{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,17]],"date-time":"2025-11-17T14:27:27Z","timestamp":1763389647251,"version":"build-2065373602"},"reference-count":59,"publisher":"MDPI AG","issue":"12","license":[{"start":{"date-parts":[[2022,11,25]],"date-time":"2022-11-25T00:00:00Z","timestamp":1669334400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"national funds","award":["2021.04756.BD"],"award-info":[{"award-number":["2021.04756.BD"]}]},{"name":"European Union","award":["2021.04756.BD"],"award-info":[{"award-number":["2021.04756.BD"]}]},{"name":"FCT","award":["2021.04756.BD"],"award-info":[{"award-number":["2021.04756.BD"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Catalysts"],"abstract":"<jats:p>Olefin epoxidation is an important transformation for the chemical valorization of olefins, which may derive from renewable sources or domestic\/industrial waste. Different post-synthesis strategies were employed to introduce molybdenum species into mesostructured and hierarchical micro-mesoporous catalysts of the type TUD-1 and BEA, respectively, to confer epoxidation activity for the conversion of relatively bulky olefins (e.g., biobased methyl oleate, DL-limonene) to epoxide products, using tert-butyl hydroperoxide as an oxidant. The influences of (i) the type of metal precursor, (ii) type of post-synthesis impregnation method, (iii) type of support and (iv) top-down versus bottom-up synthesis methodologies were studied to achieve superior catalytic performances. Higher epoxidation activity was achieved for a material prepared via (post-synthesis) incipient wetness impregnation of MoO2(acac)2 (acac = acetylacetonate) on (pre-treated) siliceous TUD-1 and calcination; for example, methyl oleate was converted to the corresponding epoxide with 100% selectivity at 89% conversion (70 \u00b0C). Catalytic and solid-state characterization studies were conducted to shed light on material stability phenomena.<\/jats:p>","DOI":"10.3390\/catal12121513","type":"journal-article","created":{"date-parts":[[2022,11,30]],"date-time":"2022-11-30T04:58:50Z","timestamp":1669784330000},"page":"1513","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Post-Synthesis Strategies to Prepare Mesostructured and Hierarchical Silicates for Liquid Phase Catalytic Epoxidation"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7077-8796","authenticated-orcid":false,"given":"Diana M.","family":"Gomes","sequence":"first","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1932-4975","authenticated-orcid":false,"given":"Patr\u00edcia","family":"Neves","sequence":"additional","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5888-2278","authenticated-orcid":false,"given":"Margarida M.","family":"Antunes","sequence":"additional","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4376-5594","authenticated-orcid":false,"given":"Ant\u00f3nio J. S.","family":"Fernandes","sequence":"additional","affiliation":[{"name":"i3N, Department of Physics, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6243-7692","authenticated-orcid":false,"given":"Martyn","family":"Pillinger","sequence":"additional","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3495-2133","authenticated-orcid":false,"given":"Anabela A.","family":"Valente","sequence":"additional","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,11,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Bakhtyari, A., Makarem, M.A., and Rahimpour, M.R. (2017). Light Olefins\/Bio-Gasoline Production from Biomass. Bioenergy Systems for the Future, Elsevier.","DOI":"10.1016\/B978-0-08-101031-0.00004-1"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"3447","DOI":"10.1021\/ie0513090","article-title":"The Production of Propene Oxide: Catalytic Processes and Recent Developments","volume":"45","author":"Nijhuis","year":"2006","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_3","unstructured":"(2022, October 22). Tert-Butyl Hydroperoxide|Ataman Kimya A.\u015e.. Available online: https:\/\/www.ataman-Chemicals.com\/en\/products\/tert-butyl-hydroperoxide-1817.html."},{"key":"ref_4","first-page":"3289","article-title":"Transition-Metal Complexes for Liquid-Phase Catalytic Oxidation: Some Aspects of Industrial Reactions and of Emerging Technologies","volume":"3","year":"2003","journal-title":"J. Chem. Soc. Dalton Trans."