{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,13]],"date-time":"2026-03-13T11:41:54Z","timestamp":1773402114250,"version":"3.50.1"},"reference-count":98,"publisher":"MDPI AG","issue":"2","license":[{"start":{"date-parts":[[2024,4,30]],"date-time":"2024-04-30T00:00:00Z","timestamp":1714435200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Funda\u00e7\u00e3o para a Cin\u00eancia e a Tecnologia\/Minist\u00e9rio da Ci\u00eancia, Tecnologia e Ensino Superior (FCT\/MCTES)","award":["UIDP\/50006\/2020"],"award-info":[{"award-number":["UIDP\/50006\/2020"]}]},{"name":"Funda\u00e7\u00e3o para a Cin\u00eancia e a Tecnologia\/Minist\u00e9rio da Ci\u00eancia, Tecnologia e Ensino Superior (FCT\/MCTES)","award":["LA\/P\/0008\/2020"],"award-info":[{"award-number":["LA\/P\/0008\/2020"]}]},{"name":"Funda\u00e7\u00e3o para a Cin\u00eancia e a Tecnologia\/Minist\u00e9rio da Ci\u00eancia, Tecnologia e Ensino Superior (FCT\/MCTES)","award":["UIDB\/50006\/2020"],"award-info":[{"award-number":["UIDB\/50006\/2020"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Compounds"],"abstract":"<jats:p>Metal\u2013organic frameworks (MOFs) have been the subject of extensive scientific investigation in the last three decades and, currently, they make up one of the types of compounds most studied for their potential application in a wide range of distinct catalytic processes. Pristine MOF compounds provide several intriguing benefits for catalytic applications, including large interior surface areas and high densities of active sites; high catalytic reaction rates per volume; post-synthesis modifications with complementary catalytic groups; and the ability for multiple functional groups to catalyze the reaction. For most large-scale catalytic applications, including those in fuel processing, gas emission reduction, and chemical synthesis, pristine MOFs often show limited stabilities and opportunities for regeneration at high temperatures. As a result, the real applications of MOFs in these technologies are likely to be constrained, and a controlled thermal modification to prepare MOF-derivative compounds has been applied to induce crystalline structural changes and increase the structural stability of the MOFs, enhancing their potential applicability in more severe catalytic processes. Recent advances concerning the use of this strategy to boost the catalytic potential of MOF-derivative compounds, particularly for stable Zr-based MOFs, are outlined in this short review article.<\/jats:p>","DOI":"10.3390\/compounds4020017","type":"journal-article","created":{"date-parts":[[2024,5,2]],"date-time":"2024-05-02T12:06:38Z","timestamp":1714651598000},"page":"315-337","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Recent Advances in Catalytic Compounds Developed by Thermal Treatment of (Zr-Based) Metal\u2013Organic Frameworks"],"prefix":"10.3390","volume":"4","author":[{"given":"Catarina E. S.","family":"Ferreira","sequence":"first","affiliation":[{"name":"LAQV-REQUIMTE & Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias da Universidade do Porto, Rua do Campo Alegre, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8984-0473","authenticated-orcid":false,"given":"Salete S.","family":"Balula","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE & Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias da Universidade do Porto, Rua do Campo Alegre, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9229-1412","authenticated-orcid":false,"given":"Lu\u00eds","family":"Cunha-Silva","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE & Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias da Universidade do Porto, Rua do Campo Alegre, 4169-007 Porto, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2024,4,30]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"407","DOI":"10.1021\/acs.accounts.6b00526","article-title":"Pore Space Partition in Metal-Organic Frameworks","volume":"50","author":"Zhai","year":"2017","journal-title":"Acc. Chem. Res."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"32955","DOI":"10.1039\/D1RA05058C","article-title":"Study on the performance of a MOF-808-based photocatalyst prepared by a microwave-assisted method for the degradation of antibiotics","volume":"11","author":"Wang","year":"2021","journal-title":"Rsc. Adv."},{"key":"ref_3","unstructured":"Xu, R., Pang, W., and Huo, Q. (2011). Modern Inorganic Synthetic Chemistry, Elsevier."