{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,17]],"date-time":"2026-04-17T06:11:33Z","timestamp":1776406293471,"version":"3.51.2"},"reference-count":101,"publisher":"MDPI AG","issue":"24","license":[{"start":{"date-parts":[[2025,12,18]],"date-time":"2025-12-18T00:00:00Z","timestamp":1766016000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"R&D unit MED\u2014Mediterranean Institute for Agriculture, Environment and Development"},{"name":"Associate Laboratory CHANGE\u2014Global Change and Sustainability Institute"},{"name":"Laborat\u00f3rio Associado para a Qu\u00edmica Verde\u201466 e Processos Limpos","award":["UIDB\/50006\/2020"],"award-info":[{"award-number":["UIDB\/50006\/2020"]}]},{"name":"Laborat\u00f3rio Associado para a Qu\u00edmica Verde\u201466 e Processos Limpos","award":["UIDP\/50006\/2020"],"award-info":[{"award-number":["UIDP\/50006\/2020"]}]},{"name":"Portuguese Foundation for Science and Technology (FCT) through FCT PhD grants","award":["SFRH\/BD\/146009\/2019"],"award-info":[{"award-number":["SFRH\/BD\/146009\/2019"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Applied Sciences"],"abstract":"<jats:p>Biocomposite films based on polylactic acid (PLA) reinforced with cellulose nanofibers (CNFs) extracted from Salicornia ramosissima by-products were developed and characterised using solvent casting (SC) and electrospinning (ES) techniques. The primary objective was to assess their suitability as sustainable food packaging materials that are compatible with high-pressure processing (HPP). The SC films exhibited a transparent, homogeneous morphology with superior ductility and water vapour barrier performance, whereas the ES films displayed a fibrous, porous structure with enhanced tensile strength and rigidity. The incorporation of CNFs significantly improved the mechanical properties, particularly the tensile strength and Young\u2019s modulus, with optimal reinforcement achieved at a loading of 0.5%. Thermal and spectroscopic analyses confirmed the effective integration of CNF without compromising the thermal stability of PLA. Pouch-type packages from CNF-reinforced SC films withstood industrial HPP conditions without rupture or leakage, demonstrating their technical feasibility for food packaging applications. This study presents the first demonstration of Salicornia ramosissima by-product valorisation for CNF production and its application in HPP-compatible food packaging, addressing both circular economy goals and emerging food processing technologies.<\/jats:p>","DOI":"10.3390\/app152413247","type":"journal-article","created":{"date-parts":[[2025,12,18]],"date-time":"2025-12-18T09:15:21Z","timestamp":1766049321000},"page":"13247","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["PLA-Based Films Reinforced with Cellulose Nanofibres from Salicornia ramosissima By-Product with Proof of Concept in High-Pressure Processing"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-7983-518X","authenticated-orcid":false,"given":"Alexandre R.","family":"Lima","sequence":"first","affiliation":[{"name":"MED\u2014Mediterranean Institute for Agriculture, Environment and Development & CHANGE\u2014Global Change and Sustainability Institute, Faculty of Sciences and Technology, Campus de Gambelas, Universidade do Algarve, 8005-139 Faro, Portugal"},{"name":"LAQV\u2013REQUIMTE\u2014Associated Laboratory for Green Chemistry of the Network of Chemistry and Technology, Department of Chemistry, Universidade de Aveiro, 3810-193 Aveiro, Portugal"},{"name":"GreenCoLab\u2014Associa\u00e7\u00e3o Oceano Verde, Universidade do Algarve, 8005-139 Faro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0919-517X","authenticated-orcid":false,"given":"Nathana L.","family":"Cristofoli","sequence":"additional","affiliation":[{"name":"MED\u2014Mediterranean Institute for Agriculture, Environment and Development & CHANGE\u2014Global Change and Sustainability Institute, Faculty of Sciences and Technology, Campus de Gambelas, Universidade do Algarve, 8005-139 Faro, Portugal"}]},{"given":"In\u00e8s","family":"Delahousse","sequence":"additional","affiliation":[{"name":"L\u2019Institut Agro Dijon, Universit\u00e9 Bourgogne Franche Comt\u00e9, 26 Bd Docteur Petitjean\u2014BP 87999, 21079 Dijon, France"}]},{"given":"Renata A.","family":"Amaral","sequence":"additional","affiliation":[{"name":"LAQV\u2013REQUIMTE\u2014Associated Laboratory for Green Chemistry of the Network of Chemistry and Technology, Department