":"10.1016\/j.apcatb.2019.05.012","article-title":"Construction of a bioinspired laccase-mimicking nanozyme for the degradation and detection of phenolic pollutants","volume":"254","author":"Wang","year":"2019","journal-title":"Appl. Catal. B Environ."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"124340","DOI":"10.1016\/j.jhazmat.2020.124340","article-title":"Biodegradation of malachite green by a novel laccase-mimicking multicopper BSA-Cu complex: Performance optimization, intermediates identification and artificial neural network modeling","volume":"406","author":"Rashtbari","year":"2021","journal-title":"J. Hazard. Mater."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"40","DOI":"10.1039\/D1AN01817E","article-title":"Copper fumarate with high-bifunctional nanozyme activities at different pH values for glucose and epinephrine colorimetric detection in human serum","volume":"147","author":"Ying","year":"2021","journal-title":"Analyst"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"138220","DOI":"10.1016\/j.cej.2022.138220","article-title":"Multivalent Ce-MOFs as biomimetic laccase nanozyme for environmental remediation","volume":"450","author":"Liang","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"701","DOI":"10.1021\/acs.nanolett.2c04697","article-title":"Amino-ligand-coordinated dicopper active sites enable catechol oxidase-like activity for chiral recognition and catalysis","volume":"23","author":"Sha","year":"2023","journal-title":"Nano Lett."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"134677","DOI":"10.1016\/j.cej.2022.134677","article-title":"Preparation of amorphous MOF based biomimetic nanozyme with high laccase- and catecholase-like activity for the degradation and detection of phenolic compounds","volume":"434","author":"Wang","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"378","DOI":"10.1007\/s00604-022-05476-2","article-title":"Colorimetric assay of phosphate using a multicopper laccase-like nanozyme","volume":"189","author":"Huang","year":"2022","journal-title":"Microchim. Acta"},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"339725","DOI":"10.1016\/j.aca.2022.339725","article-title":"Buffer species-dependent catalytic activity of Cu-Adenine as a laccase mimic for constructing sensor array to identify multiple phenols","volume":"1204","author":"Tian","year":"2022","journal-title":"Anal. Chim. Acta"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"113187","DOI":"10.1016\/j.bios.2021.113187","article-title":"DNA-copper hybrid nanoflowers as efficient laccase mimics for colorimetric detection of phenolic compounds in paper microfluidic devices","volume":"182","author":"Tran","year":"2021","journal-title":"Biosens. Bioelectron."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"7608","DOI":"10.1021\/bi952971a","article-title":"Oxidation of phenols, anilines, and benzenethiols by fungal laccases: Correlation between activity and redox potentials as well as halide inhibition","volume":"35","author":"Xu","year":"1996","journal-title":"Biochemistry"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"737","DOI":"10.1021\/cr00027a010","article-title":"Copper-Dioxygen Complexes. Inorganic and Bioinorganic Perspectives","volume":"94","author":"Kitajima","year":"1994","journal-title":"Chem. Rev."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"121606","DOI":"10.1016\/j.saa.2022.121606","article-title":"Extension of the alkyl chain length to adjust the properties of laccase-mimicking MOFs for phenolic detection and discrimination","volume":"281","author":"Fu","year":"2022","journal-title":"Spectrochim. Acta Part A Mol. Biomol. Spectrosc."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"203","DOI":"10.1007\/s00604-012-0830-5","article-title":"Quantum dot induced phototransformation of 2,4-dichlorophenol, and its subsequent chemiluminescence reaction","volume":"178","author":"Wu","year":"2012","journal-title":"Microchim. Acta"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"3358","DOI":"10.1039\/c2ay25574j","article-title":"Myoglobin functioning as cytochrome P450 for biosensing of 2,4-dichlorophenol","volume":"4","author":"Sun","year":"2012","journal-title":"Anal. Methods"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"4802","DOI":"10.1039\/c1an15649g","article-title":"In situ encapsulation of laccase in nanofibers by electrospinning for development of enzyme biosensors for chlorophenol monitoring","volume":"136","author":"Liu","year":"2011","journal-title":"Analyst"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"4511","DOI":"10.1039\/C9AY01468C","article-title":"A matrix of perovskite micro-seeds and polypyrrole nanotubes tethered laccase\/graphite biosensor for sensitive quantification of 2,4-dichlorophenol in wastewater","volume":"11","author":"Yashas","year":"2019","journal-title":"Anal. Methods"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"3420","DOI":"10.20964\/2018.04.48","article-title":"Development of a metal-organic framework for the sensitive determination of 2,4-dichlorophenol","volume":"13","author":"Cui","year":"2018","journal-title":"Int. J. Electrochem. Sci."