},{"key":"ref_4","first-page":"2","article-title":"Alterations to secondary building units of metal\u2013organic frameworks for the development of new functions","volume":"7","author":"Ha","year":"2019","journal-title":"Inorg. Chem. Front."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"011306","DOI":"10.1063\/5.0075283","article-title":"Coordination polymers for emerging molecular devices","volume":"3","author":"Morritt","year":"2022","journal-title":"Chem. Phys. Rev."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"64","DOI":"10.1016\/j.micromeso.2011.12.010","article-title":"Modulated synthesis of Zr-fumarate MOF","volume":"152","author":"Schaate","year":"2012","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_7","doi-asserted-by":"crossref","unstructured":"Raptopoulou, C.P. (2021). Metal-Organic Frameworks: Synthetic Methods and Potential Applications. Materials, 14.","DOI":"10.3390\/ma14020310"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"18","DOI":"10.51167\/acm00007","article-title":"Reticular Chemistry and Harvesting Water from Desert Air","volume":"1","author":"Liu","year":"2020","journal-title":"ACM"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"5432","DOI":"10.1002\/adma.201501523","article-title":"Flexible Metal-Organic Frameworks: Recent Advances and Potential Applications","volume":"27","author":"Chang","year":"2015","journal-title":"Adv. Mater."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"135261","DOI":"10.1016\/j.chemosphere.2022.135261","article-title":"Recent developments in MOF and MOF based composite as potential adsorbents for removal of aqueous environmental contaminants","volume":"304","author":"Darabdhara","year":"2022","journal-title":"Chemosphere"},{"key":"ref_11","doi-asserted-by":"crossref","unstructured":"Han, Y., Yang, H., and Gua, X. (2020). Synthesis Methods and Crystallization, IntechOpen.","DOI":"10.5772\/intechopen.90435"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"3539","DOI":"10.1021\/acs.cgd.5b00719","article-title":"Interpenetrated Frameworks with Anisotropic Pore Structures from a Tetrahedral Pyridine Ligand","volume":"15","author":"Geyer","year":"2015","journal-title":"Cryst. Growth Des."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"114897","DOI":"10.1016\/j.poly.2020.114897","article-title":"A comprehensive review on synthetic approaches for metal-organic frameworks: From traditional solvothermal to greener protocols","volume":"193","author":"Sud","year":"2021","journal-title":"Polyhedron"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"401","DOI":"10.1016\/j.trac.2019.06.007","article-title":"A review on metal-organic frameworks: Synthesis and applications","volume":"118","author":"Safaei","year":"2019","journal-title":"TrAC Trends Anal. Chem."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"112223","DOI":"10.1016\/j.inoche.2024.112223","article-title":"Metal-organic frameworks: Recent advances in synthesis strategies and applications","volume":"162","author":"Mathew","year":"2024","journal-title":"Inorg. Chem. Commun."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"59","DOI":"10.1016\/j.poly.2019.01.024","article-title":"Mechanochemical synthesis of metal\u2013organic frameworks","volume":"162","author":"Chen","year":"2019","journal-title":"Polyhedron"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1152","DOI":"10.1016\/j.cej.2010.11.098","article-title":"Facile synthesis of nano-sized metal-organic frameworks, chromium-benzenedicarboxylate, MIL-101","volume":"166","author":"Hhan","year":"2011","journal-title":"Chem. Eng. J."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"140","DOI":"10.3390\/cleantechnol5010009","article-title":"Synthesis of Metal Organic Frameworks (MOFs) and Their Derived Materials for Energy Storage Applications","volume":"5","author":"Dutt","year":"2023","journal-title":"Clean Technol."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"2580","DOI":"10.1021\/cm900069f","article-title":"Patterned Growth of Metal-Organic Framework Coatings by Electrochemical Synthesis","volume":"21","author":"Ameloot","year":"2009","journal-title":"Chem. Mater."