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This comprehensive literature review evaluated various binder materials, including cement, geopolymers, earthen materials, supplementary cementitious materials, polymers, and biopolymers, with a focus on their environmental impacts and rheological properties. The study revealed an increasing interest in cementitious binders, which deliver essential structural strength and exhibit a wide range of yield stress values (15 to 6500 Pa), influenced by binder type and supplementary materials such as nanoclay. However, the significant CO2 emissions associated with cement pose major sustainability challenges. As a sustainable alternative, geopolymers demonstrate lower yield stress values (800 to 3000 Pa) while ensuring adequate buildability for vertical printing and reducing environmental impact. These findings underscore the need to adopt sustainable binder matrices to align 3D printing construction practices with global sustainability goals.<\/jats:p>","DOI":"10.3390\/buildings15010075","type":"journal-article","created":{"date-parts":[[2025,1,1]],"date-time":"2025-01-01T14:35:42Z","timestamp":1735742142000},"page":"75","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Comprehensive Review of Binder Matrices in 3D Printing Construction: Rheological Perspectives"],"prefix":"10.3390","volume":"15","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3901-9070","authenticated-orcid":false,"given":"Ye\u015fim","family":"Tarhan","sequence":"first","affiliation":[{"name":"Technical Sciences Vocational School, Ardahan University, Ardahan 75000, T\u00fcrkiye"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5161-3718","authenticated-orcid":false,"given":"\u0130smail Hakk\u0131","family":"Tarhan","sequence":"additional","affiliation":[{"name":"Department of Civil Engineering, Faculty of Engineering and Architecture, Tokat Gaziosmanpa\u015fa University, Tokat 60150, T\u00fcrkiye"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5400-7732","authenticated-orcid":false,"given":"Remzi","family":"\u015eahin","sequence":"additional","affiliation":[{"name":"Department of Civil Engineering, Atat\u00fcrk University, Erzurum 25030, T\u00fcrkiye"}]}],"member":"1968","published-online":{"date-parts":[[2024,12,29]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"100454","DOI":"10.1016\/j.dibe.2024.100454","article-title":"The Early-Age Cracking Sensitivity, Shrinkage, Hydration Process, Pore Structure and Micromechanics of Cement-Based Materials Containing Alkalis with Different Metal Ions","volume":"18","author":"Li","year":"2024","journal-title":"Dev. 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