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"814","DOI":"10.1016\/j.ijbiomac.2020.02.043","article-title":"Nanocapsulation of horseradish peroxidase (HRP) enhances enzymatic performance in removing phenolic compounds","volume":"150","author":"Liu","year":"2020","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_44","first-page":"3144","article-title":"Synthesis of Fe-TiO2@Fe3O4 magnetic nanoparticles as a recyclable sonocatalyst for the degradation of 2,4-dichlorophenol","volume":"30","author":"Norabadi","year":"2023","journal-title":"Environ. Sci. Pollut. Res."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"132950","DOI":"10.1016\/j.chemosphere.2021.132950","article-title":"Green synthesis of MIL-100(Fe) derivatives and revealing their structure-activity relationship for 2,4-dichlorophenol photodegradation","volume":"291","author":"Wang","year":"2022","journal-title":"Chemosphere"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"1036","DOI":"10.1016\/j.enzmictec.2006.02.006","article-title":"Biodegradation of high amounts of phenol, catechol, 2,4-dichlorophenol and 2,6-dimethoxyphenol by Aspergillus awamori cells","volume":"39","author":"Stoilova","year":"2006","journal-title":"Enzyme Microb. Technol."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"121461","DOI":"10.1016\/j.seppur.2022.121461","article-title":"Core-shell bimetallic Fe-Co MOFs to activated peroxymonosulfate for efficient degradation of 2-chlorophenol","volume":"298","author":"Gu","year":"2022","journal-title":"Sep. Purif. Technol."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"6267","DOI":"10.1007\/s13762-019-02272-z","article-title":"Direct sunlight-driven degradation of 2-chlorophenol catalyzed by kaolinite-supported ZnO","volume":"16","author":"Zyoud","year":"2019","journal-title":"Int. J. Environ. Sci. Technol."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"120588","DOI":"10.1016\/j.jclepro.2020.120588","article-title":"Design of ternary Ni(OH)2\/graphene oxide\/TiO2 nanocomposite for enhanced photocatalytic degradation of organic, microbial contaminants, and aerobic digestion of dairy wastewater","volume":"258","author":"Barakat","year":"2020","journal-title":"J. Clean. Prod."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"128692","DOI":"10.1016\/j.chemosphere.2020.128692","article-title":"Removal of phenolic contaminants from water by in situ coated surfactant on Keggin-aluminum nanocluster and biodegradation","volume":"269","author":"Demissie","year":"2021","journal-title":"Chemosphere"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"122861","DOI":"10.1016\/j.jhazmat.2020.122861","article-title":"Roles of the mineral constituents in sludge-derived biochar in persulfate activation for phenol degradation","volume":"398","author":"Liang","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"129404","DOI":"10.1016\/j.chemosphere.2020.129404","article-title":"Preferential and efficient degradation of phenolic pollutants with cooperative hydrogen-bond interactions in photocatalytic process","volume":"269","author":"Zhang","year":"2021","journal-title":"Chemosphere"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"101489","DOI":"10.1016\/j.jwpe.2020.101489","article-title":"Phenol contaminated water treatment by photocatalytic degradation on electrospun Ag\/TiO2 nanofibers: Optimization by the response surface method","volume":"37","author":"Norouzi","year":"2020","journal-title":"J. Water Process. Eng."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"224","DOI":"10.5004\/dwt.2019.23673","article-title":"Photocatalytic degradation of phenolic compound (phenol, resorcinol and cresol) by titanium dioxide photocatalyst on ordered mesoporous carbon (CMK-3) support under UV irradiation","volume":"144","author":"Rahmani","year":"2019","journal-title":"Desalination Water Treat."