of Chemistry, Universidade de Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5536-6056","authenticated-orcid":false,"given":"Jorge A.","family":"Saraiva","sequence":"additional","affiliation":[{"name":"LAQV\u2013REQUIMTE\u2014Associated Laboratory for Green Chemistry of the Network of Chemistry and Technology, Department of Chemistry, Universidade de Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2774-706X","authenticated-orcid":false,"given":"Margarida C.","family":"Vieira","sequence":"additional","affiliation":[{"name":"MED\u2014Mediterranean Institute for Agriculture, Environment and Development & CHANGE\u2014Global Change and Sustainability Institute, Faculty of Sciences and Technology, Campus de Gambelas, Universidade do Algarve, 8005-139 Faro, Portugal"},{"name":"ISE\u2014High Institute of Engineering, Department of Food Engineering, Campus da Penha, Universidade do Algarve, 8000-139 Faro, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2025,12,18]]},"reference":[{"key":"ref_1","unstructured":"European Parliament (2025). Regulation (EU) 2025\/40 of the European Parliament and the Council of 19 December 2024 on Packaging and Packaging Waste, Amending Regulation (EU) 2019\/1020 and Directive (EU) 2019\/904, and Repealing Directive 94\/62\/EC, Publications Office of the European Union."},{"key":"ref_2","unstructured":"(2025, December 07). United Nations Transforming Our World: The 2030 Agenda for Sustainable Development. Available online: https:\/\/sustainabledevelopment.un.org\/post2015\/transformingourworld."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"255","DOI":"10.1002\/pts.2868","article-title":"Environmental Sustainability, Food Quality and Convertibility of Bio-Based Barrier Coatings for Fibre-Based Food Packaging: A Semisystematic Review","volume":"38","author":"Vinitskaia","year":"2024","journal-title":"Packg. Techn. and Sci."},{"key":"ref_4","doi-asserted-by":"crossref","unstructured":"Cristofoli, N.L., Lima, A.R., Tchonkouang, R.D.N., Quintino, A.C., and Vieira, M.C. (2023). Advances in the Food Packaging Production from Agri-Food Waste and By-Products: Market Trends for a Sustainable Development. Sustainability, 15.","DOI":"10.3390\/su15076153"},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"327","DOI":"10.1016\/j.carbpol.2018.03.023","article-title":"Cellulose Nanocrystals from Grape Pomace: Production, Properties and Cytotoxicity Assessment","volume":"192","author":"Coelho","year":"2018","journal-title":"Carbohydr. Polym."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"214","DOI":"10.1016\/j.fbp.2022.11.012","article-title":"Comparative Study of the Production of Cellulose Nanofibers from Agro-Industrial Waste Streams of Salicornia Ramosissima by Acid and Enzymatic Treatment","volume":"137","author":"Lima","year":"2023","journal-title":"Food and Bioprod. Process."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"192","DOI":"10.1016\/j.foodhyd.2017.08.027","article-title":"Cellulose Nanofibers Produced from Banana Peel by Chemical and Mechanical Treatments: Characterization and Cytotoxicity Assessment","volume":"75","author":"Tibolla","year":"2018","journal-title":"Food Hydrocoll."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"53","DOI":"10.1016\/j.carbpol.2019.05.053","article-title":"Extraction and Characterization of Cellulose Nanofibers from Rose Stems (Rosa Spp.)","volume":"220","author":"Tecante","year":"2019","journal-title":"Carbohydr. Polym."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"22","DOI":"10.1177\/00952443211017169","article-title":"The Effect of Nanocellulose on Mechanical and Physical Properties of Chitosan-Based Biocomposites","volume":"54","author":"Talebi","year":"2022","journal-title":"J. Elast. Plast."},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Zhao, L., Duan, G., Zhang, G., Yang, H., Jiang, S., and He, S. (2020). Electrospun Functional Materials toward Food Packaging Applications: A Review. Nanomaterials, 10.","DOI":"10.3390\/nano10010150"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"3450","DOI":"10.1007\/s11694-023-01890-z","article-title":"An Electrospun Polylactic Acid Film Containing Silver Nanoparticles and Encapsulated Thymus Daenensis Essential Oil: Release Behavior, Physico-Mechanical and Antibacterial Studies","volume":"17","author":"Bamian","year":"2023","journal-title":"J. Food Meas. Charact."