{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,20]],"date-time":"2026-01-20T04:10:25Z","timestamp":1768882225239,"version":"3.49.0"},"reference-count":65,"publisher":"MDPI AG","issue":"5","license":[{"start":{"date-parts":[[2024,5,17]],"date-time":"2024-05-17T00:00:00Z","timestamp":1715904000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia (FCT)","doi-asserted-by":"publisher","award":["UID\/Multi\/04349\/2019"],"award-info":[{"award-number":["UID\/Multi\/04349\/2019"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia (FCT)","doi-asserted-by":"publisher","award":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"],"award-info":[{"award-number":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia (FCT)","doi-asserted-by":"publisher","award":["LISBOA-01-0145-FEDER-022125"],"award-info":[{"award-number":["LISBOA-01-0145-FEDER-022125"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia (FCT)","doi-asserted-by":"publisher","award":["Lisboa2020"],"award-info":[{"award-number":["Lisboa2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia (FCT)","doi-asserted-by":"publisher","award":["47836RH"],"award-info":[{"award-number":["47836RH"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"National Infrastructure Roadmap","doi-asserted-by":"publisher","award":["UID\/Multi\/04349\/2019"],"award-info":[{"award-number":["UID\/Multi\/04349\/2019"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"National Infrastructure Roadmap","doi-asserted-by":"publisher","award":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"],"award-info":[{"award-number":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"National Infrastructure Roadmap","doi-asserted-by":"publisher","award":["LISBOA-01-0145-FEDER-022125"],"award-info":[{"award-number":["LISBOA-01-0145-FEDER-022125"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"National Infrastructure Roadmap","doi-asserted-by":"publisher","award":["Lisboa2020"],"award-info":[{"award-number":["Lisboa2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"National Infrastructure Roadmap","doi-asserted-by":"publisher","award":["47836RH"],"award-info":[{"award-number":["47836RH"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"RNEM\u2014Portuguese Mass Spectrometry Network","doi-asserted-by":"publisher","award":["UID\/Multi\/04349\/2019"],"award-info":[{"award-number":["UID\/Multi\/04349\/2019"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"RNEM\u2014Portuguese Mass Spectrometry Network","doi-asserted-by":"publisher","award":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"],"award-info":[{"award-number":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"RNEM\u2014Portuguese Mass Spectrometry Network","doi-asserted-by":"publisher","award":["LISBOA-01-0145-FEDER-022125"],"award-info":[{"award-number":["LISBOA-01-0145-FEDER-022125"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"RNEM\u2014Portuguese Mass Spectrometry Network","doi-asserted-by":"publisher","award":["Lisboa2020"],"award-info":[{"award-number":["Lisboa2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"RNEM\u2014Portuguese Mass Spectrometry Network","doi-asserted-by":"publisher","award":["47836RH"],"award-info":[{"award-number":["47836RH"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Lisboa Regional Operational Program","award":["UID\/Multi\/04349\/2019"],"award-info":[{"award-number":["UID\/Multi\/04349\/2019"]}]},{"name":"Lisboa Regional Operational Program","award":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"],"award-info":[{"award-number":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"]}]},{"name":"Lisboa Regional Operational Program","award":["LISBOA-01-0145-FEDER-022125"],"award-info":[{"award-number":["LISBOA-01-0145-FEDER-022125"]}]},{"name":"Lisboa Regional Operational Program","award":["Lisboa2020"],"award-info":[{"award-number":["Lisboa2020"]}]},{"name":"Lisboa Regional Operational Program","award":["47836RH"],"award-info":[{"award-number":["47836RH"]}]},{"name":"PHC PESSOA","award":["UID\/Multi\/04349\/2019"],"award-info":[{"award-number":["UID\/Multi\/04349\/2019"]}]},{"name":"PHC