{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,10]],"date-time":"2026-02-10T19:51:14Z","timestamp":1770753074976,"version":"3.50.0"},"reference-count":57,"publisher":"MDPI AG","issue":"17","license":[{"start":{"date-parts":[[2025,8,25]],"date-time":"2025-08-25T00:00:00Z","timestamp":1756080000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","doi-asserted-by":"publisher","award":["UI\/BD\/153712\/2022"],"award-info":[{"award-number":["UI\/BD\/153712\/2022"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","doi-asserted-by":"publisher","award":["2023.09426.CEECIND"],"award-info":[{"award-number":["2023.09426.CEECIND"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","doi-asserted-by":"publisher","award":["UIDB\/04540\/2020"],"award-info":[{"award-number":["UIDB\/04540\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","doi-asserted-by":"publisher","award":["UID\/50006"],"award-info":[{"award-number":["UID\/50006"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","doi-asserted-by":"publisher","award":["CEECIND\/00793\/2018"],"award-info":[{"award-number":["CEECIND\/00793\/2018"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","doi-asserted-by":"publisher","award":["CEECIND\/03877\/2018"],"award-info":[{"award-number":["CEECIND\/03877\/2018"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","doi-asserted-by":"publisher","award":["SFRH\/BD\/150659\/2020"],"award-info":[{"award-number":["SFRH\/BD\/150659\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"CeFEMA","doi-asserted-by":"publisher","award":["UI\/BD\/153712\/2022"],"award-info":[{"award-number":["UI\/BD\/153712\/2022"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"CeFEMA","doi-asserted-by":"publisher","award":["2023.09426.CEECIND"],"award-info":[{"award-number":["2023.09426.CEECIND"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"CeFEMA","doi-asserted-by":"publisher","award":["UIDB\/04540\/2020"],"award-info":[{"award-number":["UIDB\/04540\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"CeFEMA","doi-asserted-by":"publisher","award":["UID\/50006"],"award-info":[{"award-number":["UID\/50006"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"CeFEMA","doi-asserted-by":"publisher","award":["CEECIND\/00793\/2018"],"award-info":[{"award-number":["CEECIND\/00793\/2018"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"CeFEMA","doi-asserted-by":"publisher","award":["CEECIND\/03877\/2018"],"award-info":[{"award-number":["CEECIND\/03877\/2018"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"CeFEMA","doi-asserted-by":"publisher","award":["SFRH\/BD\/150659\/2020"],"award-info":[{"award-number":["SFRH\/BD\/150659\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"name":"PT national funds","award":["UI\/BD\/153712\/2022"],"award-info":[{"award-number":["UI\/BD\/153712\/2022"]}]},{"name":"PT national funds","award":["2023.09426.CEECIND"],"award-info":[{"award-number":["2023.09426.CEECIND"]}]},{"name":"PT national funds","award":["UIDB\/04540\/2020"],"award-info":[{"award-number":["UIDB\/04540\/2020"]}]},{"name":"PT national funds","award":["UID\/50006"],"award-info":[{"award-number":["UID\/50006"]}]},{"name":"PT national funds","award":["CEECIND\/00793\/2018"],"award-info":[{"award-number":["CEECIND\/00793\/2018"]}]},{"name":"PT national funds","award":["CEECIND\/03877\/2018"],"award-info":[{"award-number":["CEECIND\/03877\/2018"]}]},{"name":"PT national funds","award":["SFRH\/BD\/150659\/2020"],"award-info":[{"award-number":["SFRH\/BD\/150659\/2020"]}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MECI","doi-asserted-by":"publisher","award":["UI\/BD\/153712\/2022"],"award-info":[{"award-number":["UI\/BD\/153712\/2022"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MECI","doi-asserted-by":"publisher","award":["2023.09426.CEECIND"],"award-info":[{"award-number":["2023.09426.CEECIND"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MECI","doi-asserted-by":"publisher","award":["UIDB\/04540\/2020"],"award-info":[{"award-number":["UIDB\/04540\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MECI","doi-asserted-by":"publisher","award":["UID\/50006"],"award-info":[{"award-number":["UID\/50006"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MECI","doi-asserted-by":"publisher","award":["CEECIND\/00793\/2018"],"award-info":[{"award-number":["CEECIND\/00793\/2018"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MECI","doi-asserted-by":"publisher","award":["CEECIND\/03877\/2018"],"award-info":[{"award-number":["CEECIND\/03877\/2018"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MECI","doi-asserted-by":"publisher","award":["SFRH\/BD\/150659\/2020"],"award-info":[{"award-number":["SFRH\/BD\/150659\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MCTES