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"313","DOI":"10.7569\/JRM.2016.634115","article-title":"Opportunities for Cellulose Nanomaterials in Packaging Films: A Review and Future Trends","volume":"4","author":"Stark","year":"2016","journal-title":"J. Renew Mater."},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Blanco, A., Monte, M.C., Campano, C., Balea, A., Merayo, N., and Negro, C. (2018). Nanocellulose for Industrial Use: Cellulose Nanofibers (CNF), Cellulose Nanocrystals (CNC), and Bacterial Cellulose (BC), Elsevier Inc.","DOI":"10.1016\/B978-0-12-813351-4.00005-5"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"382","DOI":"10.1016\/j.aiepr.2023.02.002","article-title":"PLA Based Biocomposites for Sustainable Products: A Review","volume":"6","author":"Trivedi","year":"2023","journal-title":"Advan. Indust, and Eng. Polym. Resear."},{"key":"ref_15","doi-asserted-by":"crossref","unstructured":"Rezvani Ghomi, E., Khosravi, F., Saedi Ardahaei, A., Dai, Y., Neisiany, R.E., Foroughi, F., Wu, M., Das, O., and Ramakrishna, S. (2021). The Life Cycle Assessment for Polylactic Acid (PLA) to Make It a Low-Carbon Material. Polymers, 13.","DOI":"10.3390\/polym13111854"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"145132","DOI":"10.1016\/j.jclepro.2025.145132","article-title":"Environmental Footprint of Polylactic Acid Production Utilizing Cane-Sugar and Microalgal Biomass: An LCA Case Study","volume":"496","author":"Islam","year":"2025","journal-title":"J. Clean. Prod."},{"key":"ref_17","doi-asserted-by":"crossref","unstructured":"Hussain, M., Khan, S.M., Shafiq, M., and Abbas, N. (2024). A Review on PLA-Based Biodegradable Materials for Biomedical Applications. Giant., 18.","DOI":"10.1016\/j.giant.2024.100261"},{"key":"ref_18","unstructured":"(2025, April 29). Grand View Research Polylactic Acid Market Size & Trends. Available online: https:\/\/www.grandviewresearch.com\/industry-analysis\/polylactic-acid-pla-market."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"485","DOI":"10.1016\/j.jmrt.2022.02.072","article-title":"Thermal and Mechanical Properties of PLA-Based Multiscale Cellulosic Biocomposites","volume":"18","year":"2022","journal-title":"J. Mater. Resear. Tech."},{"key":"ref_20","doi-asserted-by":"crossref","unstructured":"Ren, Q., Wu, M., Wang, L., Zheng, W., Hikima, Y., Semba, T., and Ohshima, M. (2022). Cellulose Nanofiber Reinforced Poly (Lactic Acid) with Enhanced Rheology, Crystallization and Foaming Ability. Carbohydr. Polym., 286.","DOI":"10.1016\/j.carbpol.2022.119320"},{"key":"ref_21","doi-asserted-by":"crossref","unstructured":"Plamadiala, I., Croitoru, C., Pop, M.A., and Roata, I.C. (2025). Enhancing Polylactic Acid (PLA) Performance: A Review of Additives in Fused Deposition Modelling (FDM) Filaments. Polymers, 17.","DOI":"10.3390\/polym17020191"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"5298","DOI":"10.1021\/acs.chemrev.8b00593","article-title":"Electrospinning and Electrospun Nanofibers: Methods, Materials, and Applications","volume":"119","author":"Xue","year":"2019","journal-title":"Chem. Rev."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"285","DOI":"10.1016\/j.ijpharm.2017.11.021","article-title":"Orodispersible Films: Product Transfer from Lab-Scale to Continuous Manufacturing","volume":"535","author":"Thabet","year":"2018","journal-title":"Int. J. Pharm."},{"key":"ref_24","unstructured":"Salit, M., Jawaid, M., Yusoff, N., and Hoque, M. Manufacturing of Natural Fibre-Reinforced Polymer Composites by Solvent Casting Method. Manufacturing of Natural Fibre Reinforced Polymer Composites, Springer."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"107074","DOI":"10.1016\/j.compositesb.2019.107074","article-title":"A Comprehensive Review of Electrospun Nanofibers: Food and Packaging Perspective","volume":"175","author":"Rajini","year":"2019","journal-title":"Compos. B Eng."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"105156","DOI":"10.1016\/j.jddst.2023.105156","article-title":"Electrospun Nanofibers: Exploring Process Parameters, Polymer Selection, and Recent Applications in Pharmaceuticals and Drug Delivery","volume":"90","author":"Abdulhussain","year":"2023","journal-title":"J. Drug Deliv. Sci. Technol."