PESSOA","award":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"],"award-info":[{"award-number":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"]}]},{"name":"PHC PESSOA","award":["LISBOA-01-0145-FEDER-022125"],"award-info":[{"award-number":["LISBOA-01-0145-FEDER-022125"]}]},{"name":"PHC PESSOA","award":["Lisboa2020"],"award-info":[{"award-number":["Lisboa2020"]}]},{"name":"PHC PESSOA","award":["47836RH"],"award-info":[{"award-number":["47836RH"]}]},{"name":"French Ministry for Europe and Foreign Affairs","award":["UID\/Multi\/04349\/2019"],"award-info":[{"award-number":["UID\/Multi\/04349\/2019"]}]},{"name":"French Ministry for Europe and Foreign Affairs","award":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"],"award-info":[{"award-number":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"]}]},{"name":"French Ministry for Europe and Foreign Affairs","award":["LISBOA-01-0145-FEDER-022125"],"award-info":[{"award-number":["LISBOA-01-0145-FEDER-022125"]}]},{"name":"French Ministry for Europe and Foreign Affairs","award":["Lisboa2020"],"award-info":[{"award-number":["Lisboa2020"]}]},{"name":"French Ministry for Europe and Foreign Affairs","award":["47836RH"],"award-info":[{"award-number":["47836RH"]}]},{"name":"French Ministry for Higher Education and Research","award":["UID\/Multi\/04349\/2019"],"award-info":[{"award-number":["UID\/Multi\/04349\/2019"]}]},{"name":"French Ministry for Higher Education and Research","award":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"],"award-info":[{"award-number":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"]}]},{"name":"French Ministry for Higher Education and Research","award":["LISBOA-01-0145-FEDER-022125"],"award-info":[{"award-number":["LISBOA-01-0145-FEDER-022125"]}]},{"name":"French Ministry for Higher Education and Research","award":["Lisboa2020"],"award-info":[{"award-number":["Lisboa2020"]}]},{"name":"French Ministry for Higher Education and Research","award":["47836RH"],"award-info":[{"award-number":["47836RH"]}]},{"name":"Portuguese FCT","award":["UID\/Multi\/04349\/2019"],"award-info":[{"award-number":["UID\/Multi\/04349\/2019"]}]},{"name":"Portuguese FCT","award":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"],"award-info":[{"award-number":["LTHMFL-NECL LISBOA-01-0145-FEDER-022096"]}]},{"name":"Portuguese FCT","award":["LISBOA-01-0145-FEDER-022125"],"award-info":[{"award-number":["LISBOA-01-0145-FEDER-022125"]}]},{"name":"Portuguese FCT","award":["Lisboa2020"],"award-info":[{"award-number":["Lisboa2020"]}]},{"name":"Portuguese FCT","award":["47836RH"],"award-info":[{"award-number":["47836RH"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Crystals"],"abstract":"<jats:p>New iron and cobalt bis(dithiolene) complexes [M(3cbdt)2] (3cbdt = 3-cyanobenzene-1,2-dithiolate) were prepared as tetraphenylphosphonium (Ph4P+) salts for Fe in the monoanionic state and for Co in both the dianionic and monoanionic states: (Ph4P)2[Fe(III)(3cbdt)2]2 (1); (Ph4P)2[Co(III)(3cbdt)2]2 (2); (Ph4P)2[Co(II)(3cbdt)2] (3). These compounds were characterized by single-crystal X-ray diffraction, cyclic voltammetry, EPR, and static magnetic susceptibility. Their properties are discussed in comparison with the corresponding complexes based on the isomer ligand 4-cyanobenzene-1,2-dithiolate (4cbdt) and 4,5-cyanobenzene-1,2-dithiolate (dcbdt), previously described by us. The Fe(III) and the Co(III) compounds (1 and 2) are isostructural, crystallizing in the triclinic P1\u00af space group, with cis [M(III)(3cbdt)2] complexes dimerized in a trans fashion, and the transition metal (M = Fe, Co) has a distorted 4+1 square pyramidal coordination geometry. The Co(II) compound (3) crystallizes in the triclinic P1\u00af space group, with the unit cell containing one cis and three trans inequivalent [Co(II)(3cbdt)2] complexes with the transition metal (Co) and having a square planar coordination geometry. The Fe(III) complex (1) is EPR-silent, and the static magnetic susceptibility shows a