},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Smith, M.B. (2017). Functional Group Exchange Reactions: Oxidations. Organic Synthesis, Elsevier (Academic Press).","DOI":"10.1016\/B978-0-12-800720-4.00010-6"},{"key":"ref_6","unstructured":"Serge Hub, V., and Philippe Maj, B. (2013). Manufacture of Tertiobutyl Hydroperoxide from Renewable Materials, Tertiobutyl Hydroperoxide Thus Obtained, and Used Thereof. (US8536379B2), U.S. Patent, Available online: https:\/\/patents.google.com\/patent\/US8536379B2\/en."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"139","DOI":"10.1021\/acscatal.0c03394","article-title":"Alkene Epoxidations with H2O2 over Groups 4\u20136, Metal-Substituted BEA Zeolites: Reactive Intermediates, Reaction Pathways, and Linear Free-Energy Relationships","volume":"11","author":"Ayla","year":"2021","journal-title":"ACS Catal."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"1123","DOI":"10.1039\/a801492b","article-title":"Metal Silicates by a Molecular Route as Catalysts for Epoxidation of Alkenes with tert-Butyl Hydroperoxide","volume":"10","author":"Juwiler","year":"1998","journal-title":"Chem. Commun."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"213","DOI":"10.1081\/CR-100100262","article-title":"Epoxidation of Functionalized Olefins over Solid Catalysts","volume":"42","author":"Dusi","year":"2000","journal-title":"Catal. Rev.-Sci. Eng."},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Shen, Y., Jiang, P., Wai, P.T., Gu, Q., and Zhang, W. (2019). Recent Progress in Application of Molybdenum-Based Catalysts for Epoxidation of Alkenes. Catalysts, 9.","DOI":"10.3390\/catal9010031"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"1093","DOI":"10.1021\/acs.iecr.9b05340","article-title":"Molybdenum-Confined Hierarchical Titanium Silicalite-1: The Synthesis, Characterization, and Catalytic Activity in Alkene Oxidation","volume":"59","author":"Wang","year":"2020","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"18518","DOI":"10.1039\/C7TA06288E","article-title":"One-Pot Synthesis of Molybdenum Oxide Nanoparticles Encapsulated in Hollow Silica Spheres: An Efficient and Reusable Catalyst for Epoxidation of Olefins","volume":"5","author":"Kuwahara","year":"2017","journal-title":"J. Mater. Chem. A"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"1894","DOI":"10.1039\/c2cy20073b","article-title":"Synthesis, Characterization and Catalytic Performance of Mo-TUD-1 Catalysts in Epoxidation of Cyclohexene","volume":"2","author":"Hamdy","year":"2012","journal-title":"Catal. Sci. Technol."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"119","DOI":"10.1016\/j.micromeso.2010.10.037","article-title":"Silica Supported Amorphous Molybdenum Catalysts Prepared via Sol-Gel Method and Its Catalytic Activity","volume":"141","author":"Adam","year":"2011","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"1447","DOI":"10.1016\/j.catcom.2006.12.015","article-title":"Comparison of the Conventional Impregnation Method Using Ammonium Heptamolybdate with a Simple Route to Silica-Supported Molybdenum(VI) Materials","volume":"8","author":"Bakala","year":"2007","journal-title":"Catal. Commun."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"91","DOI":"10.1016\/j.apcata.2005.09.038","article-title":"Comparison of Liquid-Phase Olefin Epoxidation over MoOx Inserted within Mesoporous Silica (MCM-41, SBA-15) and Grafted onto Silica","volume":"300","author":"Bakala","year":"2006","journal-title":"Appl. Catal. A Gen."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"51","DOI":"10.1016\/S0926-860X(02)00015-7","article-title":"Oxidation Capabilities of BEA Isomorphously Substituted with Molybdenum, Vanadium and Titanium: An Explorative Study","volume":"229","author":"Niederer","year":"2002","journal-title":"Appl. Catal. A Gen."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1016\/S1387-1811(98)00342-4","article-title":"Using Inorganic Silicate Precursor\/Molybdenum Peroxo Complexes\/Onium Salt Interfaces in Aqueous Acidic Media to Design Mesoporous Silica with High Molybdenum Content and High Dispersion","volume":"29","author":"Piquemal","year":"1999","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"642","DOI":"10.1039\/B904193A","article-title":"TUD-1: Synthesis and Application of a Versatile Catalyst, Carrier, Material","volume":"20","author":"Telalovi","year":"2010","journal-title":"J. Mater. Chem."