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"3130","DOI":"10.1002\/app.31396","article-title":"The Influence of Electrospinning Parameters on the Structural Morphology and Diameter of Electrospun Nanofibers","volume":"115","author":"Jacobs","year":"2009","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_28","doi-asserted-by":"crossref","unstructured":"Maduna, L., and Patnaik, A. (2024). Challenges Associated with the Production of Nanofibers. Processes, 12.","DOI":"10.3390\/pr12102100"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"5058","DOI":"10.1038\/s41598-018-23378-3","article-title":"Electrospinning over Solvent Casting: Tuning of Mechanical Properties of Membranes","volume":"8","author":"Ghosal","year":"2018","journal-title":"Sci. Rep."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1266","DOI":"10.1039\/D4FB00147H","article-title":"Electrospinning of Sustainable Polymers from Biomass for Active Food Packaging","volume":"2","author":"Topuz","year":"2024","journal-title":"Sustain. Food Technol."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"11129","DOI":"10.1021\/acsomega.3c09564","article-title":"Biodegradable Electrospun Membranes for Sustainable Industrial Applications","volume":"9","author":"Borah","year":"2024","journal-title":"ACS Omega"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"429","DOI":"10.1007\/s42765-022-00237-5","article-title":"A Review on Electrospinning as Versatile Supports for Diverse Nanofibers and Their Applications in Environmental Sensing","volume":"5","author":"Song","year":"2023","journal-title":"Adv. Fiber Mater."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"e70190","DOI":"10.1002\/fsn3.70190","article-title":"Eco-Friendly and Smart Electrospun Food Packaging Films Based on Polyvinyl Alcohol and Sumac Extract: Physicochemical, Mechanical, Antibacterial, and Antioxidant Properties","volume":"13","author":"Shiri","year":"2025","journal-title":"Food Sci. Nutr."},{"key":"ref_34","doi-asserted-by":"crossref","unstructured":"Melendez-Rodriguez, B., Castro-Mayorga, J.L., Reis, M.A.M., Sammon, C., Cabedo, L., Torres-Giner, S., and Lagaron, J.M. (2018). Preparation and Characterization of Electrospun Food Biopackaging Films of Poly(3-Hydroxybutyrate-Co-3-Hydroxyvalerate) Derived From Fruit Pulp Biowaste. Front. Sustain. Food Syst., 2.","DOI":"10.3389\/fsufs.2018.00038"},{"key":"ref_35","first-page":"e07128","article-title":"The Efficacy and Safety of High-Pressure Processing of Food","volume":"20","author":"Koutsoumanis","year":"2022","journal-title":"EFSA J."},{"key":"ref_36","doi-asserted-by":"crossref","unstructured":"Garcia-Vaquero, M., and Rajauria, G. (2022). High-Pressure Processing for Food Preservation. Innovative and Emerging Technologies in the Bio-Marine Food Sector-Applications, Regulations, and Prospects, Academic Press.","DOI":"10.1016\/B978-0-12-820096-4.00021-3"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"109516","DOI":"10.1016\/j.foodcont.2022.109516","article-title":"Influence of High Pressure Pasteurization on Nutritional, Functional and Rheological Characteristics of Fruit and Vegetable Juices and Purees-an Updated Review","volume":"146","author":"Ravichandran","year":"2023","journal-title":"Food Control"},{"key":"ref_38","doi-asserted-by":"crossref","unstructured":"Machado, F., Duarte, R.V., Pinto, C.A., Casal, S., Lopes-da-Silva, J.A., and Saraiva, J.A. (2023). High Pressure and Pasteurization Effects on Dairy Cream. Foods, 12.","DOI":"10.3390\/foods12193640"},{"key":"ref_39","doi-asserted-by":"crossref","unstructured":"Scepankova, H., Majtan, J., Estevinho, L.M., and Saraiva, J.A. (2024). The High Pressure Preservation of Honey: A Comparative Study on Quality Changes during Storage. Foods, 13.","DOI":"10.3390\/foods13070989"},{"key":"ref_40","unstructured":"(2018). Standard Test Method For Tensile Properties of Thin Plastic Sheeting (Standard No. ASTM D882-18)."},{"key":"ref_41","unstructured":"(2016). Standard Test Methods for Water Vapor Transmission of Materials (Standard No. ASTM E96\/E96M-15)."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"614","DOI":"10.1016\/j.ijbiomac.2021.04.143","article-title":"Nopal Cladode as a Novel Reinforcing and Antioxidant Agent for Starch-Based Films: A Comparison with Lignin and Propolis Extract","volume":"183","year":"2021","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_43","unstructured":"(2021). Standard Test Method for Thermal Stability by Thermogravimetry (Standard No. ASTM E2550-21)."