and European Social Fund","doi-asserted-by":"publisher","award":["UI\/BD\/153712\/2022"],"award-info":[{"award-number":["UI\/BD\/153712\/2022"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MCTES and European Social Fund","doi-asserted-by":"publisher","award":["2023.09426.CEECIND"],"award-info":[{"award-number":["2023.09426.CEECIND"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MCTES and European Social Fund","doi-asserted-by":"publisher","award":["UIDB\/04540\/2020"],"award-info":[{"award-number":["UIDB\/04540\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MCTES and European Social Fund","doi-asserted-by":"publisher","award":["UID\/50006"],"award-info":[{"award-number":["UID\/50006"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MCTES and European Social Fund","doi-asserted-by":"publisher","award":["CEECIND\/00793\/2018"],"award-info":[{"award-number":["CEECIND\/00793\/2018"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MCTES and European Social Fund","doi-asserted-by":"publisher","award":["CEECIND\/03877\/2018"],"award-info":[{"award-number":["CEECIND\/03877\/2018"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\/MCTES and European Social Fund","doi-asserted-by":"publisher","award":["SFRH\/BD\/150659\/2020"],"award-info":[{"award-number":["SFRH\/BD\/150659\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Energies"],"abstract":"<jats:p>A series of metal\u2013organic framework-based materials of the MIL-101 family was prepared for potential application as anodic electrocatalysts in the direct borohydride fuel cell. The MIL-101-based materials were tested for borohydride oxidation reaction using cyclic voltammetry and chronoamperometry in alkaline media, with Au@MIL-101-NH2 showing high responsiveness. The obtained data allow for the determination of kinetic parameters that characterize the borohydride oxidation on the prepared electrocatalysts. The activation energy for borohydride oxidation using an Au@MIL-101-NH2 electrocatalyst was as low as 13.6 kJ mol\u22121 with a reaction order of 0.4. The anodic charge transfer coefficient was 0.85, and the number of transferred electrons was 7.97, matching the theoretical maximum value of 8 electrons transferred during the borohydride oxidation reaction. The promising performance of Au@MIL-101-NH2 suggests its potential application as an anode for direct borohydride fuel cells.<\/jats:p>","DOI":"10.3390\/en18174503","type":"journal-article","created":{"date-parts":[[2025,8,26]],"date-time":"2025-08-26T06:26:14Z","timestamp":1756189574000},"page":"4503","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["Au\u2013MIL Nanocomposites with Enhanced Borohydride Oxidation Kinetics for Potential Use in Direct Liquid Fuel Cells"],"prefix":"10.3390","volume":"18","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5784-0439","authenticated-orcid":false,"given":"Ines","family":"Belhaj","sequence":"first","affiliation":[{"name":"Centre of Physics and Engineering of Advanced Materials, Laboratory of Physics for Materials and Emerging Technologies, Chemical Engineering Department, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal"}]},{"given":"Alexander","family":"Becker","sequence":"additional","affiliation":[{"name":"Centre of Physics and Engineering of Advanced Materials, Laboratory of Physics for Materials and Emerging Technologies, Chemical Engineering Department, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal"},{"name":"Technical University of Clausthal, 38678 