{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,7]],"date-time":"2026-03-07T19:50:40Z","timestamp":1772913040049,"version":"3.50.1"},"reference-count":27,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2020,10,17]],"date-time":"2020-10-17T00:00:00Z","timestamp":1602892800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Sloval Research and Development Agency","award":["APVV-SK-BY-RD-19-0008"],"award-info":[{"award-number":["APVV-SK-BY-RD-19-0008"]}]},{"name":"Belarussian Republican Foundation for Basic Research","award":["T20SLKG-001"],"award-info":[{"award-number":["T20SLKG-001"]}]},{"name":"P.J. \u0160af\u00e1rik University in Ko\u0161ice","award":["VVGS-2020-1403"],"award-info":[{"award-number":["VVGS-2020-1403"]}]},{"name":"FCT\/MEC Portugal","award":["UIDB\/50011\/2020 & UIDP\/50011\/2020"],"award-info":[{"award-number":["UIDB\/50011\/2020 & UIDP\/50011\/2020"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Crystals"],"abstract":"<jats:p>Magnetic properties of the high-pressure stabilized perovskite BiFe1-yScyO3 phases (0.1 \u2264 y \u2264 0.9) have been studied by means of magnetization measurements and neutron diffraction. The metastable perovskites of this series undergo irreversible polymorphic transformations upon annealing, the phenomenon referred to as conversion polymorphism. It has been found that the solid solutions with y \u2265 0.70 exhibit no long-range magnetic ordering regardless of their polymorph modification, while those with y \u2264 0.60 are all antiferromagnets. Depending on the scandium content, temperature and structural distortions, three types of the antiferromagnetic orderings, involving collinear, canted and cycloidal spin arrangements, have been revealed in the phases obtained via conversion polymorphism and the corresponding magnetic phase diagram has been suggested.<\/jats:p>","DOI":"10.3390\/cryst10100950","type":"journal-article","created":{"date-parts":[[2020,10,17]],"date-time":"2020-10-17T08:14:50Z","timestamp":1602922490000},"page":"950","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":11,"title":["Magnetic Diagram of the High-Pressure Stabilized Multiferroic Perovskites of the BiFe1-yScyO3 Series"],"prefix":"10.3390","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-0454-2240","authenticated-orcid":false,"given":"Elena L.","family":"Fertman","sequence":"first","affiliation":[{"name":"B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine (NASU), Nauky 47, 61103 Kharkiv, Ukraine"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7768-8032","authenticated-orcid":false,"given":"Alexey V.","family":"Fedorchenko","sequence":"additional","affiliation":[{"name":"B. Verkin Institute for Low Temperature Physics and Engineering of the National Academy of Sciences of Ukraine (NASU), Nauky 47, 61103 Kharkiv, Ukraine"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6289-110X","authenticated-orcid":false,"given":"Erik","family":"\u010ci\u017em\u00e1r","sequence":"additional","affiliation":[{"name":"Faculty of Sciences, Institute of Physics, P. J. \u0160af\u00e1rik University, Park Angelinum 9, 041 54 Ko\u0161ice, Slovakia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5884-3292","authenticated-orcid":false,"given":"Serhii","family":"Vorobiov","sequence":"additional","affiliation":[{"name":"Faculty of Sciences, Institute of Physics, P. J. \u0160af\u00e1rik University, Park Angelinum 9, 041 54 Ko\u0161ice, Slovakia"}]},{"given":"Alexander","family":"Feher","sequence":"additional","affiliation":[{"name":"Faculty of Sciences, Institute of Physics, P. J. \u0160af\u00e1rik University, Park Angelinum 9, 041 54 Ko\u0161ice, Slovakia"}]},{"given":"Yury V.","family":"Radyush","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of the National Academy of Sciences of Belarus (NASB), P. Brovka 19, 220072 Minsk, Belarus"}]},{"given":"Anatoli V.","family":"Pushkarev","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of the National Academy of Sciences of Belarus (NASB), P. Brovka 19, 220072 Minsk, Belarus"}]},{"given":"Nikolai M.","family":"Olekhnovich","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of the National Academy of Sciences of Belarus (NASB), P. Brovka 19, 220072 Minsk, Belarus"}]},{"given":"Andrius","family":"Stanulis","sequence":"additional","affiliation":[{"name":"Energy Safety Research Institute (ESRI), Bay Campus, Swansea University, Fabian Way, Swansea SA1 8EN, UK"}]},{"given":"Andrew R.","family":"Barron","sequence":"additional","affiliation":[{"name":"Energy Safety Research Institute (ESRI), Bay Campus, Swansea University, Fabian Way, Swansea SA1 8EN, UK"},{"name":"Department of Chemistry and Department of Materials Science and Nanoengineering, Rice University, Houston, TX 77005, USA"},{"name":"Faculty of Engineering, Universiti Teknologi Brunei, Jalan Tungku Link, Gadong, Bandar Seri Begawan BE1410, Brunei"}]},{"given":"Dmitry D.","family":"Khalyavin","sequence":"additional","affiliation":[{"name":"ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX, UK"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5386-0280","authenticated-orcid":false,"given":"Andrei N.","family":"Salak","sequence":"additional","affiliation":[{"name":"Department of Materials and Ceramics Engineering\/CICECO-Aveiro Institute of Materials, University of 3810-193 Aveiro, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2020,10,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2463","DOI":"10.1002\/adma.200802849","article-title":"Physics and Applications of Bismuth Ferrite","volume":"21","author":"Catalan","year":"2009","journal-title":"Adv. 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