temperature dependence typical of dimers of antiferromagnetically coupled S = 3\/2 spins with \u2212J\/kB = 233.6 K and g = 1.8. Static magnetic susceptibility measurements of compound (3) show that this Co(II) complex is paramagnetic, corresponding to an S = \u00bd state with g = 2, in agreement with EPR spectra showing in solid state a hyperfine structure typical of the I(59Co) = 7\/2. Static susceptibility measurements of Co(III) complex (2) showed an increase in the paramagnetic susceptibility upon warming above 100 K, which is consistent with strong AFM coupling between dimerized S = 1 units with a constant \u2212J\/kB ~1286 K.<\/jats:p>","DOI":"10.3390\/cryst14050469","type":"journal-article","created":{"date-parts":[[2024,5,17]],"date-time":"2024-05-17T04:26:29Z","timestamp":1715919989000},"page":"469","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Cobalt and Iron Cyano Benzene Bis(Dithiolene) Complexes"],"prefix":"10.3390","volume":"14","author":[{"given":"Ant\u00f3nio G.","family":"Costa","sequence":"first","affiliation":[{"name":"Centro de Ci\u00eancias e Tecnologias Nucleares (C2TN), Associa\u00e7\u00e3o do Instituto Superior T\u00e9cnico para a Investiga\u00e7\u00e3o e Desenvolvimento (IST-ID), Departamento de Engenharia e Tecnologias Nucleares (DECN), Instituto Superior T\u00e9cnico (IST), Universidade de Lisboa, Estrada Nacional 10, 2695-066 Bobadela, Portugal"}]},{"given":"Gon\u00e7alo","family":"Lopes","sequence":"additional","affiliation":[{"name":"Centro de Ci\u00eancias e Tecnologias Nucleares (C2TN), Associa\u00e7\u00e3o do Instituto Superior T\u00e9cnico para a Investiga\u00e7\u00e3o e Desenvolvimento (IST-ID), Departamento de Engenharia e Tecnologias Nucleares (DECN), Instituto Superior T\u00e9cnico (IST), Universidade de Lisboa, Estrada Nacional 10, 2695-066 Bobadela, Portugal"}]},{"given":"Jo\u00e3o F. G.","family":"Rodrigues","sequence":"additional","affiliation":[{"name":"Centro de Ci\u00eancias e Tecnologias Nucleares (C2TN), Associa\u00e7\u00e3o do Instituto Superior T\u00e9cnico para a Investiga\u00e7\u00e3o e Desenvolvimento (IST-ID), Departamento de Engenharia e Tecnologias Nucleares (DECN), Instituto Superior T\u00e9cnico (IST), Universidade de Lisboa, Estrada Nacional 10, 2695-066 Bobadela, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8350-480X","authenticated-orcid":false,"given":"Isabel C.","family":"Santos","sequence":"additional","affiliation":[{"name":"Centro de Ci\u00eancias e Tecnologias Nucleares (C2TN), Associa\u00e7\u00e3o do Instituto Superior T\u00e9cnico para a Investiga\u00e7\u00e3o e Desenvolvimento (IST-ID), Departamento de Engenharia e Tecnologias Nucleares (DECN), Instituto Superior T\u00e9cnico (IST), Universidade de Lisboa, Estrada Nacional 10, 2695-066 Bobadela, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5493-8158","authenticated-orcid":false,"given":"Dulce","family":"Sim\u00e3o","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural (CQE), Associa\u00e7\u00e3o do Instituto Superior T\u00e9cnico para a Investiga\u00e7\u00e3o e Desenvolvimento (IST-ID), Departamento de Engenharia Qu\u00edmica (DEQ), Instituto Superior T\u00e9cnico (IST), Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1855-7758","authenticated-orcid":false,"given":"Elsa B.","family":"Lopes","sequence":"additional","affiliation":[{"name":"Centro de Ci\u00eancias e Tecnologias Nucleares (C2TN), Associa\u00e7\u00e3o do Instituto Superior T\u00e9cnico para a Investiga\u00e7\u00e3o e Desenvolvimento (IST-ID), Departamento de Engenharia e Tecnologias Nucleares (DECN), Instituto Superior T\u00e9cnico (IST), Universidade de Lisboa, Estrada Nacional 10, 2695-066 Bobadela, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8818-0039","authenticated-orcid":false,"given":"Laura C. J.","family":"Pereira","sequence":"additional","affiliation":[{"name":"Centro de Ci\u00eancias e Tecnologias Nucleares (C2TN), Associa\u00e7\u00e3o do Instituto Superior T\u00e9cnico para a Investiga\u00e7\u00e3o e Desenvolvimento (IST-ID), Departamento de Engenharia e Tecnologias