{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,26]],"date-time":"2026-03-26T18:59:48Z","timestamp":1774551588439,"version":"3.50.1"},"reference-count":99,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2019,2,26]],"date-time":"2019-02-26T00:00:00Z","timestamp":1551139200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"the Russian Foundation for Basic Research","award":["16-03-00254 and 18-03-00155"],"award-info":[{"award-number":["16-03-00254 and 18-03-00155"]}]},{"name":"the Fundac\u0327a\u0303o para a Cie\u0302ncia e a Tecnologia (FCT), Portugal","award":["UID\/QUI\/00100\/2013 and PTDC\/QEQ-QIN\/3967\/2014"],"award-info":[{"award-number":["UID\/QUI\/00100\/2013 and PTDC\/QEQ-QIN\/3967\/2014"]}]},{"name":"RUDN University Program \u201c5-100\u201d","award":["5-100"],"award-info":[{"award-number":["5-100"]}]},{"name":"the Initiative Programs, the State Task 0082-2014-0007","award":["\u0410\u0410\u0410\u0410-\u041016-116020350251-6"],"award-info":[{"award-number":["\u0410\u0410\u0410\u0410-\u041016-116020350251-6"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Catalysts"],"abstract":"<jats:p>Reactions of [VCl3(thf)3] or VBr3 with 2,2\u2032-bipyridine (bpy) or 1,10-phenanthroline (phen) in a 1:1 molar ratio in air under solventothermal conditions has afforded polymeric oxidovanadium(IV) four complexes 1\u20134 of a general formula [VO(L)X2]n (L = bpy, phen and X = Cl, Br). Monomeric complex [VO(DMF)(phen)Br2] (4a) has been obtained by the treatment of compound 4 with DMF. The complexes were characterized by IR spectroscopy and elemental analysis. The crystal structures of 3 and 4a were determined by an X-ray diffraction (XRD) analysis. The {VOBr2(bpy)} fragments in 3 form infinite chains due to the V = O\u2026V interactions. The vanadium atom has a distorted octahedral coordination environment. Complexes 1\u20134 have been tested as catalysts in the homogeneous oxidation of alkanes (to produce corresponding alkyl hydroperoxides which can be easily reduced to alcohols by PPh3) and alcohols (to corresponding ketones) with H2O2 or tert-butyl hydroperoxide in MeCN. Compound 1 exhibited the highest activity. The mechanism of alkane oxidation was established using experimental selectivity and kinetic data and theoretical DFT calculations. The mechanism is of the Fenton type involving the generation of HO\u2022 radicals.<\/jats:p>","DOI":"10.3390\/catal9030217","type":"journal-article","created":{"date-parts":[[2019,2,27]],"date-time":"2019-02-27T11:41:03Z","timestamp":1551267663000},"page":"217","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":27,"title":["New Oxidovanadium(IV) Complexes with 2,2\u2032-bipyridine and 1,10-phenathroline Ligands: Synthesis, Structure and High Catalytic Activity in Oxidations of Alkanes and Alcohols with Peroxides"],"prefix":"10.3390","volume":"9","author":[{"given":"Iakov S.","family":"Fomenko","sequence":"first","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Prospekt Acad. Lavrentieva, dom 3, 630090 Novosibirsk, Russia"}]},{"given":"Artem L.","family":"Gushchin","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Prospekt Acad. Lavrentieva, dom 3, 630090 Novosibirsk, Russia"},{"name":"Novosibirsk State University, ul. Pirogova, dom 2, 630090 Novosibirsk, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4479-5100","authenticated-orcid":false,"given":"Pavel A.","family":"Abramov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Prospekt Acad. Lavrentieva, dom 3, 630090 Novosibirsk, Russia"},{"name":"Novosibirsk State University, ul. Pirogova, dom 2, 630090 Novosibirsk, Russia"}]},{"given":"Maksim N.","family":"Sokolov","sequence":"additional","affiliation":[{"name":"Nikolaev Institute of Inorganic Chemistry, Siberian Branch of Russian Academy of Sciences, Prospekt Acad. Lavrentieva, dom 3, 630090 Novosibirsk, Russia"},{"name":"Novosibirsk State University, ul. Pirogova, dom 2, 630090 Novosibirsk, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1448-9228","authenticated-orcid":false,"given":"Lidia S.","family":"Shul'pina","sequence":"additional","affiliation":[{"name":"Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova, dom 28, 119991 Moscow, Russia"}]},{"given":"Nikolay S.","family":"Ikonnikov","sequence":"additional","affiliation":[{"name":"Nesmeyanov Institute of Organoelement Compounds, Russian Academy of Sciences, ul. Vavilova, dom 28, 119991 Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5729-6189","authenticated-orcid":false,"given":"Maxim L.","family":"Kuznetsov","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Avenida Rovisco Pais, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8323-888X","authenticated-orcid":false,"given":"Armando J. L.","family":"Pombeiro","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Avenida Rovisco Pais, 1049-001 Lisboa, Portugal"}]},{"given":"Yuriy N.","family":"Kozlov","sequence":"additional","affiliation":[{"name":"Semenov Institute of Chemical Physics, Department of Dynamics of Chemical and Biological Processes, Russian Academy of Sciences, ul. Kosygina, dom 4, 119991 Moscow, Russia"},{"name":"Chair of Chemistry and Physics, Plekhanov Russian University of Economics, Stremyannyi pereulok, dom 36, 117997 Moscow, Russia"}]},{"given":"Georgiy B.","family":"Shul\u2019pin","sequence":"additional","affiliation":[{"name":"Semenov Institute of Chemical Physics, Department of Dynamics of Chemical and Biological Processes, Russian Academy of Sciences, ul. Kosygina, dom 4, 119991 Moscow, Russia"},{"name":"Chair of Chemistry and Physics, Plekhanov Russian University of Economics, Stremyannyi pereulok, dom 36, 117997 Moscow, Russia"},{"name":"RussiaPeople\u2019s Friendship University of Russia, ul. Miklukho-Maklaya, dom 6, 117198 Moscow, Russia"}]}],"member":"1968","published-online":{"date-parts":[[2019,2,26]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2879","DOI":"10.1021\/cr9411886","article-title":"Activation of C\u2013H Bonds by Metal Complexes","volume":"97","author":"Shilov","year":"1997","journal-title":"Chem. Rev."},{"key":"ref_2","unstructured":"Shilov, A.E., and Shul\u2019pin, G.B. (2002). Activation and Catalytic Reactions of Saturated Hydrocarbons in the Presence of Metal Complexes, Kluwer Academic Publishers."},{"key":"ref_3","first-page":"215","article-title":"Oxidations of C\u2013H Compounds Catalyzed by Metal Complexes","volume":"Volume 2","author":"Beller","year":"2004","journal-title":"Transition Metals for Organic Synthesis"},{"key":"ref_4","first-page":"95","article-title":"Metal-catalysed hydrocarbon oxidations","volume":"6","year":"2009","journal-title":"Mini-Rev. Org. 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