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[Zn2(\u03bc3-1\u03baN,2\u03baN\u2032,3\u03baO-HL)2(DMF)2]n\u00b7nH2O (HL2\u2212 = 4-((4-(1H-tetrazol-5-yl)phenyl)carbamoyl)benzoate), denoted as ZnMOF, for the efficient conversion of carbon dioxide (CO2) to cyclic carbonates via cycloaddition with epoxides. It was synthesised from a tetrazole appended amide-functionalised pro-ligand (H3L) and Zn(NO3)2\u00b76H2O under hydrothermal conditions. The synthesised material was characterised namely by elemental analysis, infrared spectroscopy, powder X-ray diffraction (PXRD), and single-crystal X-ray diffraction analyses. The catalytic potential of ZnMOF was investigated in the CO2 cycloaddition reaction with various epoxides, with conversions ranging from 17% to 99%. The catalyst retained its activity across multiple reaction cycles, demonstrating its stability and reusability. The influence of co-catalysts on the reaction was explored, with tetrabutylammonium bromide (TBABr) emerging as the most effective one. A plausible reaction mechanism is proposed.<\/jats:p>","DOI":"10.3390\/catal14010006","type":"journal-article","created":{"date-parts":[[2023,12,20]],"date-time":"2023-12-20T03:51:45Z","timestamp":1703044305000},"page":"6","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Nitrogen-Rich Tetrazole\u2013Amide-Functionalised Zn Metal\u2013Organic Framework as Catalyst for Efficient Catalytic CO2 Cycloaddition with Epoxides"],"prefix":"10.3390","volume":"14","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1596-0675","authenticated-orcid":false,"given":"Anup","family":"Paul","sequence":"first","affiliation":[{"name":"Centro de Qu\u00edmica Estrutura, Institute of Molecular Sciences, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6000-3583","authenticated-orcid":false,"given":"Ismayil M.","family":"Garazade","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutura, Institute of Molecular Sciences, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"},{"name":"Department of Chemistry, Baku State University, Z. Khalilov Str. 23, 1148 Baku, Azerbaijan"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3047-2204","authenticated-orcid":false,"given":"Anirban","family":"Karmakar","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutura, Institute of Molecular Sciences, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7599-8464","authenticated-orcid":false,"given":"Rais Ahmad","family":"Khan","sequence":"additional","affiliation":[{"name":"Department of Chemistry, King Saud University, Riyadh 11451, Saudi Arabia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4836-2409","authenticated-orcid":false,"given":"Maria F\u00e1tima C.","family":"Guedes da Silva","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutura, Institute of Molecular Sciences, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"},{"name":"Departamento de Engenharia Qu\u00edmica, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"}]},{"given":"Ana V. M.","family":"Nunes","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Departamento de Qu\u00edmica, Faculdade de Ci\u00eancias e Tecnologia, Universidade Nova de Lisboa, 2829-516 Caparica, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8323-888X","authenticated-orcid":false,"given":"Armando J. L.","family":"Pombeiro","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutura, Institute of Molecular Sciences, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2023,12,20]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"114801","DOI":"10.1016\/j.ejmech.2022.114801","article-title":"Metal-Organic Frameworks (MOFs) as Biomolecules Drug Delivery Systems for Anticancer Purposes","volume":"244","author":"Coluccia","year":"2022","journal-title":"Eur. J. Med. Chem."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"2201550","DOI":"10.1002\/smll.202201550","article-title":"Metal-Organic Frameworks for Greenhouse Gas Applications","volume":"19","author":"Dong","year":"2023","journal-title":"Small"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"9970","DOI":"10.1021\/acsami.1c24759","article-title":"Energy Transfer in Metal-Organic Frameworks for Fluorescence Sensing","volume":"14","author":"Wang","year":"2022","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"215364","DOI":"10.1016\/j.ccr.2023.215364","article-title":"Confining Atomically Precise Nanoclusters in Metal\u2013Organic Frameworks for Advanced Catalysis","volume":"495","author":"Li","year":"2023","journal-title":"Coord. Chem. Rev."