{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,1]],"date-time":"2026-05-01T23:32:47Z","timestamp":1777678367473,"version":"3.51.4"},"reference-count":56,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2022,3,2]],"date-time":"2022-03-02T00:00:00Z","timestamp":1646179200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","doi-asserted-by":"publisher","award":["UIDB\/00100\/2020 UIDP\/00100\/2020"],"award-info":[{"award-number":["UIDB\/00100\/2020 UIDP\/00100\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Catalysts"],"abstract":"<jats:p>Rhenium nanoparticles (Re NPs) supported on Norit (activated carbon\u2014C) and graphene (G) were prepared by a solvothermal method under microwave irradiation (MW). The synthesised heterogeneous catalysts were characterised and tested as reduction and oxidation catalysts, highlighting their dual catalytic behaviour. In the first case, they were used, for the first time, to reduce 4-nitrophenol, in aqueous medium, under MW irradiation. Re catalysts were easily recovered by centrifugation and recycled up to six times without significant activity loss. However, the same Re catalysts in MW-assisted oxidation of 1-phenylethanol with no added solvent experienced a significant loss of activity when recycled. The higher activity of the rhenium nanoparticles supported on graphene (Re\/G) catalyst in both reactions was assigned to the higher dispersion and smaller particle size of Re NPs when graphene is the support.<\/jats:p>","DOI":"10.3390\/catal12030285","type":"journal-article","created":{"date-parts":[[2022,3,2]],"date-time":"2022-03-02T22:53:25Z","timestamp":1646261605000},"page":"285","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["C-Heterogenized Re Nanoparticles as Effective Catalysts for the Reduction of 4-Nitrophenol and Oxidation of 1-Phenylethanol"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-4323-4328","authenticated-orcid":false,"given":"Ana P. C.","family":"Ribeiro","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Qu\u00edmica, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8912-5138","authenticated-orcid":false,"given":"Beatriz M.","family":"Santos","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Qu\u00edmica, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5109-8832","authenticated-orcid":false,"given":"Rute F. C.","family":"Faustino","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Qu\u00edmica, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8323-888X","authenticated-orcid":false,"given":"Armando J. L.","family":"Pombeiro","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Qu\u00edmica, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"},{"name":"Peoples\u2019 Friendship University of Russia (RUDN University), Research Institute of Chemistry, 6 Miklukho-Maklaya Street, 117198 Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5403-9352","authenticated-orcid":false,"given":"Lu\u00edsa M. D. R. S.","family":"Martins","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Institute of Molecular Sciences, Departamento de Engenharia Qu\u00edmica, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,3,2]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"164","DOI":"10.1039\/B411438H","article-title":"Microwaves in organic synthesis. Thermal and non-thermal microwave effects","volume":"34","author":"Moreno","year":"2005","journal-title":"Chem. Soc. Rev."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1170","DOI":"10.1021\/cr4002353","article-title":"Modern microwave methods in solid-state inorganic materials chemistry: From fundamentals to manufacturing","volume":"114","author":"Kitchen","year":"2014","journal-title":"Chem. 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