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metal-organic framework (MOF), UiO-66(Hf), modified with a very small amount of meso-tetrakis(4-carboxyphenyl) N-methylpyrrolidine-fused chlorin (TCPC), TCPC@MOF. Chlorin\u2019s incorporation into the UiO-66(Hf) framework was verified by several characterization methods and revealed that the as-synthesized TCPC@MOF brings together the chemical stability of UiO-66(Hf) and the photophysical properties of the pyrrolidine-fused chlorin which is about five times more emissive than the porphyrin counterpart. TCPC@MOF was further incorporated into polydimethylsiloxane (PDMS) and the resulting TCPC@MOF@PDMS film was tested in NO2 gas sensing. It showed notable sensitivity as well as a fast response in the range between 0.5 and 500 ppm where an emission intensity quenching is observed up to 96% for 500 ppm. This is a rare example of a chlorin-derivative used for gas-sensing applications through emission changes, and an unusual case of this type of optical-sensing composites of NO2.<\/jats:p>","DOI":"10.3390\/chemosensors10120511","type":"journal-article","created":{"date-parts":[[2022,12,1]],"date-time":"2022-12-01T05:30:46Z","timestamp":1669872646000},"page":"511","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["MOF-Based Materials with Sensing Potential: Pyrrolidine-Fused Chlorin at UiO-66(Hf) for Enhanced NO2 Detection"],"prefix":"10.3390","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0485-8023","authenticated-orcid":false,"given":"Carla","family":"Queir\u00f3s","sequence":"first","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6030-0449","authenticated-orcid":false,"given":"Francisco G.","family":"Moscoso","sequence":"additional","affiliation":[{"name":"Department of Physical, Chemical and Natural Systems, University Pablo de Olavide, Ctra. Utrera Km. 1, 41013 Sevilla, Spain"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2656-6443","authenticated-orcid":false,"given":"Jos\u00e9","family":"Almeida","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0393-1655","authenticated-orcid":false,"given":"Ana M. G.","family":"Silva","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7064-7841","authenticated-orcid":false,"given":"Ahmad","family":"Sousaraei","sequence":"additional","affiliation":[{"name":"Madrid Institute for Advanced Studies in Nanoscience, IMDEA Nanociencia, Universitaria de Cantoblanco, Calle Faraday 9, 28049 Madrid, Spain"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9926-3833","authenticated-orcid":false,"given":"Juan","family":"Cabanillas-Gonz\u00e1lez","sequence":"additional","affiliation":[{"name":"Madrid Institute for Advanced Studies in Nanoscience, IMDEA Nanociencia, Universitaria de Cantoblanco, Calle Faraday 9, 28049 Madrid, Spain"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4856-5150","authenticated-orcid":false,"given":"Manuela","family":"Ribeiro Carrott","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Institute for Research and Advanced Studies, Department of Chemistry and Biochemistry, School of Sciences and Technology, University of \u00c9vora, 7000-671 \u00c9vora, Portugal"}]},{"given":"T\u00e2nia","family":"Lopes-Costa","sequence":"additional","affiliation":[{"name":"Department of Physical, Chemical and Natural Systems, University Pablo de Olavide, Ctra. Utrera Km. 1, 41013 Sevilla, Spain"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8750-6220","authenticated-orcid":false,"given":"Jos\u00e9 M.","family":"Pedrosa","sequence":"additional","affiliation":[{"name":"Department of Physical, Chemical and Natural Systems, University Pablo de Olavide, Ctra. Utrera Km. 1, 41013 Sevilla, Spain"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9229-1412","authenticated-orcid":false,"given":"Lu\u00eds","family":"Cunha-Silva","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,12,1]]},"reference":[{"key":"ref_1","unstructured":"(2021, October 12). Briefing: Europe\u2019s Air Quality Status. 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