Nucleares (DECN), Instituto Superior T\u00e9cnico (IST), Universidade de Lisboa, Estrada Nacional 10, 2695-066 Bobadela, Portugal"}]},{"given":"Nolwenn","family":"Le Breton","sequence":"additional","affiliation":[{"name":"Institut de Chimie, UMR CNRS 7177, Universit\u00e9 de Strasbourg, Institut Le Bel, 4 Rue Blaise Pascal, CS 90032, 67081 Strasbourg, France"}]},{"given":"Sylvie","family":"Choua","sequence":"additional","affiliation":[{"name":"Institut de Chimie, UMR CNRS 7177, Universit\u00e9 de Strasbourg, Institut Le Bel, 4 Rue Blaise Pascal, CS 90032, 67081 Strasbourg, France"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1517-704X","authenticated-orcid":false,"given":"St\u00e9phane A.","family":"Baudron","sequence":"additional","affiliation":[{"name":"CNRS, CMC UMR 7140, Universit\u00e9 de Strasbourg, 4 rue Blaise Pascal, 67000 Strasbourg, France"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2222-5641","authenticated-orcid":false,"given":"Manuel","family":"Almeida","sequence":"additional","affiliation":[{"name":"Centro de Ci\u00eancias e Tecnologias Nucleares (C2TN), Associa\u00e7\u00e3o do Instituto Superior T\u00e9cnico para a Investiga\u00e7\u00e3o e Desenvolvimento (IST-ID), Departamento de Engenharia e Tecnologias Nucleares (DECN), Instituto Superior T\u00e9cnico (IST), Universidade de Lisboa, Estrada Nacional 10, 2695-066 Bobadela, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5324-8013","authenticated-orcid":false,"given":"Sandra","family":"Raba\u00e7a","sequence":"additional","affiliation":[{"name":"Centro de Ci\u00eancias e Tecnologias Nucleares (C2TN), Associa\u00e7\u00e3o do Instituto Superior T\u00e9cnico para a Investiga\u00e7\u00e3o e Desenvolvimento (IST-ID), Departamento de Engenharia e Tecnologias Nucleares (DECN), Instituto Superior T\u00e9cnico (IST), Universidade de Lisboa, Estrada Nacional 10, 2695-066 Bobadela, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2024,5,17]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3596","DOI":"10.1021\/ja00877a045","article-title":"A Spin-Free Square Planar Cobaltous Complex","volume":"84","author":"Gray","year":"1962","journal-title":"J. Am. Chem. Soc."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/S0010-8545(01)00457-X","article-title":"Metal bis-1,2-dithiolene complexes in conducting or magnetic crystalline assemblies","volume":"227","author":"Robertson","year":"2002","journal-title":"Coord. Chem. Rev."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"5319","DOI":"10.1021\/cr030655t","article-title":"Conducting metal dithiolene complexes: Structural and electronic properties","volume":"104","author":"Kato","year":"2004","journal-title":"Chem. Rev."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"9741","DOI":"10.1021\/ic2011748","article-title":"Noninnocence in Metal Complexes: A Dithiolene Dawn","volume":"50","author":"Eisenberg","year":"2011","journal-title":"Inorg. Chem."},{"key":"ref_5","unstructured":"Coucouvanis, D. (1970). Progress in Inorganic Chemistry, Wiley Online Library."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"8267","DOI":"10.1021\/jacs.2c01996","article-title":"Redox-Active Covalent Organic Frameworks with Nickel-Bis(dithiolene) Units as Guiding Layers for High-Performance Lithium Metal Batteries","volume":"144","author":"Ke","year":"2022","journal-title":"J. Am. Chem. Soc."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"586","DOI":"10.1038\/s41467-022-35195-4","article-title":"Photothermal bleaching of nickel dithiolene for bright multi-colored 3D printed parts","volume":"14","author":"Olubummo","year":"2023","journal-title":"Nat. Commun."