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"186","DOI":"10.1016\/j.micromeso.2014.10.034","article-title":"A water-born Zr-based porous coordination polymer: Modulated synthesis of Zr-fumarate MOF","volume":"203","author":"Zahn","year":"2015","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"1200250","DOI":"10.1016\/j.ica.2020.120025","article-title":"New fast synthesis of MOF-801 for water and hydrogen storage: Modulator effect and recycling options","volume":"514","author":"Butova","year":"2021","journal-title":"Inorganica Chim. Acta"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"6643","DOI":"10.1002\/chem.201003211","article-title":"Modulated Synthesis of Zr-Based Metal\u2013Organic Frameworks: From Nano to Single Crystals","volume":"17","author":"Schaate","year":"2011","journal-title":"Chem. Eur. J."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"2327","DOI":"10.1039\/C5CS00837A","article-title":"Zr-based metal-organic frameworks: Design, synthesis, structure, and applications","volume":"45","author":"Bai","year":"2016","journal-title":"Chem. Soc. Rev."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"4539","DOI":"10.1021\/acs.inorgchem.0c03472","article-title":"A Zr-Based Metal\u2013Organic Framework with a DUT-52 Structure Containing a Trifluoroacetamido-Functionalized Linker for Aqueous Phase Fluorescence Sensing of the Cyanide Ion and Aerobic Oxidation of Cyclohexane","volume":"60","author":"Gogoi","year":"2021","journal-title":"Inorg. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"4032","DOI":"10.1039\/D1SE00522G","article-title":"Synergistic combination of the nanoporous system of MOF-808 with a polyoxomolybdate to design an effective catalyst: Simultaneous oxidative desulfurization and denitrogenation processes","volume":"5","author":"Fernandes","year":"2021","journal-title":"Sustain. Energ. Fuels"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"673","DOI":"10.1021\/cr300014x","article-title":"Introduction to Metal-Organic Frameworks","volume":"112","author":"Zhou","year":"2012","journal-title":"Chem. Rev."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"13009","DOI":"10.1021\/acs.inorgchem.8b02272","article-title":"Encapsulation of Phosphotungstic Acid into Metal-Organic Frameworks with Tunable Window Sizes: Screening of PTA@MOF Catalysts for Efficient Oxidative Desulfurization","volume":"57","author":"Lin","year":"2018","journal-title":"Inorg. Chem."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"1703663","DOI":"10.1002\/adma.201703663","article-title":"Metal\u2013Organic Frameworks as Platforms for Catalytic Applications","volume":"30","author":"Jiao","year":"2017","journal-title":"Adv. Mater."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"10209","DOI":"10.1039\/C9SC03916C","article-title":"Improving MOF stability: Approaches and applications","volume":"10","author":"Ding","year":"2019","journal-title":"Chem. Sci."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"13850","DOI":"10.1021\/ja8057953","article-title":"A new zirconium inorganic building brick forming metal organic frameworks with exceptional stability","volume":"130","author":"Cavka","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref_31","first-page":"244","article-title":"Creation of Active Sites in MOF-808(Zr) by a Facile Route for Oxidative Desulfurization of Model Diesel Oil","volume":"5","author":"Gu","year":"2020","journal-title":"Chem. Sel."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"3006","DOI":"10.1021\/acs.chemmater.6b05444","article-title":"Missing Linkers: An Alternative Pathway to UiO-66 Electronic Structure Engineering","volume":"29","author":"Hendrickx","year":"2017","journal-title":"Chem. Mater."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"3701","DOI":"10.1002\/ejic.201000473","article-title":"Metals@MOFs\u2014Loading MOFs with Metal Nanoparticles for Hybrid Functions","volume":"2010","author":"Meilikhov","year":"2010","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"3437","DOI":"10.1021\/acs.jpclett.5b01135","article-title":"Defects in Metal-Organic Frameworks: Challenge or Opportunity?","volume":"6","author":"Sholl","year":"2015","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"4137","DOI":"10.1039\/C7CE00224F","article-title":"Using water adsorption measurements to access the chemistry of defects in the metal-organic framework UiO-66","volume":"19","author":"Dissegna","year":"2017","journal-title":"Crystengcomm"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"6804","DOI":"10.1002\/chem.202005050","article-title":"Tuning the Properties of MOF-808 via Defect Engineering and Metal Nanoparticle Encapsulation","volume":"27","author":"Hardian","year":"2021","journal-title":"Chem. Eur. J."