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The incorporation of natural pigments (e.g., xanthophylls and phycobiliproteins) is a fundamental step in a broad spectrum of applications that are presently marred by their limited stability. The incorporation of bio-based luminescent molecules into solid matrices allows the fabrication of thin films, which may dramatically increase the range of applications, including sustainable photovoltaic systems, such as luminescent solar concentrators or downshifting layers. In this work, we incorporated R-phycoerythrin (R-PE), C-phycocyanin (C-PC), and fucoxanthin (FX) into poly(vinyl alcohol) (PVA) and studied their optical properties. It was found that the emission and excitation spectra of the phycobiliproteins and FX were not modified by incorporation into the PVA matrix. Moreover, in the case of FX, the emission quantum yield (\u03b7) values also remained unaltered after incorporation, showing the suitability of the PVA as a host matrix. A preliminary photostability study was performed by exposing the solid samples to continuous AM1.5G solar radiation, which evidenced the potential of these materials for future photovoltaics.<\/jats:p>","DOI":"10.3390\/app12125839","type":"journal-article","created":{"date-parts":[[2022,6,9]],"date-time":"2022-06-09T10:49:14Z","timestamp":1654771754000},"page":"5839","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Uncovering the Use of Fucoxanthin and Phycobiliproteins into Solid Matrices to Increase Their Emission Quantum Yield and Photostability"],"prefix":"10.3390","volume":"12","author":[{"given":"L\u00edlia M. S.","family":"Dias","sequence":"first","affiliation":[{"name":"Department of Physics and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"given":"Gabriela","family":"Kovaleski","sequence":"additional","affiliation":[{"name":"Department of Physics and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"},{"name":"Department of Chemistry and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9887-371X","authenticated-orcid":false,"given":"Lianshe","family":"Fu","sequence":"additional","affiliation":[{"name":"Department of Physics and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"given":"T\u00e2nia R.","family":"Dias","sequence":"additional","affiliation":[{"name":"Department of Biology and CESAM\u2014Centre for Environmental and Marine Studies, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"given":"In\u00eas P. E.","family":"Mac\u00e1rio","sequence":"additional","affiliation":[{"name":"Department of Chemistry and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"},{"name":"Department of Biology and CESAM\u2014Centre for Environmental and Marine Studies, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6851-6041","authenticated-orcid":false,"given":"Sandra F. H.","family":"Correia","sequence":"additional","affiliation":[{"name":"Instituto de Telecomunica\u00e7\u00f5es and University of Aveiro, Campus Universit\u00e1rio de Santiago, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7573-6184","authenticated-orcid":false,"given":"Joana L.","family":"Pereira","sequence":"additional","affiliation":[{"name":"Department of Biology and CESAM\u2014Centre for Environmental and Marine Studies, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3841-743X","authenticated-orcid":false,"given":"Jo\u00e3o A. P.","family":"Coutinho","sequence":"additional","affiliation":[{"name":"Department of Chemistry and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9049-4267","authenticated-orcid":false,"given":"S\u00f3nia P. M.","family":"Ventura","sequence":"additional","affiliation":[{"name":"Department of Chemistry and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1085-7836","authenticated-orcid":false,"given":"Rute A. S.","family":"Ferreira","sequence":"additional","affiliation":[{"name":"Department of Physics and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,6,8]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"105","DOI":"10.1016\/j.mattod.2019.10.002","article-title":"Spectral converters for photovoltaics\u2014What\u2019s ahead","volume":"33","author":"Ferreira","year":"2020","journal-title":"Mater. 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