Clausthal-Zellerfeld, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4472-5834","authenticated-orcid":false,"given":"Alexandre M.","family":"Viana","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1494-1453","authenticated-orcid":false,"given":"Filipe M. B.","family":"Gusm\u00e3o","sequence":"additional","affiliation":[{"name":"Centre of Physics and Engineering of Advanced Materials, Laboratory of Physics for Materials and Emerging Technologies, Chemical Engineering Department, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal"}]},{"given":"Miguel","family":"Chaves","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"given":"Biljana","family":"\u0160ljuki\u0107","sequence":"additional","affiliation":[{"name":"Centre of Physics and Engineering of Advanced Materials, Laboratory of Physics for Materials and Emerging Technologies, Chemical Engineering Department, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8984-0473","authenticated-orcid":false,"given":"Salete S.","family":"Balula","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9229-1412","authenticated-orcid":false,"given":"Lu\u00eds","family":"Cunha-Silva","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7920-2638","authenticated-orcid":false,"given":"Diogo M. F.","family":"Santos","sequence":"additional","affiliation":[{"name":"Centre of Physics and Engineering of Advanced Materials, Laboratory of Physics for Materials and Emerging Technologies, Chemical Engineering Department, Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisbon, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2025,8,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"7271748","DOI":"10.1155\/2024\/7271748","article-title":"A Recent Comprehensive Review of Fuel Cells: History, Types, and Applications","volume":"36","author":"Qasem","year":"2024","journal-title":"Int. J. Energy Res."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"116499","DOI":"10.1016\/j.ssi.2024.116499","article-title":"Structural and Electrochemical Studies of Triple Conducting Nanocomposites for Energy Conversion Devices","volume":"407","author":"Javeed","year":"2024","journal-title":"Solid State Ion."},{"key":"ref_3","unstructured":"Akay, R.G., and Bayrak\u00e7eken Yurtcan, A. (2021). Direct borohydride fuel cells (DBFCs). Direct Liquid Fuel Cells, Elsevier."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"158273","DOI":"10.1016\/j.jallcom.2020.158273","article-title":"Enhanced borohydride oxidation kinetics at gold-rare earth alloys","volume":"857","author":"Saccone","year":"2021","journal-title":"J. Alloys Compd."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"2425","DOI":"10.1002\/anie.201509643","article-title":"A mononuclear CoII coordination complex locked in a confined space and acting as an electrochemical water-oxidation catalyst: A \u2018ship-in-a-bottle\u2019 approach","volume":"55","author":"Manna","year":"2016","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"14129","DOI":"10.1021\/jacs.5b08212","article-title":"Metal\u2013organic frameworks for electrocatalytic reduction of carbon dioxide","volume":"137","author":"Kornienko","year":"2015","journal-title":"J. Am. Chem. Soc."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"27056","DOI":"10.1016\/j.ijhydene.2020.07.034","article-title":"Ruthenium(0) nanoparticles stabilized by metal-organic framework as an efficient electrocatalyst for borohydride oxidation reaction","volume":"45","author":"Yurderi","year":"2020","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"10319","DOI":"10.1016\/j.ijhydene.2010.09.077","article-title":"Nanoporous gold anode catalyst for direct borohydride fuel cell","volume":"36","author":"Nagle","year":"2011","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"10142","DOI":"10.1016\/j.ijhydene.2017.01.117","article-title":"Direct liquid fuel cells: A review","volume":"42","author":"Ong","year":"2017","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.jpowsour.2006.07.032","article-title":"Which type of fuel cell is more competitive for portable application: Direct methanol fuel cells or direct borohydride fuel cells?","volume":"161","author":"Wee","year":"2006","journal-title":"J. Power