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"14297","DOI":"10.1002\/chem.201602641","article-title":"Ruthenium Metal-Organic Frameworks with Different Defect Types: Influence on Porosity, Sorption, and Catalytic Properties","volume":"22","author":"Zhang","year":"2016","journal-title":"Chem. Eur. J."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"3417","DOI":"10.1002\/anie.201410252","article-title":"\u201cHeterogeneity within Order\u201d in Metal\u2013Organic Frameworks","volume":"54","author":"Furukawa","year":"2015","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1016\/j.cclet.2017.09.057","article-title":"Continuous synthesis for zirconium metal-organic frameworks with high quality and productivity via microdroplet flow reaction","volume":"29","author":"Wang","year":"2017","journal-title":"Chin. Chem. Lett."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"2541","DOI":"10.1039\/D2CC06948B","article-title":"Zr- and Ti-based metal\u2013organic frameworks: Synthesis, structures and catalytic applications","volume":"59","author":"Li","year":"2023","journal-title":"Chem. Commun."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"7086","DOI":"10.1021\/ic5012764","article-title":"Porous zirconium metal-organic framework constructed from 2D \u2192 3D interpenetration based on a 3,6-connected kgd net","volume":"53","author":"Wang","year":"2014","journal-title":"Inorg. Chem."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"2270","DOI":"10.1021\/acs.inorgchem.6b02969","article-title":"Green Synthesis of Zr-CAU-28: Structure and Properties of the First Zr-MOF Based on 2,5-Furandicarboxylic Acid","volume":"56","author":"Dreischarf","year":"2017","journal-title":"Inorg. Chem."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"213526","DOI":"10.1016\/j.ccr.2020.213526","article-title":"Metal-organic frameworks as advanced adsorbents for pharmaceutical and personal care products","volume":"425","author":"Jin","year":"2020","journal-title":"Coord. Chem. Rev."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"1704303","DOI":"10.1002\/adma.201704303","article-title":"Stable Metal\u2013Organic Frameworks: Design, Synthesis, and Applications","volume":"30","author":"Yuan","year":"2018","journal-title":"Adv. Mater."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"12844","DOI":"10.1021\/ja507119n","article-title":"Superacidity in sulfated metal-organic framework-808","volume":"136","author":"Jiang","year":"2014","journal-title":"J. Am. Chem. Soc."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"890","DOI":"10.1016\/j.ijhydene.2013.10.087","article-title":"Modulated synthesis of zirconium-metal organic framework (Zr-MOF) for hydrogen storage applications","volume":"39","author":"Ren","year":"2014","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"2006291","DOI":"10.1002\/adfm.202006291","article-title":"Post-Synthetic Modification of Metal\u2013Organic Frameworks Toward Applications","volume":"31","author":"Mandal","year":"2021","journal-title":"Adv. Funct. Mater."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"15018","DOI":"10.1038\/natrevmats.2015.18","article-title":"Chemical, thermal and mechanical stabilities of metal\u2013organic frameworks","volume":"1","author":"Howarth","year":"2016","journal-title":"Nat. Rev. Mater."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"455","DOI":"10.1126\/science.1230444","article-title":"The chemistry and applications of metal-organic frameworks","volume":"341","author":"Furukawa","year":"2013","journal-title":"Science"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"520","DOI":"10.1021\/acsenergylett.9b02625","article-title":"Metal\u2013Organic Framework-Based Materials for Energy Conversion and Storage","volume":"5","author":"Qiu","year":"2020","journal-title":"ACS Energy Lett."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"121","DOI":"10.1038\/nature03968","article-title":"A general strategy for nanocrystal synthesis","volume":"437","author":"Wang","year":"2005","journal-title":"Nature"},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"616","DOI":"10.1039\/B919421E","article-title":"Aminoclay: A permselective matrix to stabilize copper nanoparticles","volume":"46","author":"Datta","year":"2010","journal-title":"Chem. Commun."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"1175","DOI":"10.1007\/s11172-010-0220-2","article-title":"Influence of the nature of organic ligands on the character of thermal decomposition products of CoII and NiII pivalate complexes with amino derivatives of pyridine","volume":"59","author":"Fomina","year":"2010","journal-title":"Russ. Chem. Bull."