{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,13]],"date-time":"2026-01-13T05:21:57Z","timestamp":1768281717382,"version":"3.49.0"},"reference-count":65,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2021,5,10]],"date-time":"2021-05-10T00:00:00Z","timestamp":1620604800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["UIDB\/00313\/2020"],"award-info":[{"award-number":["UIDB\/00313\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["UIDB\/00100\/2020"],"award-info":[{"award-number":["UIDB\/00100\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["PTDC\/QEQ-ERQ\/1648\/2014"],"award-info":[{"award-number":["PTDC\/QEQ-ERQ\/1648\/2014"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["PTDC\/QUI-OUT\/27996\/2017"],"award-info":[{"award-number":["PTDC\/QUI-OUT\/27996\/2017"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["PD\/BD\/114340\/2016 CATSUS"],"award-info":[{"award-number":["PD\/BD\/114340\/2016 CATSUS"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001807","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo","doi-asserted-by":"publisher","award":["2016\/16738-7"],"award-info":[{"award-number":["2016\/16738-7"]}],"id":[{"id":"10.13039\/501100001807","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001807","name":"Funda\u00e7\u00e3o de Amparo \u00e0 Pesquisa do Estado de S\u00e3o Paulo","doi-asserted-by":"publisher","award":["2019\/13569-8"],"award-info":[{"award-number":["2019\/13569-8"]}],"id":[{"id":"10.13039\/501100001807","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Quadro de Refer\u00eancia Estrat\u00e9gico Nacional - Portugal","award":["QREN-Mais Centro Project ICT_2009_02_012_1890"],"award-info":[{"award-number":["QREN-Mais Centro Project ICT_2009_02_012_1890"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Catalysts"],"abstract":"<jats:p>Two heterogeneous catalysts, MNP@SiO2-N-Xantphos\/Rh(I) and MNP@SiO2-NH-C-scorpionate\/Fe(II), were prepared by reaction of chloro-functionalized MNP@SiO2 with N-Xantphos and amino-functionalized MNP@SiO2 with iron(II)\/C-allyl-scorpionate through nucleophilic substitution and hydroaminomethylation reactions, respectively. All catalysts were characterized using standard spectroscopic means, transmission electron microscopy (TEM), thermogravimetry (TG), and inductively coupled plasma optical emission spectrometry (ICP-OES). An active and highly selective one-pot hydroformylation\/acetalization homogeneous system for the transformation of terminal and highly substituted olefins (including terpenes) onto ethyl acetals is described. A synergic effect of bimetallic Rh(I)\/P and Fe(II)\/C-scorpionate catalysts is disclosed for the first time. The further sequential use of the heterogeneous catalysts, MNP@SiO2-N-Xantphos\/Rh(I) and MNP@SiO2-NH-C-scorpionate\/Fe(II) in hydroformylation\/acetalization reactions allows the direct transformation of olefin onto ethyl acetals, keeping the activity and selectivity. Both catalysts were easily recovered by magnetic separation and reused with negligible loss of activity\/selectivity, after six reutilization cycles.<\/jats:p>","DOI":"10.3390\/catal11050608","type":"journal-article","created":{"date-parts":[[2021,5,10]],"date-time":"2021-05-10T10:49:51Z","timestamp":1620643791000},"page":"608","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Immobilization of Rh(I)-N-Xantphos and Fe(II)-C-Scorpionate onto Magnetic Nanoparticles: Reusable Catalytic System for Sequential Hydroformylation\/Acetalization"],"prefix":"10.3390","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1085-2720","authenticated-orcid":false,"given":"F\u00e1bio M. S.","family":"Rodrigues","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica de Coimbra, Departamento de Qu\u00edmica Rua Larga, Universidade de Coimbra, 3004-535 Coimbra, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2858-7539","authenticated-orcid":false,"given":"Lucas D.","family":"Dias","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica de Coimbra, Departamento de Qu\u00edmica Rua Larga, Universidade de Coimbra, 3004-535 Coimbra, Portugal"},{"name":"S\u00e3o Carlos Institute of Physics, University of S\u00e3o Paulo, S\u00e3o Carlos-SP 13566-590, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2094-4781","authenticated-orcid":false,"given":"M\u00e1rio J. F.","family":"Calvete","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica de Coimbra, Departamento de Qu\u00edmica Rua Larga, Universidade de Coimbra, 3004-535 Coimbra, Portugal"}]},{"given":"Teresa M. R.","family":"Maria","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica de Coimbra, Departamento de Qu\u00edmica Rua Larga, Universidade de Coimbra, 3004-535 Coimbra, Portugal"}]},{"given":"Liane M.","family":"Rossi","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica Fundamental, Instituto de Qu\u00edmica, Universidade de S\u00e3o Paulo, S\u00e3o Paulo-SP 05508-000, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8323-888X","authenticated-orcid":false,"given":"Armando J. L.","family":"Pombeiro","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5403-9352","authenticated-orcid":false,"given":"Lu\u00edsa M. D. R. S.","family":"Martins","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4958-7677","authenticated-orcid":false,"given":"Mariette M.","family":"Pereira","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica de Coimbra, Departamento de Qu\u00edmica Rua Larga, Universidade de Coimbra, 3004-535 Coimbra, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2021,5,10]]},"reference":[{"key":"ref_1","first-page":"1306","article-title":"Multicomponent and multicatalytic reactions\u2014A synthetic strategy inspired by nature","volume":"9","year":"2016","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"477","DOI":"10.1038\/nchem.2262","article-title":"Orthogonal tandem catalysis","volume":"7","author":"Lohr","year":"2015","journal-title":"Nat. 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