},{"key":"ref_44","doi-asserted-by":"crossref","unstructured":"Liu, Y., Liang, X., Wang, S., Qin, W., and Zhang, Q. (2018). Electrospun Antimicrobial Polylactic Acid\/Tea Polyphenol Nanofibers For. Polymers, 10.","DOI":"10.3390\/polym10050561"},{"key":"ref_45","doi-asserted-by":"crossref","unstructured":"Chen, Z., Guan, M., Bian, Y., and Yin, X. (2024). Multifunctional Electrospun Nanofibers for Biosensing and Biomedical Engineering Applications. Biosensors, 14.","DOI":"10.3390\/bios14010013"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"4751","DOI":"10.2174\/138161206779026326","article-title":"The Role of Electrospinning in the Emerging Field of Nanomedicine","volume":"12","author":"Chew","year":"2006","journal-title":"Curr. Pharm. Des."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1016\/j.nanoms.2020.11.003","article-title":"Nano Materials Science Hierarchically Electrospun Nano Fi Bers and Their Applications: A Review","volume":"3","author":"Badmus","year":"2021","journal-title":"Nano Mater. Sci."},{"key":"ref_48","first-page":"1851","article-title":"Effects of Solvents on Electrospun Polymeric Fibers: Preliminary Study on Polystyrene","volume":"1859","author":"Wannatong","year":"2004","journal-title":"Polym. Sci."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"81","DOI":"10.1016\/j.carbpol.2017.01.016","article-title":"Preparation and Characterization of Chitosan Film Incorporated with Thinned Young Apple Polyphenols as an Active Packaging Material","volume":"163","author":"Sun","year":"2017","journal-title":"Carbohydr. Polym."},{"key":"ref_50","doi-asserted-by":"crossref","unstructured":"Xiao, Y., Luo, H., Tang, R., and Hou, J. (2021). Preparation and Applications of Electrospun Optically Transparent Fibrous Membrane. Polymers, 13.","DOI":"10.3390\/polym13040506"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"50302","DOI":"10.1002\/app.50302","article-title":"Polylactide Films Produced with Bixin and Acetyl Tributyl Citrate: Functional Properties for Active Packaging","volume":"138","author":"Stoll","year":"2020","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"367","DOI":"10.1016\/j.addr.2016.06.012","article-title":"Physical and Mechanical Properties of PLA, and Their Functions in Widespread Applications\u2014A Comprehensive Review","volume":"107","author":"Farah","year":"2016","journal-title":"Adv. Drug Deliv. Rev."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"147","DOI":"10.1163\/156856299X00108","article-title":"Parameters Affecting Cellular Adhesion to Polylactide Films","volume":"10","author":"Burg","year":"1999","journal-title":"J. Biomater. Sci. Polym. Ed."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.addr.2016.04.003","article-title":"PLA Composites: From Production to Properties","volume":"107","author":"Murariu","year":"2016","journal-title":"Adv. Drug Deliv. Rev."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"188","DOI":"10.1016\/j.matdes.2017.11.012","article-title":"Toughening of Nanocelluose\/PLA Composites via Bio-Epoxy Interaction: Mechanistic Study","volume":"139","author":"Meng","year":"2018","journal-title":"Mater. Des."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"e24692","DOI":"10.1016\/j.heliyon.2024.e24692","article-title":"Nanotechnology-Enhanced Fiber-Reinforced Polymer Composites: Recent Advancements on Processing Techniques and Applications","volume":"10","author":"Haque","year":"2024","journal-title":"Heliyon"},{"key":"ref_57","doi-asserted-by":"crossref","unstructured":"Jamr\u00f3z, E., Kulawik, P., and Kopel, P. (2019). The Effect of Nanofillers on the Functional Properties of Biopolymer-Based Films: A Review. Polymers, 11.","DOI":"10.3390\/polym11040675"},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"23819","DOI":"10.1038\/s41598-024-71619-5","article-title":"PLA Based Biodegradable Bionanocomposite Filaments Reinforced with Nanocellulose: Development and Analysis of Properties","volume":"14","author":"Trivedi","year":"2024","journal-title":"Sci. Rep."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"111531","DOI":"10.1016\/j.mtcomm.2025.111531","article-title":"Synergistic Enhancement of PLA\/PHA Bio-Based Films Using Tempo-Oxidized Cellulose Nanofibers, Graphene Oxide, and Clove Oil for Sustainable Packaging","volume":"42","author":"Mazaheri","year":"2025","journal-title":"Mater. Today Commun."