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"28028","DOI":"10.1021\/acs.jpcc.5b09148","article-title":"Two-Dimensional pi-Conjugated Metal Bis(dithiolene) Complex Nanosheets as Selective Catalysts for Oxygen Reduction Reaction","volume":"119","author":"Zhang","year":"2015","journal-title":"J. Phys. Chem. C"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"974","DOI":"10.1039\/d0mt00064g","article-title":"Gold(III) bis(dithiolene) complexes: From molecular conductors to prospective anticancer, antimicrobial and antiplasmodial agents","volume":"12","author":"Fontinha","year":"2020","journal-title":"Metallomics"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"4406","DOI":"10.1021\/acsabm.1c00168","article-title":"Tunable NIR Absorption Property of a Dithiolene Nickel Complex: A Promising NIR-II Absorption Material for Photothermal Therapy","volume":"4","author":"Chen","year":"2021","journal-title":"Acs Appl. Bio Mater."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"508","DOI":"10.1002\/ejic.201901118","article-title":"(Photo)Thermal Stimulation of Functional Dithiolene Complexes in Soft Matter","volume":"2020","author":"Camerel","year":"2020","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"12016","DOI":"10.1021\/acsnano.0c05200","article-title":"Highly Conductive Two-Dimensional Metal-Organic Frameworks for Resilient Lithium Storage with Superb Rate Capability","volume":"14","author":"Wu","year":"2020","journal-title":"Acs Nano"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"8536","DOI":"10.1021\/acs.chemrev.9b00766","article-title":"Electrically Conductive Metal-Organic Frameworks","volume":"120","author":"Xie","year":"2020","journal-title":"Chem. Rev."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"4120","DOI":"10.1021\/cm101238m","article-title":"Conductivity, Doping, and Redox Chemistry of a Microporous Dithiolene-Based Metal-Organic Framework","volume":"22","author":"Kobayashi","year":"2010","journal-title":"Chem. Mater."},{"key":"ref_15","doi-asserted-by":"crossref","unstructured":"Sousa, A., Santos, J.F., Silva, F., Sousa, S.A., Leit\u00e3o, J.H., Matos, A.P., Pinheiro, T., Silva, R.A.L., Belo, D., and Almeida, M. (2023). Antitumoral and Antimicrobial Activities of Block Copolymer Micelles Containing Gold Bisdithiolate Complexes. Pharmaceutics, 15.","DOI":"10.3390\/pharmaceutics15020564"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"1357","DOI":"10.1016\/j.ccr.2010.01.015","article-title":"Dithiolenes and non-innocent redox-active ligands","volume":"254","author":"Vlcek","year":"2010","journal-title":"Coord. Chem. Rev."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1002\/9780470166116.ch2","article-title":"Metal 1,2-Dithiolene and Related Complexes","volume":"10","author":"McCleverty","year":"1968","journal-title":"Prog. Inorg. Chem"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"511","DOI":"10.1002\/1521-3765(20010119)7:2<511::AID-CHEM511>3.0.CO;2-5","article-title":"Gold complexes with dithiothiophene ligands: A metal based on a neutral molecule","volume":"7","author":"Belo","year":"2001","journal-title":"Chem. Eur. J."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"285","DOI":"10.1126\/science.291.5502.285","article-title":"A three-dimensional synthetic metallic crystal composed of single-component molecules","volume":"291","author":"Tanaka","year":"2001","journal-title":"Science"},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"10591","DOI":"10.1039\/D1TC01407B","article-title":"The quest for single component molecular metals within neutral transition metal complexes","volume":"9","author":"Velho","year":"2021","journal-title":"J. Mater. Chem. C"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"658","DOI":"10.1039\/B602268E","article-title":"Fe(qdt)2](-) salts; an undimerised Fe-III bis(dithiolene) complex stabilised by cation interactions","volume":"8","author":"Simao","year":"2006","journal-title":"Crystengcomm"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"5131","DOI":"10.1021\/ic0624569","article-title":"Reversible, electrochemically controlled binding of phosphine to iron and cobalt bis(dithiolene) complexes","volume":"46","author":"Yu","year":"2007","journal-title":"Inorg. Chem."