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"4683","DOI":"10.1039\/c3cc49457h","article-title":"\u2018Click\u2019-Extended Nitrogen-Rich Metal\u2013Organic Frameworks and Their High Performance in CO2-Selective Capture","volume":"50","author":"Li","year":"2014","journal-title":"Chem. Commun."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"37","DOI":"10.1016\/j.enmf.2023.03.001","article-title":"High-Efficiency Catalysis of Nitrogen-Rich Metal-Organic Frameworks and Their Derivatives for the Thermal Decomposition of Ammonium Perchlorate","volume":"4","author":"Cheng","year":"2023","journal-title":"Energ. Mater. Front."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"555","DOI":"10.1016\/j.jechem.2020.06.038","article-title":"Nitrogen-Rich Metal-Organic Framework Mediated Cu\u2013N\u2013C Composite Catalysts for the Electrochemical Reduction of CO2","volume":"54","author":"Cao","year":"2021","journal-title":"J. Energy Chem."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"2177","DOI":"10.1021\/acsomega.0c05457","article-title":"Nitrogen-Rich Tetraphenylethene-Based Luminescent Metal-Organic Framework for Efficient Detection of Carcinogens","volume":"6","author":"Guo","year":"2021","journal-title":"ACS Omega"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"50619","DOI":"10.1021\/acsami.0c15395","article-title":"A Rational Design of Microporous Nitrogen-Rich Lanthanide Metal-Organic Frameworks for CO2\/CH4 Separation","volume":"12","author":"Mohan","year":"2020","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"5176","DOI":"10.1021\/cg201054f","article-title":"Porous Nitrogen Rich Cadmium-Tetrazolate Based Metal Organic Framework (MOF) for H2 and CO2 Uptake","volume":"11","author":"Pachfule","year":"2011","journal-title":"Cryst. Growth Des."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"47437","DOI":"10.1021\/acsami.9b17348","article-title":"Facile Incorporation of Au Nanoparticles into an Unusual Twofold Entangled Zn(II)-MOF with Nanocages for Highly Efficient CO2 Fixation under Mild Conditions","volume":"11","author":"Wu","year":"2019","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"2300797","DOI":"10.1002\/advs.202300797","article-title":"MOF-on-MOF-Derived Hollow Co3O4\/In2O3 Nanostructure for Efficient Photocatalytic CO2 Reduction","volume":"10","author":"Han","year":"2023","journal-title":"Adv. Sci."},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Xu, L., Qiao, J., Xu, S., Zhao, X., Gong, W., and Huang, T. (2020). Constructing Strategies and Applications of Nitrogen-Rich Energetic Metal\u2013Organic Framework Materials. Catalysts, 10.","DOI":"10.3390\/catal10060690"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"2200763","DOI":"10.1002\/adfm.202200763","article-title":"Oxygen-Rich Cobalt\u2013Nitrogen\u2013Carbon Porous Nanosheets for Bifunctional Oxygen Electrocatalysis","volume":"32","author":"Zhang","year":"2022","journal-title":"Adv. Funct. Mater."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"104932","DOI":"10.1039\/C5RA22144G","article-title":"High and Selective CO2 Uptake in a Nitrogen-Rich Pillar-Layered Metal Organic Framework","volume":"5","author":"Chen","year":"2015","journal-title":"RSC Adv."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"2991","DOI":"10.1021\/acs.cgd.9b00190","article-title":"Enhanced Catalytic Performance for Oxygen Reduction Reaction Derived from Nitrogen-Rich Tetrazolate-Based Heterometallic Metal-Organic Frameworks","volume":"19","author":"Ji","year":"2019","journal-title":"Cryst. Growth Des."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"8213","DOI":"10.1021\/acs.inorgchem.0c00567","article-title":"A 2-Fold Interpenetrated Nitrogen-Rich Metal-Organic Framework for Rapid and Selective Adsorption of Congo Red","volume":"59","author":"Mao","year":"2020","journal-title":"Inorg. Chem."