{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,18]],"date-time":"2026-02-18T06:09:37Z","timestamp":1771394977521,"version":"3.50.1"},"reference-count":418,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2026,2,16]],"date-time":"2026-02-16T00:00:00Z","timestamp":1771200000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100000780","name":"European Union","doi-asserted-by":"crossref","award":["101086302"],"award-info":[{"award-number":["101086302"]}],"id":[{"id":"10.13039\/501100000780","id-type":"DOI","asserted-by":"crossref"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Biomimetics"],"abstract":"<jats:p>From Palaeolithic ornaments to modern biomimetics, the use of nacre and shells has evolved. Initially utilised for jewellery and tools, they now inspire the development of advanced materials. This paper reviews the current knowledge on nacre\u2019s composition, focusing on the highly regulated biomineralisation process wherein amorphous calcium carbonate (ACC) transforms into crystalline aragonite. It examines the important role of the organic matrix (specifically soluble, insoluble, and acidic proteins) in controlling crystal nucleation, growth, and polymorph selection. Scientists study natural nacre formation to create nacre-inspired composites for various applications. Charles Hatchett\u2019s in 1799 shell categorisation, Sorby and Sowerby\u2019s 19th-century microscopy, Taylor, Beedham, B\u00f8ggild, and Currey\u2019s mid-20th-century research on bivalve structures, and mechanical property investigations in the 1970s are some of the major developments. The hierarchical structure, cooperative plastic deformation, surface asperities, organic\u2013inorganic interactions, and interphase in such complex composite materials give rise to impressive mechanical properties. In the early 2000s, with the emergence of biomimetics, inspired by nacre, several macroscopic structural materials with uniform micro- and nanoscale architectures have been synthesised in recent decades, and their mechanical properties and potential applications have been explored. Modern nacre-inspired fabrication utilises 3D printing for precision, freeze casting for sustainability, and mineralisation for scalability. Techniques like layer-by-layer assembly and nanomaterial integration enhance mechanical performance through advanced interfacial engineering.<\/jats:p>","DOI":"10.3390\/biomimetics11020148","type":"journal-article","created":{"date-parts":[[2026,2,16]],"date-time":"2026-02-16T12:37:28Z","timestamp":1771245448000},"page":"148","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Nacre and Nacre-Inspired Materials: Historical Background, Definition, Fabrication Techniques and Gaps"],"prefix":"10.3390","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3895-7700","authenticated-orcid":false,"given":"Naim","family":"Sedira","sequence":"first","affiliation":[{"name":"C-MADE, The Centre of Materials and Civil Engineering for Sustainability, Universidade da Beira Interior (UBI), 6201-001 Covilh\u00e3, Portugal"},{"name":"Department of Civil Engineering and Architecture, University of Beira Interior (UBI), 6200-358 Covilh\u00e3, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2694-5462","authenticated-orcid":false,"given":"Jo\u00e3o","family":"Castro-Gomes","sequence":"additional","affiliation":[{"name":"C-MADE, The Centre of Materials and Civil Engineering for Sustainability, Universidade da Beira Interior (UBI), 6201-001 Covilh\u00e3, Portugal"},{"name":"Department of Civil Engineering and Architecture, University of Beira Interior (UBI), 6200-358 Covilh\u00e3, Portugal"}]},{"given":"Jorge","family":"Pinto","sequence":"additional","affiliation":[{"name":"C-MADE, The Centre of Materials and Civil Engineering for Sustainability, Universidade da Beira Interior (UBI), 6201-001 Covilh\u00e3, Portugal"},{"name":"Department of Engineering, School of Sciences and Technologies, University of Tr\u00e1s-os-Montes e Alto Douro (UTAD), 5000-801 Vila Real, Portugal"}]},{"given":"Pengkou","family":"Hou","sequence":"additional","affiliation":[{"name":"Shandong Provincial Key Laboratory of Green and Intelligent Building Materials, University of Jinan, Jinan 250022, China"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2630-7900","authenticated-orcid":false,"given":"Sandra","family":"Pereira","sequence":"additional","affiliation":[{"name":"C-MADE, The Centre of Materials and Civil Engineering for Sustainability, Universidade da Beira Interior (UBI), 6201-001 Covilh\u00e3, Portugal"},{"name":"Department of Engineering, School of Sciences and Technologies, University of Tr\u00e1s-os-Montes e Alto Douro (UTAD), 5000-801 Vila Real, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2026,2,16]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"912","DOI":"10.1038\/40010","article-title":"A pavement of pearl","volume":"389","author":"Addadi","year":"1997","journal-title":"Nature"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"831","DOI":"10.1007\/s10126-022-10145-9","article-title":"Organic Matrix and Secondary Metabolites in Nacre","volume":"24","author":"Iandolo","year":"2022","journal-title":"Mar. 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