},{"key":"ref_23","doi-asserted-by":"crossref","unstructured":"Eisenberg, R. (1970). Structural Systematics of 1,1- and 1,2-Dithiolato Chelates, John Wiley & Sons Ltd.","DOI":"10.1002\/9780470166130.ch4"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"1318","DOI":"10.1002\/ejic.200300476","article-title":"A series of transition metal bis(dicyanobenzenedithiolate) complexes [M(dcbdt)2] (M = Fe, Co, Ni, Pd, Pt, Cu, Au and Zn)","volume":"2004","author":"Alves","year":"2004","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"3705","DOI":"10.1021\/ic00069a027","article-title":"A novel trinuclear cobalt complex crystal and electronic structure of (Per)4[Co(mnt)2]3","volume":"32","author":"Gama","year":"1993","journal-title":"Inorg. Chem."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"1986","DOI":"10.1021\/ja00032a008","article-title":"(Perylene)Co(mnt)2(CH2Cl2)0.5: A mixed perylenecobalt complex as molecular and polymeric conductor","volume":"114","author":"Gama","year":"1992","journal-title":"J. Am. Chem. Soc."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"3119","DOI":"10.1002\/1099-0682(200112)2001:12<3119::AID-EJIC3119>3.0.CO;2-0","article-title":"Synthesis, structure and physical properties of tetrabutylammonium salts of nickel complexes with the new ligand dcbdt = 4,5-dicyanobenzene-1,2-dithiolate, [Ni(dcbdt)2](z-) (z = 0.4, 1, 2)","volume":"2001","author":"Simao","year":"2001","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"1011","DOI":"10.1016\/S0379-6779(00)00980-2","article-title":"Structure and physical properties of (n-Bu4N)2 [Au(dcbdt)2]5","volume":"120","author":"Alves","year":"2001","journal-title":"Synth. Met."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"543","DOI":"10.1016\/S0379-6779(02)00728-2","article-title":"Charge transfer salts based on M(dcbdt)2 complexes (M = Au and Ni)","volume":"135\u2013136","author":"Alves","year":"2003","journal-title":"Synth. Met."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"2481","DOI":"10.1016\/S0277-5387(03)00211-0","article-title":"(n-Bu4N)2[Fe(dcbdt)2]2. Synthesis, crystal structure and magnetic characterisation","volume":"22","author":"Alves","year":"2003","journal-title":"Polyhedron"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"397","DOI":"10.1016\/S0379-6779(02)00411-3","article-title":"Conductors based on metal-bisdicyanobenzodithiolate complexes","volume":"133\u2013134","author":"Alves","year":"2003","journal-title":"Synth. Met."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"2825","DOI":"10.1039\/b719418h","article-title":"The family of molecular conductors [(n-Bu)4N]2[M(dcbdt)2]5, M = Cu, Ni, Au; band filling and stacking modulation effects","volume":"18","author":"Lopes","year":"2008","journal-title":"J. Mater. Chem."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"3836","DOI":"10.1016\/j.ica.2008.02.068","article-title":"(n-Bu4N)[Fe(cbdt)2]: Synthesis, crystal structure and magnetic characterisation of a new Fe-III bis(dithiolene) complex","volume":"361","author":"Cerdeira","year":"2008","journal-title":"Inorganica Chim. Acta"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"228","DOI":"10.1016\/j.poly.2012.07.010","article-title":"Synthesis, structure and physical properties of transition metal bis 4-cyanobenzene-1,2-dithiolate complexes [M(cbdt)2]z- (M = Zn, Co, Cu, Au, Ni, Pd, z = 0, 1, 2)","volume":"44","author":"Cerdeira","year":"2012","journal-title":"Polyhedron"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"951","DOI":"10.3762\/bjoc.11.106","article-title":"Synthesis and characterization of the cyanobenzene-ethylenedithio-TTF donor","volume":"11","author":"Oliveira","year":"2015","journal-title":"Beilstein J. Org. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"6677","DOI":"10.1021\/acs.inorgchem.5b01240","article-title":"Bilayer molecular metals based on dissymmetrical electron donors","volume":"54","author":"Oliveira","year":"2015","journal-title":"Inorg. Chem."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"637","DOI":"10.1039\/C8CE01967C","article-title":"A 4-cyanobenzene-ethylenedithio-TTF electron donor and its (1:1) triiodide radical cation salt; isomer effects in C-N center dot center dot center dot H-C interactions","volume":"21","author":"Lopes","year":"2019","journal-title":"Crystengcomm"},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"1493","DOI":"10.1016\/j.ccr.2009.12.006","article-title":"Dithiolene complexes containing N coordinating groups and corresponding tetrathiafulvalene donors","volume":"254","author":"Rabaca","year":"2010","journal-title":"Coord. Chem. Rev."