},{"key":"ref_20","unstructured":"Angevine, P.J., Gaffney, A.M., Shan, Z., Koegler, J.H., and Yeh, C.Y. (2008, January 6\u201310). TUD-1: A Generalised Mesoporous Catalyst Family for Industrial Applications. Proceedings of the 235th ACS National Meeting, New Orleans, LA, USA."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"074001","DOI":"10.1088\/2053-1591\/ab12be","article-title":"Comparison Study on Molybdena-Titania Supported on TUD-1 and TUD-C Synthesized via Sol-Gel Templating Method: Properties and Catalytic Performance in Olefins Epoxidation","volume":"6","author":"Ooi","year":"2019","journal-title":"Mater. Res. Express"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"411","DOI":"10.1016\/j.micromeso.2016.01.016","article-title":"Mesostructured TUD-C Supported Molybdena Doped Titania as High Selective Oxidative Catalyst for Olefins Epoxidation at Ambient Condition","volume":"225","author":"Ooi","year":"2016","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"1887","DOI":"10.1039\/C39940001887","article-title":"Titanium-Substituted Zeolite Beta(Ti-Al-\u03b2)-Catalysed Epoxidation of Oct-1-ene with tert-Butyl Hydroperoxide (TBHP)","volume":"16","author":"Sato","year":"1994","journal-title":"J. Chem. Soc. Chem. Commun."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1006\/jcat.1995.1055","article-title":"Oxidation of Olefins with Hydrogen Peroxide and Tert-Butyl Hydroperoxide on Ti-Beta Catalyst","volume":"152","author":"Corma","year":"1995","journal-title":"J. Catal."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1724","DOI":"10.1135\/cccc19981724","article-title":"Activities and Stabilities of Redox Molecular Sieve Catalysts in Liquid Phase Oxidations. A Review","volume":"63","author":"Sheldon","year":"1998","journal-title":"Collect. Czech. Chem. Commun."},{"key":"ref_26","first-page":"34","article-title":"Characterization of Micro\/Mesoporous Materials by Physisorption: Concepts and Case Studies","volume":"3","author":"Sotomayor","year":"2018","journal-title":"Acc. Mater. Surf. Res."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"2002181","DOI":"10.1002\/admi.202002181","article-title":"Characterization of Hierarchically Ordered Porous Materials by Physisorption and Mercury Porosimetry\u2014A Tutorial Review","volume":"8","author":"Schlumberger","year":"2021","journal-title":"Adv. Mater. Interfaces"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"56","DOI":"10.1016\/j.jcat.2021.12.022","article-title":"Renewable Bio-Based Routes to \u03b3-Valerolactone in the Presence of Hafnium Nanocrystalline or Hierarchical Microcrystalline Zeotype Catalysts","volume":"406","author":"Antunes","year":"2022","journal-title":"J. Catal."},{"key":"ref_29","first-page":"1805","article-title":"Facile Synthesis of Mesoporous Silica Nanoparticles Using Modified Sol- Gel Method: Optimization and in Vitro Cytotoxicity Studies","volume":"32","author":"Mehmood","year":"2019","journal-title":"Pak. J. Pharm. Sci."},{"key":"ref_30","first-page":"1","article-title":"Efficient Loading and Encapsulation of Anti-Tuberculosis Drugs Using Multifunctional Mesoporous Silicate Nanoparticles Running Title: Mesoporous Silicate Nanoparticles as Smart Drug Delivery System","volume":"1","author":"Shawky","year":"2016","journal-title":"J. Nanosci. Curr. Res."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"174","DOI":"10.20884\/1.jm.2017.12.2.382","article-title":"Silica Content and Structure from Corncob Ash with Various Acid Treatment (HCl, HBr, and Citric Acid)","volume":"12","author":"Ayu","year":"2017","journal-title":"Molekul"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"779","DOI":"10.1007\/s10934-021-01031-1","article-title":"High-Dispersed MoO3 Nanoparticles in 3D-Dendritic Mesoporous Silica Nanospheres: Heterogeneous Catalysts for the Epoxidation of Olefins","volume":"28","author":"Gu","year":"2021","journal-title":"J. Porous Mater."