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"103114","DOI":"10.1016\/j.jwpe.2022.103114","article-title":"Comparative study of dihydroxybenzene isomers degradation and bioelectricity generation using CuO as cathodic catalyst in double chambered microbial fuel cell","volume":"49","author":"Yap","year":"2022","journal-title":"J. Water Process. Eng."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"468","DOI":"10.1080\/10826068.2012.746233","article-title":"Ligninolytic activity patterns of pleurotus ostreatus obtained by submerged fermentation in presence of 2,6-dimethoxyphenol and remazol brilliant blue R dye","volume":"43","year":"2013","journal-title":"Prep. Biochem. Biotechnol."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"105591","DOI":"10.1016\/j.mssp.2020.105591","article-title":"Hydrothermal preparation of B\u2013TiO2-graphene oxide ternary nanocomposite, characterization and photocatalytic degradation of bisphenol A under simulated solar irradiation","volume":"123","author":"Altin","year":"2021","journal-title":"Mater. Sci. Semicond. Process."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"114720","DOI":"10.1016\/j.envres.2022.114720","article-title":"Performance and mechanism of a novel S-scheme heterojunction sonocatalyst CuS\/BaWO4 for degradation of bisphenol A by ultrasonic activation","volume":"216","author":"Liu","year":"2023","journal-title":"Environ. Res."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"117947","DOI":"10.1016\/j.envpol.2021.117947","article-title":"Biodegradation and photo-Fenton degradation of bisphenol A, bisphenol S and fluconazole in water","volume":"289","author":"Frankowski","year":"2021","journal-title":"Environ. Pollut."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"141883","DOI":"10.1016\/j.scitotenv.2020.141883","article-title":"Activation of peroxydisulfate by a novel Cu0-Cu2O@CNTs composite for 2,4-dichlorophenol degradation","volume":"754","author":"Liu","year":"2021","journal-title":"Sci. Total Environ."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"526","DOI":"10.1016\/j.jhazmat.2005.11.001","article-title":"Degradation of 2,4-dichlorophenol by using glow discharge electrolysis","volume":"136","author":"Lu","year":"2006","journal-title":"J. Hazard. Mater."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"125758","DOI":"10.1016\/j.chemosphere.2019.125758","article-title":"Emerging organic contaminants in wastewater: Understanding electrochemical reactors for triclosan and its by-products degradation","volume":"247","author":"Magro","year":"2020","journal-title":"Chemosphere"},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"125490","DOI":"10.1016\/j.chemosphere.2019.125490","article-title":"Insights into mechanisms of UV\/ferrate oxidation for degradation of phenolic pollutants: Role of superoxide radicals","volume":"244","author":"Wu","year":"2020","journal-title":"Chemosphere"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"129320","DOI":"10.1016\/j.chemosphere.2020.129320","article-title":"Photoelectrocatalytic degradation of 2,4-dichlorophenol in a TiO2 nanotube-coated disc flow reactor","volume":"268","author":"Alarcon","year":"2021","journal-title":"Chemosphere"},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"921","DOI":"10.1016\/j.chemosphere.2007.01.039","article-title":"Kinetics of 2,4-dichlorophenol and 4-Cl-m-cresol degradation by Pseudomonas sp. cultures in the presence of glucose","volume":"68","author":"Ziagova","year":"2007","journal-title":"Chemosphere"},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"383","DOI":"10.1016\/j.jhazmat.2008.06.102","article-title":"Co-metabolism of 2,4-dichlorophenol and 4-Cl-m-cresol in the presence of glucose as an easily assimilated carbon source by Staphylococcus xylosus","volume":"163","author":"Ziagova","year":"2009","journal-title":"J. Hazard. Mater."}],"container-title":["Sensors"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1424-8220\/23\/19\/8137\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T21:00:37Z","timestamp":1760130037000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1424-8220\/23\/19\/8137"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,9,28]]},"references-count":66,"journal-issue":{"issue":"19","published-online":{"date-parts":[[2023,10]]}},"alternative-id":["s23198137"],"URL":"https:\/\/doi.org\/10.3390\/s23198137","relation":{},"ISSN":["1424-8220"],"issn-type":[{"value":"1424-8220","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,9,28]]}}}