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"139836","DOI":"10.1016\/j.ijbiomac.2025.139836","article-title":"Role of Silane Compatibilization on Cellulose Nanofiber Reinforced Poly (Lactic Acid) (PLA) Composites with Superior Mechanical Properties, Thermal Stability, and Tunable Degradation Rates","volume":"297","author":"Guo","year":"2025","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"22","DOI":"10.1016\/j.carbpol.2013.11.052","article-title":"Effect of Silver Nanoparticles and Cellulose Nanocrystals on Electrospun Poly(Lactic) Acid Mats: Morphology, Thermal Properties and Mechanical Behavior","volume":"103","author":"Cacciotti","year":"2014","journal-title":"Carbohydr. Polym."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"1742","DOI":"10.1016\/j.compscitech.2010.07.005","article-title":"Mechanical Properties of Cellulose Nanofiber (CNF) Reinforced Polylactic Acid (PLA) Prepared by Twin Screw Extrusion","volume":"70","author":"Jonoobi","year":"2010","journal-title":"Compos. Sci. Technol."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"109048","DOI":"10.1016\/j.compositesb.2021.109048","article-title":"Constructing Robust Chain Entanglement Network, Well-Defined Nanosized Crystals and Highly Aligned Graphene Oxide Nanosheets: Towards Strong, Ductile and High Barrier Poly(Lactic Acid) Nanocomposite Films for Green Packaging","volume":"222","author":"Xu","year":"2021","journal-title":"Compos. B Eng."},{"key":"ref_64","doi-asserted-by":"crossref","unstructured":"Weng, Q.H., Hu, M.H., Wang, J.F., and Hu, J.J. (2025). Enhancing the Flexibility and Hydrophilicity of PLA via Polymer Blends: Electrospinning vs. Solvent Casting. Polymers, 17.","DOI":"10.3390\/polym17060800"},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"2103","DOI":"10.1016\/j.compscitech.2008.03.006","article-title":"Cellulose Nanofiber-Reinforced Polylactic Acid","volume":"68","author":"Iwatake","year":"2008","journal-title":"Compos. Sci. Technol."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"1248","DOI":"10.1007\/s42452-019-1288-4","article-title":"A Review on Fabrication of Nanofibers via Electrospinning and Their Applications","volume":"1","author":"Islam","year":"2019","journal-title":"SN Appl. Sci."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"169","DOI":"10.1016\/j.actbio.2018.09.055","article-title":"Correlating Diameter, Mechanical and Structural Properties of Poly(L-Lactide) Fibres from Needleless Electrospinning","volume":"81","author":"Morel","year":"2018","journal-title":"Acta Biomater."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"50","DOI":"10.1038\/s41598-023-50298-8","article-title":"Water Vapor Transport Properties of Bio-Based Multilayer Materials Determined by Original and Complementary Methods","volume":"14","author":"Guivier","year":"2024","journal-title":"Sci. Rep."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1021\/acssuschemeng.7b03523","article-title":"Moisture and Oxygen Barrier Properties of Cellulose Nanomaterial-Based Films","volume":"6","author":"Wang","year":"2018","journal-title":"ACS Sustain. Chem. Eng."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"113417","DOI":"10.1016\/j.matdes.2024.113417","article-title":"Current Advances in Processing and Modification of Cellulose Nanofibrils for High-Performance Composite Applications","volume":"247","author":"Oesef","year":"2024","journal-title":"Mater. Des."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"1925","DOI":"10.1021\/acs.chemrev.2c00611","article-title":"Understanding Nanocellulose-Water Interactions: Turning a Detriment into an Asset","volume":"123","author":"Solhi","year":"2023","journal-title":"Chem. Rev."},{"key":"ref_72","doi-asserted-by":"crossref","unstructured":"Esakkimuthu, E.S., Ponnuchamy, V., Sipponen, M.H., and DeVallance, D. (2024). Elucidating Intermolecular Forces to Improve Compatibility of Kraft Lignin in Poly(Lactic Acid). Front. Chem., 12.","DOI":"10.3389\/fchem.2024.1347147"},{"key":"ref_73","doi-asserted-by":"crossref","unstructured":"Bikiaris, N.D., Koumentakou, I., Samiotaki, C., Meimaroglou, D., Varytimidou, D., Karatza, A., Kalantzis, Z., Roussou, M., Bikiaris, R.D., and Papageorgiou, G.Z. (2023). Recent Advances in the Investigation of Poly(Lactic Acid) (PLA) Nanocomposites: Incorporation of Various Nanofillers and Their Properties and Applications. Polymers, 15.","DOI":"10.3390\/polym15051196"},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"26159","DOI":"10.1021\/acsomega.4c01594","article-title":"Preparation of High-Toughness Cellulose Nanofiber\/Polylactic Acid Bionanocomposite Films via Gel-like Cellulose Nanofibers","volume":"9","author":"Keeratipinit","year":"2024","journal-title":"ACS Omega"},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"6449","DOI":"10.1007\/s10570-021-03937-0","article-title":"Mechanical Enhancement of Cellulose Nanofibril (CNF) Films through the Addition of Water-Soluble Polymers","volume":"28","author":"Forti","year":"2021","journal-title":"Cellulose"},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"4241","DOI":"10.1002\/app.38022","article-title":"A Comparative Study on Curing Characteristics and Thermomechanical Properties of Elastomeric Nanocomposites: The Effects of Eggshell and Calcium Carbonate Nanofillers","volume":"127","author":"Saeb","year":"2013","journal-title":"J. Appl. Polym. Sci."