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"215","DOI":"10.1016\/j.cattod.2019.03.073","article-title":"Highly Dispersed Molybdenum Containing Mesoporous Silicate (Mo-TUD-1) for Olefin Metathesis","volume":"343","author":"Uchagawkar","year":"2020","journal-title":"Catal. Today"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"1664","DOI":"10.1002\/cctc.201400040","article-title":"The Enhancing Effect of Br\u00f8nsted Acidity of Supported MoOx Species on Their Activity and Selectivity in Ethylene\/Trans-2-Butene Metathesis","volume":"6","author":"Hahn","year":"2014","journal-title":"ChemCatChem"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1016\/j.apcata.2011.03.032","article-title":"Applied Catalysis A: General Structure of Molybdenum Oxide Supported on Silica SBA-15 Studied by Raman, UV-Vis and X-Ray Absorption Spectroscopy","volume":"399","author":"Thielemann","year":"2011","journal-title":"Appl. Catal. A Gen."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"142","DOI":"10.1016\/j.apcata.2006.08.029","article-title":"Gas-Phase Epoxidation of Propylene through Radicals Generated by Silica-Supported Molybdenum Oxide","volume":"316","author":"Song","year":"2007","journal-title":"Appl. Catal. A Gen."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"118","DOI":"10.1016\/j.micromeso.2017.03.001","article-title":"Microporous and Mesoporous Materials Synthesis of Molybdenum-Incorporated Mesoporous Silicates by Evaporation-Induced Self-Assembly: Insights into Surface Oxide Species and Corresponding Olefin Metathesis Activity","volume":"245","author":"Ramanathan","year":"2017","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"5740","DOI":"10.1021\/acscatal.6b00098","article-title":"Highly Efficient Activation, Regeneration, and Active Site Identification of Oxide-Based Olefin Metathesis Catalysts","volume":"5","author":"Ding","year":"2016","journal-title":"ACS Catal."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"19060","DOI":"10.1039\/C4TA03754E","article-title":"One-Pot Synthesis of Ultrasmall MoO3","volume":"2","author":"Chandra","year":"2014","journal-title":"J. Mater. Chem. A"},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"122839","DOI":"10.1016\/j.cej.2019.122839","article-title":"Transesterification of Rice Bran Oil to Biodiesel Using Mesoporous NaBeta Zeolite-Supported Molybdenum Catalyst: Experimental and Kinetic Studies","volume":"382","author":"Chen","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"14110","DOI":"10.1021\/jp103269w","article-title":"Molecular Structural Determination of Molybdena in Different Environments: Aqueous Solutions, Bulk Mixed Oxides, and Supported MoO3 Catalysts","volume":"114","author":"Tian","year":"2010","journal-title":"J. Phys. Chem. C"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"14410","DOI":"10.1021\/jp0735482","article-title":"In Situ Spectroscopic Investigation of the Molecular and Electronic Structures of SiO2 Supported Surface Metal Oxides","volume":"111","author":"Lee","year":"2007","journal-title":"J. Phys. Chem. C"},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"446","DOI":"10.1016\/S0144-2449(88)80219-7","article-title":"The framework topology of zeolite beta","volume":"8","author":"Higgins","year":"1988","journal-title":"Zeolites"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"20167","DOI":"10.1021\/jp808356q","article-title":"Two Kinds of Framework Al Sites Studied in BEA Zeolite by X-ray Diffraction, Fourier Transform Infrared Spectroscopy, NMR Techniques, and V Probe","volume":"112","author":"Hajjar","year":"2008","journal-title":"Phys. Chem. C"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1016\/j.molstruc.2015.05.004","article-title":"Structural analysis of zeolite beta through periodic ab initio simulations of XRD and 29Si and 17O NMR spectra","volume":"1097","author":"Costa","year":"2015","journal-title":"J. Mol. Struct."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"874","DOI":"10.1366\/0003702914336651","article-title":"FT-IR Emission Spectroscopy Studies of Molybdenum Oxide and Supported Molybdena on Alumina, Silica, Zirconia, and Titania","volume":"45","author":"Li","year":"1991","journal-title":"Appl. Spectrosc."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"1383","DOI":"10.1039\/b515484g","article-title":"Olefin Epoxidation with Tert-Butyl Hydroperoxide Catalyzed by MoO2X2L Complexes: A DFT Mechanistic Study","volume":"11","author":"Veiros","year":"2006","journal-title":"Dalton Trans."