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"5390","DOI":"10.1021\/ja7106146","article-title":"Metal-organic framework as a template for porous carbon synthesis","volume":"130","author":"Liu","year":"2008","journal-title":"J. Am. Chem. Soc."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"29","DOI":"10.1007\/s41918-018-0024-x","article-title":"Metal\u2013Organic Frameworks (MOFs) and MOF-Derived Materials for Energy Storage and Conversion","volume":"2","author":"Zhang","year":"2018","journal-title":"Electrochem. Energy Rev."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"122431","DOI":"10.1016\/j.cej.2019.122431","article-title":"Ce(III) nanocomposites by partial thermal decomposition of Ce-MOF for effective phosphate adsorption in a wide pH range","volume":"379","author":"He","year":"2020","journal-title":"Chem. Eng. J."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"1837","DOI":"10.1039\/C5EE00762C","article-title":"Metal\u2013organic frameworks and their derived nanostructures for electrochemical energy storage and conversion","volume":"8","author":"Xia","year":"2015","journal-title":"Energy Environ. Sci."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"25562","DOI":"10.1039\/C7TA08314A","article-title":"Controlled pyrolysis of MIL-88A to Fe2O3@C nanocomposites with varied morphologies and phases for advanced lithium storage","volume":"5","author":"Wang","year":"2017","journal-title":"J. Mater. Chem. A"},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"5887","DOI":"10.1021\/acscatal.6b01222","article-title":"Development of MOF-Derived Carbon-Based Nanomaterials for Efficient Catalysis","volume":"6","author":"Shen","year":"2016","journal-title":"ACS Catal."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"88","DOI":"10.1016\/j.mattod.2018.10.016","article-title":"MOF-derived carbonaceous materials enriched with nitrogen: Preparation and applications in adsorption and catalysis","volume":"25","author":"Bhadra","year":"2019","journal-title":"Mater. Today"},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"9","DOI":"10.1016\/j.chroma.2015.03.033","article-title":"Iron oxide functionalized graphene nano-composite for dispersive solid phase extraction of chemical warfare agents from aqueous samples","volume":"1394","author":"Chinthakindi","year":"2015","journal-title":"J. Chromatogr. A"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"1709","DOI":"10.1039\/C7QM00007C","article-title":"Metal organic frameworks as precursors for the manufacture of advanced catalytic materials","volume":"1","author":"Wezendonk","year":"2017","journal-title":"Mater. Chem. Front."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"12125","DOI":"10.3390\/molecules200712125","article-title":"Post-Synthetic Shaping of Porosity and Crystal Structure of Ln-Bipy-MOFs by Thermal Treatment","volume":"20","author":"Matthes","year":"2015","journal-title":"Molecules"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"119643","DOI":"10.1016\/j.seppur.2021.119643","article-title":"Controlled thermal treatment of NH2-MIL-125(Ti) for drastically enhanced photocatalytic reduction of Cr(VI)","volume":"277","author":"Mo","year":"2021","journal-title":"Sep. Purif. Technol."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"4939","DOI":"10.1039\/D0QI00929F","article-title":"Application of MOF-derived transition metal oxides and composites as anodes for lithium-ion batteries","volume":"7","author":"Tan","year":"2020","journal-title":"Inorg. Chem. Front."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"376","DOI":"10.1016\/j.jhazmat.2010.11.019","article-title":"MOF-derived ZnO and ZnO@C composites with high photocatalytic activity and adsorption capacity","volume":"186","author":"Yang","year":"2011","journal-title":"J. Hazard. Mater."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"4606","DOI":"10.1021\/cr9003924","article-title":"Engineering Metal Organic Frameworks for Heterogeneous Catalysis","volume":"110","author":"Corma","year":"2010","journal-title":"Chem. Rev."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"1450","DOI":"10.1039\/b807080f","article-title":"Metal-organic framework materials as catalysts","volume":"38","author":"Lee","year":"2009","journal-title":"Chem. Soc. Rev."