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(ERDF)","award":["POCI-01-0247-FEDER-047728"],"award-info":[{"award-number":["POCI-01-0247-FEDER-047728"]}]},{"name":"European Regional Development Fund (ERDF)","award":["UIDP\/50022\/2020"],"award-info":[{"award-number":["UIDP\/50022\/2020"]}]},{"name":"European Regional Development Fund (ERDF)","award":["PTDC\/QUI-ELT\/2593\/2021"],"award-info":[{"award-number":["PTDC\/QUI-ELT\/2593\/2021"]}]},{"name":"European Regional Development Fund (ERDF)","award":["612675-EPP-1-2019-1-SE-EPPKA2-SSA-B"],"award-info":[{"award-number":["612675-EPP-1-2019-1-SE-EPPKA2-SSA-B"]}]},{"name":"Erasmus Program of the European Union","award":["POCI-01-0247-FEDER-047728"],"award-info":[{"award-number":["POCI-01-0247-FEDER-047728"]}]},{"name":"Erasmus Program of the European Union","award":["UIDP\/50022\/2020"],"award-info":[{"award-number":["UIDP\/50022\/2020"]}]},{"name":"Erasmus Program of the European Union","award":["PTDC\/QUI-ELT\/2593\/2021"],"award-info":[{"award-number":["PTDC\/QUI-ELT\/2593\/2021"]}]},{"name":"Erasmus Program of the European Union","award":["612675-EPP-1-2019-1-SE-EPPKA2-SSA-B"],"award-info":[{"award-number":["612675-EPP-1-2019-1-SE-EPPKA2-SSA-B"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Batteries"],"abstract":"<jats:p>Taking advantage of electrode thicknesses well beyond conventional dimensions allowed us to follow the surface plasmonic THz frequency phenomenon with vacuum wavelengths of 100 \u03bcm to 1 mm, only to scrutinize them within millimeters-thicknesses insulators. Here, we analyze an Al\/insulator\/Cu cell in which the metal electrodes-collectors were separated by a gap that was alternatively filled by SiO2, MgO, Li2O, Na3Zr2Si2PO12\u2013NASICON, Li1.5Al0.5Ge1.5(PO4)3\u2013LAGP, and Li2.99Ba0.005ClO\u2013Li+ glass. A comparison was drawn using experimental surface chemical potentials, cyclic voltammetry (I-V plots), impedance spectroscopy, and theoretical approaches such as structure optimization, simulation of the electronic band structures, and work functions. The analysis reveals an unexpected common emergency from the cell\u2019s materials to align their surface chemical potential, even in operando when set to discharge under an external resistor of 1842 \u03a9.cminsulator. A very high capability of the metal electrodes to vary their surface chemical potentials and specific behavior among dielectric oxides and solid electrolytes was identified. Whereas LAGP and Li2O behaved as p-type semiconductors below 40 \u00b0C at OCV and while set to discharge with a resistor in agreement with the Li+ diffusion direction, NASICON behaved as a quasi n-type semiconductor at OCV, as MgO, and as a quasi p-type semiconductor while set to discharge. The capacity to behave as a p-type semiconductor may be related to the ionic conductivity of the mobile ion. The ferroelectric behavior of Li2.99Ba0.005ClO has shown surface plasmon polariton (SPP) waves in the form of surface propagating solitons, as in complex phenomena, as well as electrodes\u2019 surface chemical potentials inversion capabilities (i.e., \u03c7 (Al) \u2212 \u03c7 (Cu) &gt; 0 to \u03c7 (Al) \u2212 \u03c7 (Cu) &lt; 0 vs. Evacuum = 0 eV) and self-charge (\u0394Vcell \u2265 +0.04 V under a 1842 \u03a9.cminsulator resistor). The multivalent 5.5 mm thick layer cell filled with Li2.99Ba0.005ClO was the only one to display a potential bulk difference of 1.1 V. The lessons learned in this work may pave the way to understanding and designing more efficient energy harvesting and storage devices.<\/jats:p>","DOI":"10.3390\/batteries8110232","type":"journal-article","created":{"date-parts":[[2022,11,10]],"date-time":"2022-11-10T19:18:29Z","timestamp":1668107909000},"page":"232","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["What Differentiates Dielectric Oxides and Solid Electrolytes on the Pathway toward More Efficient Energy Storage?"],"prefix":"10.3390","volume":"8","author":[{"given":"Antonio Nuno","family":"Guerreiro","sequence":"first","affiliation":[{"name":"Engineering Physics Department, Engineering Faculty, University of Porto, 4200-465 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5252-4760","authenticated-orcid":false,"given":"Beatriz Arouca","family":"Maia","sequence":"additional","affiliation":[{"name":"Engineering Physics Department, Engineering Faculty, University of Porto, 4200-465 Porto, Portugal"},{"name":"LAETA\u2014INEGI, Institute of Science and Innovation in Mechanical and Industrial Engineering, 4200-465 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6683-7936","authenticated-orcid":false,"given":"Hesham","family":"Khalifa","sequence":"additional","affiliation":[{"name":"Engineering Physics Department, Engineering Faculty, University of Porto, 4200-465 Porto, Portugal"},{"name":"Department of Physics, Faculty of Science, Damanhur University, Damanhur 22511, Egypt"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8933-2751","authenticated-orcid":false,"given":"Manuela Carvalho","family":"Baptista","sequence":"additional","affiliation":[{"name":"Engineering Physics Department, Engineering Faculty, University of Porto, 4200-465 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4577-2154","authenticated-orcid":false,"given":"Maria Helena","family":"Braga","sequence":"additional","affiliation":[{"name":"Engineering Physics Department, Engineering Faculty, University of Porto, 4200-465 Porto, Portugal"},{"name":"LAETA\u2014INEGI, Institute of Science and Innovation in Mechanical and Industrial Engineering, 4200-465 Porto, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,10]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"15729","DOI":"10.1073\/pnas.0603395103","article-title":"Powering the planet: Chemical challenges in solar energy utilization","volume":"103","author":"Lewis","year":"2006","journal-title":"Proc. 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