{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T11:56:10Z","timestamp":1774526170792,"version":"3.50.1"},"reference-count":45,"publisher":"MDPI AG","issue":"4","license":[{"start":{"date-parts":[[2021,11,11]],"date-time":"2021-11-11T00:00:00Z","timestamp":1636588800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100009027","name":"Advanced Low Carbon Technology Research and Development Program","doi-asserted-by":"publisher","award":["FY2016"],"award-info":[{"award-number":["FY2016"]}],"id":[{"id":"10.13039\/501100009027","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100005278","name":"Universidad de Antioquia","doi-asserted-by":"publisher","award":["1115-745-58653"],"award-info":[{"award-number":["1115-745-58653"]}],"id":[{"id":"10.13039\/501100005278","id-type":"DOI","asserted-by":"publisher"}]},{"name":"TRONEX S.A.S","award":["FP44842-13-2017"],"award-info":[{"award-number":["FP44842-13-2017"]}]},{"name":"Colombian Ministry of Science","award":["1115-745-58653"],"award-info":[{"award-number":["1115-745-58653"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Batteries"],"abstract":"<jats:p>All-solid-state batteries (ASSBs) are a promising response to the need for safety and high energy density of large-scale energy storage systems in challenging applications such as electric vehicles and grid integration. ASSBs based on sulfide solid electrolytes (SEs) have attracted much attention because of their high ionic conductivity and wide electrochemical windows of the sulfide SEs. Here, we study the electrochemical performance of ASSBs using composite electrodes prepared via two processes (simple mixture and solution processes) and varying the ionic conductor additive (80Li2S\u221920P2S5 and argyrodite-type Li6PS5Cl). The composite electrodes consist of lithium-silicate-coated LiNi1\/3Mn1\/3Co1\/3O2 (NMC), a sulfide SE, and carbon additives. The charge-transfer resistance at the interface of the solid electrolyte and NMC is the main parameter related to the ASSB\u2019s status. This value decreases when the composite electrodes are prepared via a solution process. The lithium silicate coating and the use of a high-Li-ion additive conductor are also important to reduce the interfacial resistance and achieve high initial capacities (140 mAh g\u22121).<\/jats:p>","DOI":"10.3390\/batteries7040077","type":"journal-article","created":{"date-parts":[[2021,11,11]],"date-time":"2021-11-11T23:02:41Z","timestamp":1636671761000},"page":"77","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":16,"title":["Preparation of Composite Electrodes for All-Solid-State Batteries Based on Sulfide Electrolytes: An Electrochemical Point of View"],"prefix":"10.3390","volume":"7","author":[{"given":"Sara","family":"Giraldo","sequence":"first","affiliation":[{"name":"Centro de Investigaci\u00f3n, Innovaci\u00f3n y Desarrollo de Materiales (CIDEMAT), Universidad de Antioquia, Street 70 # 52-21, Medell\u00edn 050010, Colombia"}]},{"given":"Koki","family":"Nakagawa","sequence":"additional","affiliation":[{"name":"Graduate School of Chemical Science and Engineering, Hokkaido University, Kita 13, Nishi 8, Sapporo 060-8628, Japan"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5011-1858","authenticated-orcid":false,"given":"Ferley A.","family":"V\u00e1squez","sequence":"additional","affiliation":[{"name":"Centro de Investigaci\u00f3n, Innovaci\u00f3n y Desarrollo de Materiales (CIDEMAT), Universidad de Antioquia, Street 70 # 52-21, Medell\u00edn 050010, Colombia"}]},{"given":"Yuta","family":"Fujii","sequence":"additional","affiliation":[{"name":"Graduate School of Chemical Science and Engineering, Hokkaido University, Kita 13, Nishi 8, Sapporo 060-8628, Japan"}]},{"given":"Yongming","family":"Wang","sequence":"additional","affiliation":[{"name":"Creative Research Institution (CRIS), Hokkaido University, Kita 21, Nishi 10, Sapporo 001-0021, Japan"}]},{"given":"Akira","family":"Miura","sequence":"additional","affiliation":[{"name":"Division of Applied Chemistry, Hokkaido University, Sapporo 060-8628, Japan"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5980-4770","authenticated-orcid":false,"given":"Jorge A.","family":"Calder\u00f3n","sequence":"additional","affiliation":[{"name":"Centro de Investigaci\u00f3n, Innovaci\u00f3n y Desarrollo de Materiales (CIDEMAT), Universidad de Antioquia, Street 70 # 52-21, Medell\u00edn 050010, Colombia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6838-2875","authenticated-orcid":false,"given":"Nataly C.","family":"Rosero-Navarro","sequence":"additional","affiliation":[{"name":"Division of Applied Chemistry, Hokkaido University, Sapporo 060-8628, Japan"}]},{"given":"Kiyoharu","family":"Tadanaga","sequence":"additional","affiliation":[{"name":"Division of Applied Chemistry, Hokkaido University, Sapporo 060-8628, Japan"}]}],"member":"1968","published-online":{"date-parts":[[2021,11,11]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1002\/aenm.201701415","article-title":"Recent Developments on and Prospects for Electrode Materials with Hierarchical Structures for Lithium-Ion Batteries","volume":"8","author":"Zhou","year":"2018","journal-title":"Adv. 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