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"7223","DOI":"10.1021\/jacs.9b00733","article-title":"Metal\u2013Organic Frameworks as Catalysts for Organic Synthesis: A Critical Perspective","volume":"141","author":"Pascanu","year":"2019","journal-title":"J. Am. Chem. Soc."},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"8468","DOI":"10.1021\/acs.chemrev.9b00685","article-title":"Metal\u2013Organic Frameworks in Heterogeneous Catalysis: Recent Progress, New Trends, and Future Perspectives","volume":"120","author":"Bavykina","year":"2020","journal-title":"Chem. Rev."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1016\/j.mattod.2022.04.002","article-title":"Self-sacrifice MOFs for heterogeneous catalysis: Synthesis mechanisms and future perspectives","volume":"55","author":"Ahmad","year":"2022","journal-title":"Mater. Today"},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/S1872-2067(22)64193-7","article-title":"Metal-organic frameworks for catalysis: Fundamentals and future prospects","volume":"45","author":"Jiao","year":"2023","journal-title":"Chin. J. Catal."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"100005","DOI":"10.1016\/j.enchem.2019.100005","article-title":"Metal-organic frameworks for catalysis: State of the art, challenges, and opportunities","volume":"1","author":"Dandan","year":"2019","journal-title":"Energy Chem."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"11465","DOI":"10.1021\/ja405078u","article-title":"Synthesis Modulation as a Tool To Increase the Catalytic Activity of Metal\u2013Organic Frameworks: The Unique Case of UiO-66(Zr)","volume":"135","author":"Vermoortele","year":"2013","journal-title":"J. Am. Chem. Soc."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"3610","DOI":"10.1039\/C8CY00742J","article-title":"Catalytic properties of pristine and defect-engineered Zr-MOF-808 metal organic frameworks","volume":"8","author":"Mautschke","year":"2018","journal-title":"Cat. Sci. Technol."},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"76","DOI":"10.1016\/j.jcat.2011.04.004","article-title":"Synthesis, structural properties, and catalytic behavior of Cu-BTC and mixed-linker Cu-BTC-PyDC in the oxidation of benzene derivatives","volume":"281","author":"Marx","year":"2011","journal-title":"J. Catal."},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"7058","DOI":"10.1002\/anie.201311128","article-title":"Multifunctional, defect-engineered metal-organic frameworks with ruthenium centers: Sorption and catalytic properties","volume":"53","author":"Kozachuk","year":"2014","journal-title":"Angew. Chem. Int. Ed. Engl."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"125085","DOI":"10.1016\/j.fuel.2022.125085","article-title":"Defect-engineered MOF-808 with highly exposed Zr sites as highly efficient catalysts for catalytic transfer hydrogenation of furfural","volume":"327","author":"Fu","year":"2022","journal-title":"Fuel"},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"5383","DOI":"10.1021\/acscatal.9b01043","article-title":"Enhanced Activity of Heterogeneous Pd(II) Catalysts on Acid-Functionalized Metal\u2013Organic Frameworks","volume":"9","author":"Otake","year":"2019","journal-title":"ACS Catal."},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"6351","DOI":"10.1039\/D0GC01999B","article-title":"Zr-Based MOFs for oxidative desulfurization: What matters?","volume":"22","author":"Hao","year":"2020","journal-title":"Green Chem."},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"4248","DOI":"10.1021\/acs.inorgchem.2c04364","article-title":"Boosting Catalytic Performance of MOF-808(Zr) by Direct Generation of Rich Defective Zr Nodes via a Solvent-Free Approach","volume":"62","author":"Ye","year":"2023","journal-title":"Inorg. Chem."},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"21526","DOI":"10.1039\/D0TA08009H","article-title":"Synthesis, characterization and application of defective metal\u2013organic frameworks: Current status and perspectives","volume":"8","author":"Xiang","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"ref_83","doi-asserted-by":"crossref","first-page":"12175","DOI":"10.1002\/anie.201907074","article-title":"Switching on the Photocatalysis of Metal\u2013Organic Frameworks by Engineering Structural Defects","volume":"58","author":"Ma","year":"2019","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_84","doi-asserted-by":"crossref","first-page":"395","DOI":"10.1039\/C4CE01672F","article-title":"Active site engineering in UiO-66 type metal\u2013organic frameworks by intentional creation of defects: A theoretical rationalization","volume":"17","author":"Vandichel","year":"2015","journal-title":"Crystengcomm"},{"key":"ref_85","doi-asserted-by":"crossref","first-page":"18698","DOI":"10.1021\/acsanm.3c03787","article-title":"Critical Role of Defects in UiO-66 Nanocrystals for Catalysis and Water Remediation","volume":"6","author":"Jrad","year":"2023","journal-title":"ACS Appl. Nano Mater."