Sources"},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"235","DOI":"10.1016\/j.jpowsour.2016.07.041","article-title":"Evaluation of anode (electro)catalytic materials for the direct borohydride fuel cell: Methods and benchmarks","volume":"327","author":"Olu","year":"2016","journal-title":"J. Power Sources"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"172","DOI":"10.1016\/j.jpowsour.2006.01.011","article-title":"Direct borohydride fuel cells","volume":"155","author":"Walsh","year":"2006","journal-title":"J. Power Sources"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1016\/j.rser.2009.08.002","article-title":"A comprehensive review of direct borohydride fuel cells","volume":"14","author":"Ma","year":"2010","journal-title":"Renew. Sustain. Energy Rev."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"1269","DOI":"10.1039\/c0ee00115e","article-title":"Direct Borohydride Oxidation: Mechanism Determination and Design of Alloy Catalysts Guided by Density Functional Theory","volume":"3","author":"Rostamikia","year":"2010","journal-title":"Energy Environ. Sci."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"325","DOI":"10.1016\/j.jpowsour.2015.03.118","article-title":"Enhanced activity of Au\u2013Fe\/C anodic electrocatalyst for direct borohydride-hydrogen peroxide fuel cell","volume":"285","author":"Yi","year":"2015","journal-title":"J. Power Sources"},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"3521","DOI":"10.1007\/s11581-021-04115-9","article-title":"Evaluation of Co\u2013Au bimetallic nanoparticles as anode electrocatalyst for direct borohydride-hydrogen peroxide fuel cell","volume":"27","author":"Duan","year":"2021","journal-title":"Ionics"},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"138253","DOI":"10.1016\/j.jcis.2025.138253","article-title":"Constructing a multisite catalyst for achieving efficient and highly selective borohydride oxidation reaction","volume":"699","author":"Xue","year":"2025","journal-title":"J. Colloid Interface Sci."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"e202500005","DOI":"10.1002\/cnma.202500005","article-title":"Reverse Micelle Synthesis of AuyNi100\u2212y Nanoparticles Decorated Multiwalled Carbon Nanotubes as High-Performance Anode Electrocatalysts for Direct Borohydride-Hydrogen Peroxide Fuel Cells","volume":"11","author":"Raul","year":"2025","journal-title":"ChemNanoMat"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"977","DOI":"10.1007\/s10800-022-01824-5","article-title":"Synthesis of AuxCo100\u2212x\/MWCNT Nanoparticles as an Efficient Anode Electrocatalyst for Borohydride Oxidation in Alkaline Medium","volume":"53","author":"Raul","year":"2023","journal-title":"J. Appl. Electrochem."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"27145","DOI":"10.1021\/acsami.4c05784","article-title":"Engineering Partially Oxidized Gold via Oleylamine Modifier as a High-Performance Anode Catalyst in a Direct Borohydride Fuel Cell","volume":"16","author":"Xue","year":"2024","journal-title":"ACS Appl. Mater. Interfaces"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"5456","DOI":"10.1039\/D4SC00676C","article-title":"Drop-Cast Gold Nanoparticles Are Not Always Electrocatalytically Active for the Borohydride Oxidation Reaction","volume":"15","author":"Gaudin","year":"2024","journal-title":"Chem. Sci."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1543","DOI":"10.1007\/s11581-023-04908-0","article-title":"ZIF-Driven N-Doped Carbon Supported Co, Ni-Codoped Au Nanoparticle Catalyst as Efficient Anode Catalyst for Borohydride Electrooxidation Reaction","volume":"29","author":"Yi","year":"2023","journal-title":"Ionics"},{"key":"ref_23","first-page":"1234","article-title":"Borohydride Oxidation Electrocatalysis at Individual, Shape-Controlled Au Nanoparticles","volume":"2","author":"Saha","year":"2021","journal-title":"Electrochem. Sci. Adv."