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"199","DOI":"10.1016\/j.inoche.2019.02.029","article-title":"Preferential CO2 Adsorption and Theoretical Simulation of a Cu(II)-Based Metal-Organic Framework with Open-Metal Sites and Basic Groups","volume":"102","author":"Gao","year":"2019","journal-title":"Inorg. Chem. Commun."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"6095","DOI":"10.1039\/D3NJ00140G","article-title":"Nitrogen-Rich Covalent Phosphazene-Based Framework for Efficient Removal of Lead(Ii) Ions","volume":"47","author":"Peng","year":"2023","journal-title":"New J. Chem."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"132451","DOI":"10.1016\/j.cej.2021.132451","article-title":"A New Sensitive Structural Motif Inlaying the Azides and Tetrazole-Based Rigid 3D Energetic MOFs: Highly Sensitive Primary Explosives with Excellent Thermal Stability","volume":"429","author":"Xu","year":"2022","journal-title":"J. Chem. Eng."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"2145","DOI":"10.1039\/C9DT04068D","article-title":"Tetrazole-Based Porous Metal-Organic Frameworks for Selective CO2 Adsorption and Isomerization Studies","volume":"49","author":"Zhang","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1016\/j.inoche.2019.04.021","article-title":"A Tetrazole-Containing Triphenylamine-Based Metal\u2013Organic Framework: Synthesis and Photocatalytic Oxidative C\u2013C Coupling Reaction","volume":"105","author":"Shi","year":"2019","journal-title":"Inorg. Chem. Commun."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"3223","DOI":"10.1039\/C7DT00005G","article-title":"Two New Metal-Organic Frameworks Based on Tetrazole-Heterocyclic Ligands Accompanied by in Situ Ligand Formation","volume":"46","author":"Li","year":"2017","journal-title":"Dalton Trans."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"3792","DOI":"10.1021\/ic802438n","article-title":"Tuning the Framework Topologies of CoII-Doped Zn II-Tetrazole-Benzoate Coordination Polymers by Ligand Modifications: Structures and Spectral Studies","volume":"48","author":"Song","year":"2009","journal-title":"Inorg. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"3402","DOI":"10.1039\/c2ce26793d","article-title":"Construction of Metal-Organic Coordination Polymers Derived from 4-Substituted Tetrazole-Benzoate Ligands: Synthesis, Structure, Luminescence, and Magnetic Behaviors","volume":"15","author":"Sun","year":"2013","journal-title":"CrystEngComm"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"193","DOI":"10.3390\/cryst5020193","article-title":"Synthesis of Framework Isomer MOFs Containing Zinc and 4-Tetrazolyl Benzenecarboxylic Acid via a Structure Directing Solvothermal Approach","volume":"5","author":"Ordonez","year":"2015","journal-title":"Crystals"},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"7945","DOI":"10.1021\/ic800761h","article-title":"A Novel Metal-Organic Network with High Thermal Stability: Nonlinear Optical and Photoluminescent Properties","volume":"47","author":"Li","year":"2008","journal-title":"Inorg. Chem."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"87400","DOI":"10.1039\/C5RA14637B","article-title":"Amide Functionalized Metal-Organic Frameworks for Diastereoselective Nitroaldol (Henry) Reaction in Aqueous Medium","volume":"5","author":"Paul","year":"2015","journal-title":"RSC Adv."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"12970","DOI":"10.1039\/D0DT02172E","article-title":"A Mechanistic Insight into the Rapid and Selective Removal of Congo Red by an Amide Functionalised Zn(II) Coordination Polymer","volume":"49","author":"Paul","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"699","DOI":"10.3389\/fchem.2019.00699","article-title":"Highly Efficient Bifunctional Amide Functionalized Zn and Cd Metal Organic Frameworks for One-Pot Cascade Deacetalization\u2013Knoevenagel Reactions","volume":"7","author":"Karmakar","year":"2019","journal-title":"Front. Chem."