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"9763","DOI":"10.1021\/ic051226b","article-title":"Between Ni(mnt)2 and Ni(tfd)2 dithiolene complexes: The unsymmetrical 2-(trifluoromethyl)acrylonitrile-1,2-dithiolate and its nickel complexes","volume":"44","author":"Jeannin","year":"2005","journal-title":"Inorg. Chem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"2449","DOI":"10.1002\/chem.201304319","article-title":"A Silver Bite: Crystalline Heterometallic Architectures Based on Ag- p Interactions with a Bis- Dipyrrin Zinc Helicate","volume":"20","author":"Ruffin","year":"2014","journal-title":"Chem. Eur. J."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"2288","DOI":"10.1039\/c001020k","article-title":"Dipyrrin based homo- and hetero-metallic infinite architectures","volume":"12","author":"Baudron","year":"2010","journal-title":"Crystengcomm"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"3805","DOI":"10.1039\/b926264d","article-title":"Hierarchical self-assembly of heteronuclear co-ordination networks","volume":"39","author":"Fenton","year":"2010","journal-title":"Dalton Trans."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"437","DOI":"10.1515\/zkri-2017-2131","article-title":"N Donor substituted acetylacetones ditopic ligands versatile","volume":"233","author":"Kremer","year":"2018","journal-title":"Z. Fur Krist.-Cryst. Mater."},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"9403","DOI":"10.1039\/c3cs60255a","article-title":"Molecularly designed architectures\u2014The metalloligand way","volume":"42","author":"Kumar","year":"2013","journal-title":"Chem. Soc. Rev."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"8313","DOI":"10.1039\/D0CE01433H","article-title":"Structural diversity in conducting bilayer salts (CNB-EDT-TTF)4A","volume":"22","author":"Santos","year":"2020","journal-title":"Crystengcomm"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"5362","DOI":"10.1039\/D3CE00782K","article-title":"Cyano benzene functionalised Ni and Cu bis(dithiolene) complexes","volume":"25","author":"Costa","year":"2023","journal-title":"Crystengcomm"},{"key":"ref_47","unstructured":"(2016). Bruker Apex3, Crystallography Software Suite, Bruker Axs Inc."},{"key":"ref_48","unstructured":"(2005). Bruker Axs: Saint+, Release 6.22. Bruker AXS:SAINT+, Release 622, Bruker Analytical Systems."},{"key":"ref_49","unstructured":"(2005). Bruker Axs: Sadabs. Bruker AXS:SADABS, Bruker Analytical Systems."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"112","DOI":"10.1107\/S0108767307043930","article-title":"A short history of SHELX","volume":"64","author":"Sheldrick","year":"2008","journal-title":"Acta Crystallogr. A-Found. Adv."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"3","DOI":"10.1107\/S2053229614024218","article-title":"Crystal structure refinement with SHELXL","volume":"71","author":"Sheldrick","year":"2015","journal-title":"Acta Crystallogr. Sect. C-Struct. Chem."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1107\/S0021889812029111","article-title":"WinGX and ORTEP for Windows: An update","volume":"45","author":"Farrugia","year":"2012","journal-title":"J. Appl. Crystallogr."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"226","DOI":"10.1107\/S1600576719014092","article-title":"Mercury 4.0: From visualization to analysis, design and prediction","volume":"53","author":"Macrae","year":"2020","journal-title":"J. Appl. Crystallogr."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"160","DOI":"10.1016\/j.ica.2014.11.034","article-title":"Dimerisation of Fe bis(dithiolene) complexes: An electrochemical study","volume":"426","author":"Afonso","year":"2015","journal-title":"Inorganica Chim. Acta"},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"4870","DOI":"10.1021\/ja00973a021","article-title":"Characterization and Electronic Structures of Metal Complexes Containing Benzene-1,2-dithiolate and Related Ligands","volume":"88","author":"Billig","year":"1966","journal-title":"J. Am. Chem. Soc."