{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T03:41:55Z","timestamp":1760240515202,"version":"build-2065373602"},"reference-count":52,"publisher":"MDPI AG","issue":"7","license":[{"start":{"date-parts":[[2019,7,20]],"date-time":"2019-07-20T00:00:00Z","timestamp":1563580800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003453","name":"Natural Science Foundation of Guangdong Province","doi-asserted-by":"publisher","award":["2016A030313761"],"award-info":[{"award-number":["2016A030313761"]}],"id":[{"id":"10.13039\/501100003453","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Foundation for Science and Technology (FCT) and Portugal 2020","award":["(IF\/01395\/2013\/CP1163\/CT005, CEECIND\/03708\/2017, LISBOA-01-0145-FEDER-029697, UID\/QUI\/00100\/2013"],"award-info":[{"award-number":["(IF\/01395\/2013\/CP1163\/CT005, CEECIND\/03708\/2017, LISBOA-01-0145-FEDER-029697, UID\/QUI\/00100\/2013"]}]},{"DOI":"10.13039\/501100018647","name":"RUDN University","doi-asserted-by":"publisher","award":["RUDN University Program 5-100"],"award-info":[{"award-number":["RUDN University Program 5-100"]}],"id":[{"id":"10.13039\/501100018647","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Guangdong Province Higher Vocational Colleges &amp; Schools Pearl River Scholar Funded Scheme","award":["2015, 2018"],"award-info":[{"award-number":["2015, 2018"]}]},{"name":"Innovation Team Project on University of Guangdong Province of P. R. China","award":["2017GKCXTD001"],"award-info":[{"award-number":["2017GKCXTD001"]}]},{"name":"Science and Technology Planning Project of Guangzhou","award":["201904010381"],"award-info":[{"award-number":["201904010381"]}]},{"name":"the Pearl River Scholar Foundation of Guangdong Industry Polytechnic","award":["RC2015-001"],"award-info":[{"award-number":["RC2015-001"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Crystals"],"abstract":"<jats:p>New iron(II) three-dimensional coordination polymer (3D CP), [Fe(\u00b53-Hcpna)2]n (1), was assembled under hydrothermal conditions from 5-(4\u2019-carboxyphenoxy)nicotinic acid (H2cpna) as a trifunctional organic N,O-building block. This stable microcrystalline CP was characterized by standard methods for coordination compounds in the solid state (infrared spectroscopy, elemental analysis, thermogravimetric analysis, powder and single-crystal X-ray diffraction). Structure and topology of 1 were examined and permitted an identification of a 3,6-connected framework of the rtl topological type. In addition, compound 1 acts as effective catalyst precursor for oxidative functionalization of alkanes (propane and cyclic C5\u2212C8 alkanes) under homogeneous catalysis conditions, namely for the oxidation of saturated hydrocarbons with H2O2\/H+ system to produce ketones and alcohols, and for alkane carboxylation with CO\/H2O\/S2O82\u2212 system to obtain carboxylic acids. The influence of an acid promoter and substrate scope (propane and cyclic C5\u2212C8 alkanes) were investigated.<\/jats:p>","DOI":"10.3390\/cryst9070369","type":"journal-article","created":{"date-parts":[[2019,7,22]],"date-time":"2019-07-22T02:55:37Z","timestamp":1563764137000},"page":"369","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":4,"title":["Synthesis, Structural Features, and Catalytic Activity of an Iron(II) 3D Coordination Polymer Driven by an Ether-Bridged Pyridine-Dicarboxylate"],"prefix":"10.3390","volume":"9","author":[{"given":"Na","family":"Zhao","sequence":"first","affiliation":[{"name":"Guangdong Research Center for Special Building Materials and Its Green Preparation Technology, Foshan Research Center for Special Functional Building Materials and their Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China"}]},{"given":"Yu","family":"Li","sequence":"additional","affiliation":[{"name":"Guangdong Research Center for Special Building Materials and Its Green Preparation Technology, Foshan Research Center for Special Functional Building Materials and their Green Preparation Technology, Guangdong Industry Polytechnic, Guangzhou 510300, China"}]},{"given":"Jinzhong","family":"Gu","sequence":"additional","affiliation":[{"name":"College of Chemistry and Chemical Engineering, Lanzhou University, Lanzhou 730000, China"}]},{"given":"Marina V.","family":"Kirillova","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisbon, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2052-5280","authenticated-orcid":false,"given":"Alexander M.","family":"Kirillov","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisbon, Portugal"},{"name":"Research Institute of Chemistry, Peoples\u2019 Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya st., 117198 Moscow, Russia"}]}],"member":"1968","published-online":{"date-parts":[[2019,7,20]]},"reference":[{"key":"ref_1","unstructured":"Glover, T.G., and Mu, B. (2018). Gas Adsorption in Metal-Organic Frameworks: Fundamentals and Applications, CRC Press."},{"key":"ref_2","doi-asserted-by":"crossref","unstructured":"Hashemi, L., and Morsali, A. (2019). 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