},{"key":"ref_31","doi-asserted-by":"crossref","unstructured":"Paul, A., Martins, L.M.D.R.S., Karmakar, A., Kuznetsov, M.L., C Guedes da Silva, M.F., and Pombeiro, A.J.L. (2020). Zn(II)-to-Cu(II) Transmetalation in an Amide Functionalized Complex and Catalytic Applications in Styrene Oxidation and Nitroaldol Coupling. Molecules, 25.","DOI":"10.3390\/molecules25112644"},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"324","DOI":"10.1016\/j.jcat.2020.03.035","article-title":"Environmentally Benign Benzyl Alcohol Oxidation and C\u2013C Coupling Catalysed by Amide Functionalized 3D Co(II) and Zn(II) Metal Organic Frameworks","volume":"385","author":"Paul","year":"2020","journal-title":"J. Catal."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"16301","DOI":"10.1021\/acs.inorgchem.0c02084","article-title":"Versatility of Amide-Functionalized Co(II) and Ni(II) Coordination Polymers: From Thermochromic-Triggered Structural Transformations to Supercapacitors and Electrocatalysts for Water Splitting","volume":"59","author":"Paul","year":"2020","journal-title":"Inorg. Chem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"18473","DOI":"10.1021\/acs.inorgchem.1c03044","article-title":"Amide-Functionalized Metal-Organic Frameworks Coupled with Open Fe\/Sc Sites for Efficient Acetylene Purification","volume":"60","author":"Fan","year":"2021","journal-title":"Inorg. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"32598","DOI":"10.1039\/C6RA01536K","article-title":"Amine-Functionalized Metal-Organic Frameworks: Structure, Synthesis and Applications","volume":"6","author":"Lin","year":"2016","journal-title":"RSC Adv."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"e202300694","DOI":"10.1002\/cctc.202300694","article-title":"Metal-Organic Gels of Tris-Tetrazole-tri-Amido Molecule with Co(II) and Ni(II) as Electrocatalysts for OER: Effect of Metal Ion, Porosity and Morphology on the Catalysis of MOGs","volume":"15","author":"Moi","year":"2023","journal-title":"ChemCatChem"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"7315","DOI":"10.1039\/c3ce41002a","article-title":"Bin Two Photoluminescent Metal-Organic Frameworks Based on a BODIPY-Derived Bipyridine Ligand","volume":"15","author":"Zhou","year":"2013","journal-title":"CrystEngComm"},{"key":"ref_38","doi-asserted-by":"crossref","unstructured":"Peedikakkal, A.M.P., and Aljund, I.H. (2021). Upgrading the Hydrogen Storage of Mof-5 by Post-Synthetic Exchange with Divalent Metal Ions. Appl. Sci., 11.","DOI":"10.3390\/app112411687"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"955","DOI":"10.1039\/B617136B","article-title":"Structural Variation in Copper(I) Complexes with Pyridylmethylamide Ligands: Structural Analysis with a New Four-Coordinate Geometry Index, \u03a44","volume":"9","author":"Yang","year":"2007","journal-title":"Dalton Trans."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"1800173","DOI":"10.1002\/smtd.201800173","article-title":"Evaluation of the BET Theory for the Characterization of Meso and Microporous MOFs","volume":"2","author":"Ambroz","year":"2018","journal-title":"Small Methods"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"33723","DOI":"10.1021\/acsami.6b12458","article-title":"Rapid, Microwave-Assisted Synthesis of Cubic, Three-Dimensional, Highly Porous MOF-205 for Room Temperature CO2 Fixation via Cyclic Carbonate Synthesis","volume":"8","author":"Babu","year":"2016","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"280","DOI":"10.1039\/C5CC07781H","article-title":"A Sustainable Protocol for the Facile Synthesis of Zinc-Glutamate MOF: An Efficient Catalyst for Room Temperature CO2 Fixation Reactions under Wet Conditions","volume":"52","author":"Kathalikkattil","year":"2016","journal-title":"Chem. Commun."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"8041","DOI":"10.1039\/C8DT01297K","article-title":"Amine-Functionalized Zn(II) MOF as an Efficient Multifunctional Catalyst for CO2 Utilization and Sulfoxidation Reaction","volume":"47","author":"Patel","year":"2018","journal-title":"Dalton Trans."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"77","DOI":"10.1039\/D0GC03465G","article-title":"Recent Developments in Organocatalysed Transformations of Epoxides and Carbon Dioxide into Cyclic Carbonates","volume":"23","author":"Guo","year":"2021","journal-title":"Green. Chem."