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"6942","DOI":"10.1039\/c2dt12284g","article-title":"New Insights into the Mechanism of Oxodiperoxomolybdenum Catalysed Olefin Epoxidation and the Crystal Structures of Several Oxo-Peroxo Molybdenum Complexes","volume":"41","author":"Herbert","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"601","DOI":"10.1002\/cctc.201200068","article-title":"Solvent-Free Epoxidation of Olefins Catalyzed by \u201c[MoO2(SAP)]\u201d: A New Mode of tert-Butyl hydroperoxide Activation","volume":"5","author":"Morlot","year":"2013","journal-title":"ChemCatChem"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"65","DOI":"10.2174\/138527212798993095","article-title":"Unveiling the Mechanisms of Catalytic Oxidation Reactions Mediated by Oxo-Molybdenum Complexes: A Computational Overview","volume":"16","author":"Calhorda","year":"2012","journal-title":"Curr. Org. Chem."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"542","DOI":"10.1002\/recl.19961151116","article-title":"Molybdenum-Catalyzed Epoxidations of Oct-1-ene and Cyclohexene with Organic Hydroperoxides: Steric Effects of the Alkyl Substituents of the Hydroperoxide on the Reaction Rate","volume":"115","author":"Sheldon","year":"1996","journal-title":"Recl. Trav. Chim. Pays-Bas"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"79","DOI":"10.1016\/j.molcata.2013.11.008","article-title":"Epoxidation of Alkenes Using Inorganic Polymer of Silica Zirconia Molybdate as Catalyst","volume":"382","author":"Sharbatdaran","year":"2014","journal-title":"J. Mol. Catal. A Chem."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"212","DOI":"10.1016\/j.mcat.2016.12.011","article-title":"Highly Dispersed Molybdenum Incorporated Hollow Mesoporous Silica Spheres as an Efficient Catalyst on Epoxidation of Olefins","volume":"433","author":"Shen","year":"2017","journal-title":"Mol. Catal."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"317","DOI":"10.1007\/s11144-021-02147-w","article-title":"The Interaction of Molybdenum and Titanium in Mesoporous Materials for Olefin Epoxidation","volume":"135","author":"Zhang","year":"2022","journal-title":"React. Kinet. Mech. Catal."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"3330","DOI":"10.1039\/c3cc39275a","article-title":"Assembly of ZIF Nanostructures around Free Pt Nanoparticles: Efficient Size-Selective Catalysts for Hydrogenation of Alkenes under Mild Conditions","volume":"49","author":"Wang","year":"2013","journal-title":"Chem Comm."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"10906","DOI":"10.1021\/ie5013695","article-title":"New Pd\/SiO2@ZIF-8 Core\u2013Shell Catalyst with Selective, Antipoisoning, and Antileaching Properties for the Hydrogenation of Alkenes","volume":"53","author":"Lin","year":"2014","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"869","DOI":"10.1007\/s10934-018-0684-2","article-title":"Enhanced Catalytic Activity over Mo-Containing Hierarchical Macro-Mesoporous SBA-15 Catalysts for Epoxidation of Olefins","volume":"26","author":"Zhang","year":"2019","journal-title":"J. Porous Mater."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"141","DOI":"10.1016\/j.apcata.2010.08.040","article-title":"Catalytic Cyclodehydration of Xylose to Furfural in the Presence of Zeolite H-Beta and a Micro\/Mesoporous Beta\/TUD-1 Composite Material","volume":"388","author":"Lima","year":"2010","journal-title":"Appl. Catal. A Gen."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"4481","DOI":"10.1021\/acs.langmuir.0c03647","article-title":"Gas Phase Modification of Silica Nanoparticles in a Fluidized Bed: Tailored Deposition of Aminopropylsiloxane","volume":"37","author":"Mahtabani","year":"2021","journal-title":"Langmuir"}],"container-title":["Catalysts"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-4344\/12\/12\/1513\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:26:38Z","timestamp":1760145998000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-4344\/12\/12\/1513"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,11,25]]},"references-count":59,"journal-issue":{"issue":"12","published-online":{"date-parts":[[2022,12]]}},"alternative-id":["catal12121513"],"URL":"https:\/\/doi.org\/10.3390\/catal12121513","relation":{},"ISSN":["2073-4344"],"issn-type":[{"type":"electronic","value":"2073-4344"}],"subject":[],"published":{"date-parts":[[2022,11,25]]}}}