},{"key":"ref_86","doi-asserted-by":"crossref","first-page":"6333","DOI":"10.1021\/cm502399q","article-title":"Postsynthesis Annealing of MOF-5 Remarkably Enhances the Framework Structural Stability and CO2 Uptake","volume":"26","author":"Gadipelli","year":"2014","journal-title":"Chem. Mater."},{"key":"ref_87","doi-asserted-by":"crossref","first-page":"2007442","DOI":"10.1002\/adma.202007442","article-title":"Programmable Logic in Metal-Organic Frameworks for Catalysis","volume":"33","author":"Shen","year":"2021","journal-title":"Adv. Mater."},{"key":"ref_88","doi-asserted-by":"crossref","first-page":"301","DOI":"10.1016\/j.jhazmat.2017.12.016","article-title":"Research of mercury removal from sintering flue gas of iron and steel by the open metal site of Mil-101(Cr)","volume":"351","author":"Zhao","year":"2018","journal-title":"J. Hazard Mater."},{"key":"ref_89","doi-asserted-by":"crossref","first-page":"5367","DOI":"10.1021\/acs.est.8b00092","article-title":"Metal Organic Framework with Coordinatively Unsaturated Sites as Efficient Fenton-like Catalyst for Enhanced Degradation of Sulfamethazine","volume":"52","author":"Tang","year":"2018","journal-title":"Environ. Sci. Technol."},{"key":"ref_90","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.matlet.2015.12.150","article-title":"Synthesis of highly efficient MnOx catalyst for low-temperature NH3-SCR prepared from Mn-MOF-74 template","volume":"168","author":"Jiang","year":"2016","journal-title":"Mater. Lett."},{"key":"ref_91","doi-asserted-by":"crossref","first-page":"122","DOI":"10.1016\/j.cattod.2017.10.044","article-title":"Synthesis of CuO catalyst derived from HKUST-1 temple for the lowtemperature NH3-SCR process","volume":"314","author":"Bo","year":"2018","journal-title":"Cat. Today"},{"key":"ref_92","doi-asserted-by":"crossref","first-page":"469","DOI":"10.1016\/j.cej.2018.03.091","article-title":"In situ pyrolysis of Ce-MOF to prepare CeO2 catalyst with obviously improved catalytic performance for toluene combustion","volume":"344","author":"Chen","year":"2018","journal-title":"Chem. Eng. J."},{"key":"ref_93","doi-asserted-by":"crossref","first-page":"3480","DOI":"10.1021\/acsanm.9b00466","article-title":"Hollow-Structural Ag\/Co3O4 Nanocatalyst for CO Oxidation: Interfacial Synergistic Effect","volume":"2","author":"Lei","year":"2019","journal-title":"ACS Appl. Nano Mater."},{"key":"ref_94","doi-asserted-by":"crossref","first-page":"373","DOI":"10.1002\/cctc.201901278","article-title":"Porous Nickel-Alumina Derived from Metal-Organic Framework (MIL-53): A New Approach to Achieve Active and Stable Catalysts in Methane Dry Reforming","volume":"12","author":"Karam","year":"2020","journal-title":"ChemCatChem"},{"key":"ref_95","doi-asserted-by":"crossref","first-page":"1437","DOI":"10.14716\/ijtech.v10i7.3605","article-title":"Preparation of Metal Organic Framework (MOF) Derived Bimetallic Catalyst for Dry Reforming of Methane","volume":"10","author":"Chin","year":"2019","journal-title":"Int. J. Technol."},{"key":"ref_96","doi-asserted-by":"crossref","unstructured":"Khan, I.S., Ramirez, A., Shterk, G., Garz\u00f3n-Tovar, L., and Gascon, J. (2020). Bimetallic Metal-Organic Framework Mediated Synthesis of Ni-Co Catalysts for the Dry Reforming of Methane. Catalysts, 10.","DOI":"10.3390\/catal10050592"},{"key":"ref_97","doi-asserted-by":"crossref","first-page":"3905","DOI":"10.1002\/cssc.201500780","article-title":"Design of Zeolitic Imidazolate Framework Derived Nitrogen-Doped Nanoporous Carbons Containing Metal Species for Carbon Dioxide Fixation Reactions","volume":"8","author":"Toyao","year":"2015","journal-title":"ChemSusChem"},{"key":"ref_98","doi-asserted-by":"crossref","first-page":"476","DOI":"10.1149\/MA2021-019476mtgabs","article-title":"Pyrolysis of Metal Organic Frameworks (MOF): Transformations Leading to Formation of Transition Metal-Nitrogen-Carbon Catalysts","volume":"MA2021-01","author":"Huang","year":"2021","journal-title":"ECS Meet. 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