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"1118","DOI":"10.1039\/D1RE00090J","article-title":"CO2 adsorption Mechanisms on MOFs: A Case Study of Open Metal Sites, Ultra-Microporosity and Flexible Framework","volume":"6","author":"Maia","year":"2021","journal-title":"React. Chem. Eng."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"13686","DOI":"10.1002\/chem.202002996","article-title":"Zinc Imine Polyhedral Oligomeric Silsesquioxane as a Quattro-Site Catalyst for the Synthesis of Cyclic Carbonates from Epoxides and Low-Pressure CO2","volume":"26","author":"Janeta","year":"2020","journal-title":"Chem.\u2014Eur. J."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1002\/cctc.201800908","article-title":"Self-Assembled Ionic Composites of Negatively Charged Zn(Salen) Complexes and Triphenylmethane Derived Polycations as Recyclable Catalysts for the Addition of Carbon Dioxide to Epoxides","volume":"11","author":"Kuznetsova","year":"2019","journal-title":"ChemCatChem"},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"13917","DOI":"10.1021\/acs.inorgchem.9b01762","article-title":"Porous Zn(Bmic)(AT) MOF with Abundant Amino Groups and Open Metal Sites for Efficient Capture and Transformation of CO2","volume":"58","author":"Li","year":"2019","journal-title":"Inorg. Chem."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"121700","DOI":"10.1016\/j.cej.2019.05.061","article-title":"Multi-Variate Metal Organic Framework as Efficient Catalyst for the Cycloaddition of CO2 and Epoxides in a Gas-Liquid-Solid Reactor","volume":"386","author":"Kurisingal","year":"2020","journal-title":"J. Chem. Eng."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"216","DOI":"10.1016\/j.jcou.2019.09.019","article-title":"A Novel Water-Stable MOF Zn(Py)(Atz) as Heterogeneous Catalyst for Chemical Conversion of CO2 with Various Epoxides under Mild Conditions","volume":"35","author":"Lan","year":"2020","journal-title":"J. CO2 Util."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"2795","DOI":"10.1021\/acssuschemeng.0c08466","article-title":"A High-Performance Zinc-Organic Framework with Accessible Open Metal Sites Catalyzes CO2 and Styrene Oxide into Styrene Carbonate under Mild Conditions","volume":"9","author":"Li","year":"2021","journal-title":"ACS Sustain. Chem. Eng."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"101718","DOI":"10.1016\/j.jcou.2021.101718","article-title":"Cyclic Carbonates Synthesis from Epoxides and CO2 over NIIC-10 Metal-Organic Frameworks","volume":"53","author":"Bondarenko","year":"2021","journal-title":"J. CO2 Util."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"115850","DOI":"10.1016\/j.poly.2022.115850","article-title":"Bin A Novel 2D Zinc(II)-Organic Framework for Efficient Catalytic Cycloaddition of CO2 with Epoxides","volume":"220","author":"Li","year":"2022","journal-title":"Polyhedron"},{"key":"ref_54","unstructured":"Bruker (2012). APEX2, Bruker AXS Inc."},{"key":"ref_55","unstructured":"Sheldrick, G.M. (2000). SADABS Program for Empirical Absorption Correction, University of Gottingen."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","article-title":"Crystal Structure Refinement with SHELXL","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. C Struct. Chem."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","article-title":"WinGX and ORTEP for Windows: An Update","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Crystallogr."}],"container-title":["Catalysts"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-4344\/14\/1\/6\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T21:41:59Z","timestamp":1760132519000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-4344\/14\/1\/6"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,12,20]]},"references-count":57,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2024,1]]}},"alternative-id":["catal14010006"],"URL":"https:\/\/doi.org\/10.3390\/catal14010006","relation":{},"ISSN":["2073-4344"],"issn-type":[{"value":"2073-4344","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,12,20]]}}}