},{"key":"ref_56","first-page":"1972","article-title":"Synthesis, structure, and spectroscopic properties of copper(II) compounds containing nitrogen-sulfur donor ligands: The crystal and molecular structure of aqua[1,7-bis(N-methylbenzimidazol-2\u2032-yl)-2,6-dithiaheptane]copper(II) perchlorate","volume":"7","author":"Addison","year":"1984","journal-title":"J. Chem. Soc. Dalton Trans. Inorg. Chem."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"14798","DOI":"10.1039\/D0DT02985H","article-title":"Five-coordinate transition metal complexes and the value of \u03c45: Observations and caveats","volume":"49","author":"Blackman","year":"2020","journal-title":"Dalton Trans."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"2476","DOI":"10.1021\/ic50140a034","article-title":"Spin delocalization in square-planar spin-triplet benzene- and toluenedithiolatecobaltate(III)","volume":"13","author":"Schilperoord","year":"1974","journal-title":"Inorg. Chem."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"9261","DOI":"10.1021\/acs.inorgchem.0c01154","article-title":"Co\/Fe(\u03b1-Alkyl-tpdt)2]x\u2212: Alkyl-Substituted Cobalt and Iron Bis-dithiolenethiophenic Complexes","volume":"59","author":"Silva","year":"2020","journal-title":"Inorg. Chem."},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"2598","DOI":"10.1021\/ic00038a053","article-title":"Low-dimensional molecular metals bis(maleonitriledithiolato)bis(perylene)metal, metal = iron and cobalt","volume":"31","author":"Gama","year":"1992","journal-title":"Inorg. Chem."},{"key":"ref_61","doi-asserted-by":"crossref","unstructured":"Rodrigues, J.V., Santos, I.C., Gama, V., Henriques, R.T., Waerenborgh, J.C., Duarte, M.T., and Almeida, M. (1994). Synthesis, structure and properties of [Hpy]2[{M(mnt)2}2](M = Co or Fe, Hpy = pyridinium, mnt = maleonitriledithiolate). J. Chem. Soc. Dalton Trans., 2655\u20132660.","DOI":"10.1039\/dt9940002655"},{"key":"ref_62","unstructured":"Weil, J.A., Bolton, J.R., and Wertz, J.E. (1994). Electron Spin Resonance: Elementary Theory and Practical Applications, Springer Science & Business Media."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"7632","DOI":"10.1021\/ja00311a067","article-title":"EPR evidence for hydrogen bond donation to the terminal oxygen of cobalt-oxygen model compounds and cobalt oxymyoglobin","volume":"107","author":"Walker","year":"1985","journal-title":"J. Am. Chem. Soc."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"61","DOI":"10.1021\/ja00704a010","article-title":"Electron paramagnetic resonance studies of some cobalt(II) Schiff base compounds and their monomeric oxygen adducts","volume":"92","author":"Hoffman","year":"1970","journal-title":"J. Am. Chem. Soc."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"204","DOI":"10.1002\/chem.200400850","article-title":"Molecular and Electronic Structure of Four- and Five-Coordinate Cobalt Complexes Containing Two o-Phenylenediamine- or Two o-Aminophenol-Type Ligands at Various Oxidation Levels: An Experimental, Density Functional, and Correlated ab initio Study","volume":"11","author":"Bill","year":"2005","journal-title":"Chem. Eur. J."}],"container-title":["Crystals"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2073-4352\/14\/5\/469\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T14:43:45Z","timestamp":1760107425000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2073-4352\/14\/5\/469"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2024,5,17]]},"references-count":65,"journal-issue":{"issue":"5","published-online":{"date-parts":[[2024,5]]}},"alternative-id":["cryst14050469"],"URL":"https:\/\/doi.org\/10.3390\/cryst14050469","relation":{},"ISSN":["2073-4352"],"issn-type":[{"value":"2073-4352","type":"electronic"}],"subject":[],"published":{"date-parts":[[2024,5,17]]}}}