{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T02:12:01Z","timestamp":1760148721632,"version":"build-2065373602"},"reference-count":61,"publisher":"MDPI AG","issue":"6","license":[{"start":{"date-parts":[[2023,5,24]],"date-time":"2023-05-24T00:00:00Z","timestamp":1684886400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia (FCT)","doi-asserted-by":"publisher","award":["UID\/QUI\/0081\/2020","LA\/P\/0056\/2020","UIDB\/50006\/2020","UID\/QUI\/50006\/2019"],"award-info":[{"award-number":["UID\/QUI\/0081\/2020","LA\/P\/0056\/2020","UIDB\/50006\/2020","UID\/QUI\/50006\/2019"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Catalysts"],"abstract":"<jats:p>A systematic synthetic study was performed to explain the usual trend in selectivity towards multi-coupling, over mono-coupling, in Suzuki\u2013Miyaura reactions. This preference was observed under different reaction conditions: for various halobenzenes, using substituents on the boronic acid, and changing the catalyst and temperature. Moreover, this reaction selectivity was found to increase for more reactive systems towards oxidative addition and more diluted media. The results constitute experimental evidence that the formation of the totally substituted coupling product is kinetically favoured by a reaction path location\u2014the proximity between the regenerated catalyst and the newly formed coupling intermediate promotes the subsequent reaction.<\/jats:p>","DOI":"10.3390\/catal13060928","type":"journal-article","created":{"date-parts":[[2023,5,25]],"date-time":"2023-05-25T03:56:58Z","timestamp":1684987018000},"page":"928","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Highlights on the General Preference for Multi-Over Mono-Coupling in the Suzuki\u2013Miyaura Reaction"],"prefix":"10.3390","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-5065-0912","authenticated-orcid":false,"given":"Carlos F. R. A. C.","family":"Lima","sequence":"first","affiliation":[{"name":"CIQUP, Institute of Molecular Sciences (IMS)\u2014Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias da Universidade do Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3517-5041","authenticated-orcid":false,"given":"Marco A. L.","family":"Lima","sequence":"additional","affiliation":[{"name":"Institut f\u00fcr Anorganische Chemie I, Universit\u00e4t Ulm Albert-Einstein-Allee 11, 89081 Ulm, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8780-3951","authenticated-orcid":false,"given":"J. Ricardo M.","family":"Pinto","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Science, University of Porto, Rua Campo Alegre s\/n, 4169-007 Porto, Portugal"}]},{"given":"M. Gabriela T. C.","family":"Ribeiro","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Science, University of Porto, Rua Campo Alegre s\/n, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2861-8286","authenticated-orcid":false,"given":"Artur M. S.","family":"Silva","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry, University of Aveiro, Campus Universit\u00e1rio de Santiago, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3040-0358","authenticated-orcid":false,"given":"Lu\u00eds M. N. B. F.","family":"Santos","sequence":"additional","affiliation":[{"name":"CIQUP, Institute of Molecular Sciences (IMS)\u2014Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias da Universidade do Porto, 4169-007 Porto, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2023,5,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3437","DOI":"10.1016\/S0040-4039(01)95429-2","article-title":"A new stereospecific cross-coupling by the palladium-catalyzed reaction of 1-alkenylboranes with 1-alkenyl or 1-alkynyl halides","volume":"20","author":"Miyaura","year":"1979","journal-title":"Tetrahedron Lett."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"513","DOI":"10.1080\/00397918108063618","article-title":"The palladium-catalyzed cross-coupling reaction of phenylboronic acid with haloarenes in the presence of bases","volume":"11","author":"Miyaura","year":"1981","journal-title":"Synth. 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