},{"key":"ref_77","doi-asserted-by":"crossref","unstructured":"Abdullah, J.A.A., Ben\u00edtez, J.J., Guerrero, A., and Romero, A. (2023). Sustainable Integration of Zinc Oxide Nanoparticles: Enhancing Properties of Poly(\u03b5-Caprolactone) Electrospun Nanofibers and Cast Films. Coatings, 13.","DOI":"10.3390\/coatings13101665"},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"100363","DOI":"10.1016\/j.fpsl.2019.100363","article-title":"Effect of Melanin Nanoparticles on the Mechanical, Water Vapor Barrier, and Antioxidant Properties of Gelatin-Based Films for Food Packaging Application","volume":"21","author":"Shankar","year":"2019","journal-title":"Food Packag. Shelf Life"},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1016\/j.jfoodeng.2018.09.002","article-title":"External Factors and Nanoparticles Effect on Water Vapor Permeability of Pectin-Based Films","volume":"245","year":"2019","journal-title":"J. Food Eng."},{"key":"ref_80","doi-asserted-by":"crossref","unstructured":"Argel-P\u00e9rez, S., Vel\u00e1squez-Cock, J., Zuluaga, R., and G\u00f3mez-Hoyos, C. (2024). Improving Hydrophobicity and Water Vapor Barrier Properties in Paper Using Cellulose Nanofiber-Stabilized Cocoa Butter and PLA Emulsions. Coatings, 14.","DOI":"10.3390\/coatings14101310"},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"324","DOI":"10.1016\/j.foodhyd.2017.08.023","article-title":"Characterization of Gelatin\/Zein Films Fabricated by Electrospinning vs Solvent Casting","volume":"74","author":"Deng","year":"2018","journal-title":"Food Hydrocoll."},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"241","DOI":"10.1016\/j.ijbiomac.2021.02.105","article-title":"Active Natural-Based Films for Food Packaging Applications: The Combined Effect of Chitosan and Nanocellulose","volume":"177","author":"Costa","year":"2021","journal-title":"Int. J. Biol. Macromol."},{"key":"ref_83","doi-asserted-by":"crossref","unstructured":"Zhang, Y., Liu, C., Wu, M., Li, Z., and Li, B. (2022). Impact of the Incorporation of Nano-Sized Cellulose Formate on the End Quality of Polylactic Acid Composite Film. Nanomaterials, 12.","DOI":"10.3390\/nano12010001"},{"key":"ref_84","doi-asserted-by":"crossref","unstructured":"Wang, C., Wang, J., Zeng, L., Qiao, Z., Liu, X., Liu, H., Zhang, J., and Ding, J. (2019). Fabrication of Electrospun Polymer Nanofibers with Diverse Morphologies. Molecules, 24.","DOI":"10.3390\/molecules24050834"},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"138205","DOI":"10.1016\/j.matlet.2025.138205","article-title":"Biodegradable PLA\/TPU Blends with Improved Mechanical Properties","volume":"387","author":"Zhang","year":"2025","journal-title":"Mater. Lett."},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"132917","DOI":"10.1016\/j.energy.2024.132917","article-title":"Comparative Study of PLA Composites Reinforced with Graphene Nanoplatelets, Graphene Oxides, and Carbon Nanotubes: Mechanical and Degradation Evaluation","volume":"308","author":"Hussain","year":"2024","journal-title":"Energy"},{"key":"ref_87","doi-asserted-by":"crossref","first-page":"102103","DOI":"10.1016\/j.coco.2024.102103","article-title":"Physical, Mechanical and Thermal Properties of Novel Bamboo\/Kenaf Fiber-Reinforced Polylactic Acid (PLA) Hybrid Composites","volume":"51","author":"Khan","year":"2024","journal-title":"Compos. Commun."},{"key":"ref_88","doi-asserted-by":"crossref","first-page":"23","DOI":"10.1016\/j.compositesa.2018.02.026","article-title":"Properties-Morphology Relationships in Electrospun Mats Based on Polylactic Acid and Graphene Nanoplatelets","volume":"108","author":"Scaffaro","year":"2018","journal-title":"Compos. Part A Appl. Sci. Manuf."},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"2352","DOI":"10.1002\/pat.5264","article-title":"Interfacial Improvements in Cellulose Nanofibers Reinforced Polylactide Bionanocomposites Prepared by in Situ Reactive Extrusion","volume":"32","author":"Li","year":"2021","journal-title":"Polym. Adv. Technol."},{"key":"ref_90","doi-asserted-by":"crossref","first-page":"1037","DOI":"10.1021\/acs.biomac.8b00023","article-title":"Electrospun Poly(Lactic Acid)-Based Fibrous Nanocomposite Reinforced by Cellulose Nanocrystals: Impact of Fiber Uniaxial Alignment on Microstructure and Mechanical Properties","volume":"19","author":"Huan","year":"2018","journal-title":"Biomacromolecules"},{"key":"ref_91","doi-asserted-by":"crossref","first-page":"948","DOI":"10.1016\/j.carbpol.2012.06.025","article-title":"Effects of Modified Cellulose Nanocrystals on the Barrier and Migration Properties of PLA Nano-Biocomposites","volume":"90","author":"Fortunati","year":"2012","journal-title":"Carbohydr. Polym."},{"key":"ref_92","doi-asserted-by":"crossref","unstructured":"Lafia-Araga, R.A., Sabo, R., Nabinejad, O., Matuana, L., and Stark, N. (2021). Influence of Lactic Acid Surface Modification of Cellulose Nanofibrils on the Properties of Cellulose Nanofibril Films and Cellulose Nanofibril\u2013Poly (Lactic Acid) Composites. Biomolecules, 11.","DOI":"10.3390\/biom11091346"},{"key":"ref_93","doi-asserted-by":"crossref","first-page":"1568725","DOI":"10.1080\/23311932.2019.1568725","article-title":"Review on High-Pressure Processing of Foods","volume":"5","author":"Abera","year":"2019","journal-title":"Cogent. Food Agric."},{"key":"ref_94","first-page":"377","article-title":"High Pressure Processing in Food Industry\u2013Characteristics and Applications","volume":"10","author":"Muntean","year":"2016","journal-title":"Agric. Agric. Sci. Procedia"},{"key":"ref_95","doi-asserted-by":"crossref","first-page":"3225","DOI":"10.1111\/1541-4337.12763","article-title":"Aspects of High Hydrostatic Pressure Food Processing: Perspectives on Technology and Food Safety","volume":"20","author":"Aganovic","year":"2021","journal-title":"Compr. Rev. Food Sci. Food Saf."},{"key":"ref_96","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/j.ifset.2004.09.002","article-title":"Effect of High Pressure Treatments on the Properties of EVOH-Based Food Packaging Materials","volume":"6","author":"Almenar","year":"2005","journal-title":"Innov. Food Sci. Emerg. Technol."},{"key":"ref_97","doi-asserted-by":"crossref","unstructured":"Muller, J., Gonz\u00e1lez-Mart\u00ednez, C., and Chiralt, A. (2017). Combination Of Poly(Lactic) Acid and Starch for Biodegradable Food Packaging. Materials, 10.","DOI":"10.3390\/ma10080952"},{"key":"ref_98","doi-asserted-by":"crossref","first-page":"735","DOI":"10.1016\/j.carbpol.2012.05.026","article-title":"Microfibrillated Cellulose-Its Barrier Properties and Applications in Cellulosic Materials: A Review","volume":"90","author":"Lavoine","year":"2012","journal-title":"Carbohydr. Polym."},{"key":"ref_99","doi-asserted-by":"crossref","first-page":"73","DOI":"10.1016\/j.polymertesting.2014.03.002","article-title":"Preparation and Characterization of Modified Celllose Nanofibers Reinforced Polylactic Acid Nanocomposite","volume":"35","author":"Abdulkhani","year":"2014","journal-title":"Polym. Test."},{"key":"ref_100","doi-asserted-by":"crossref","first-page":"35","DOI":"10.1016\/j.jfca.2017.02.003","article-title":"Halophytes: Gourmet Food with Nutritional Health Benefits?","volume":"59","author":"Barreira","year":"2017","journal-title":"J. Food Comp. Anal."},{"key":"ref_101","doi-asserted-by":"crossref","first-page":"127525","DOI":"10.1016\/j.foodchem.2020.127525","article-title":"Influence of Cultivation Salinity in the Nutritional Composition, Antioxidant Capacity and Microbial Quality of Salicornia Ramosissima Commercially Produced in Soilless Systems","volume":"333","author":"Lima","year":"2020","journal-title":"Food. Chem."}],"container-title":["Applied Sciences"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2076-3417\/15\/24\/13247\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,12,18]],"date-time":"2025-12-18T09:46:16Z","timestamp":1766051176000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2076-3417\/15\/24\/13247"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,12,18]]},"references-count":101,"journal-issue":{"issue":"24","published-online":{"date-parts":[[2025,12]]}},"alternative-id":["app152413247"],"URL":"https:\/\/doi.org\/10.3390\/app152413247","relation":{},"ISSN":["2076-3417"],"issn-type":[{"value":"2076-3417","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,12,18]]}}}