},{"key":"ref_24","doi-asserted-by":"crossref","unstructured":"Bal\u010di\u016bnait\u0117, A., Zabielait\u0117, A., Sukackien\u0117, Z., Kepenien\u0117, V., \u0160imk\u016bnait\u0117, D., Selskis, A., Tama\u0161auskait\u0117-Tama\u0161i\u016bnait\u0117, L., and Norkus, E. (2022). Fabrication of Efficient Gold\u2013Nickel-Supported Titania Nanotube Electrocatalysts for Sodium Borohydride\u2013Hydrogen Peroxide Fuel Cells. Coatings, 12.","DOI":"10.3390\/coatings12060850"},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"21206","DOI":"10.1039\/D1NJ03909A","article-title":"Investigation of ZIF-Derived Co, N Co-Doped Porous Carbon-Supported Au Nanoparticles as an Effective Catalyst for Borohydride Electrooxidation","volume":"45","author":"Yi","year":"2021","journal-title":"New J. Chem."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"14779","DOI":"10.1039\/D1NJ02240G","article-title":"N-Doped Carbon-Coated Co2P-Supported Au Nanocomposite as the Anode Catalyst for Borohydride Electrooxidation","volume":"45","author":"Yi","year":"2021","journal-title":"New J. Chem."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"1351","DOI":"10.1016\/j.renene.2020.12.003","article-title":"Carbon Nanotube\u2013Graphene Supported Bimetallic Electrocatalyst for Direct Borohydride Hydrogen Peroxide Fuel Cells","volume":"172","author":"Uzundurukan","year":"2021","journal-title":"Renew. Energy"},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1016\/j.jcis.2022.12.167","article-title":"Recent advances of metal-organic framework-based and derivative materials in the heterogeneous catalytic removal of volatile organic compounds","volume":"636","author":"Rao","year":"2023","journal-title":"J. Colloid Interface Sci."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"446","DOI":"10.1007\/s12613-022-2562-9","article-title":"A literature review of MOF derivatives of electromagnetic wave absorbers mainly based on pyrolysis","volume":"30","author":"Wang","year":"2023","journal-title":"Int. J. Miner. Metall. Mater."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"146448","DOI":"10.1016\/j.cej.2023.146448","article-title":"Bi-metal-organic framework-derived S-scheme InP\/CuO-C heterostructure for robust photocatalytic degradation of ciprofloxacin in a microfluidic photoreactor","volume":"475","author":"Parsaei","year":"2023","journal-title":"Chem. Eng. J."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"275","DOI":"10.1016\/j.jiec.2023.01.031","article-title":"A spiral shape microfluidic photoreactor with MOF(NiFe)-derived NiSe-Fe3O4\/C heterostructure for photodegradation of tetracycline","volume":"121","author":"Rashid","year":"2023","journal-title":"J. Ind. Eng. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"3644","DOI":"10.1039\/C9SC05636J","article-title":"General synthesis of hierarchical sheet\/plate-like M-BDC (M = Cu, Mn, Ni, and Zr) metal\u2013organic frameworks for electrochemical non-enzymatic glucose sensing","volume":"11","author":"Gumilar","year":"2020","journal-title":"Chem. Sci."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"5414","DOI":"10.1002\/anie.201505581","article-title":"Metal\u2013organic framework (MOF) compounds: Photocatalysts for redox reactions and solar fuel production","volume":"55","author":"Dhakshinamoorthy","year":"2016","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"22159","DOI":"10.1039\/D1TA06238G","article-title":"Revisiting the MIL-101 metal\u2013organic framework: Design, synthesis, modifications, advances, and recent applications","volume":"9","author":"Zorainy","year":"2021","journal-title":"J. Mater. Chem. A"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"132360","DOI":"10.1016\/j.seppur.2025.132360","article-title":"Silver-incorporated NH2-MIL-101(Cr) electrode for highly efficient iodide removal through pseudocapacitive deionization","volume":"364","author":"Eom","year":"2025","journal-title":"Sep. Purif. Technol."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"6775","DOI":"10.1016\/j.electacta.2010.05.091","article-title":"Cyclic voltammetry investigation of borohydride oxidation at a gold electrode","volume":"55","author":"Santos","year":"2010","journal-title":"Electrochim. Acta"},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"F16","DOI":"10.1149\/1.3256136","article-title":"Chronopotentiometric investigation of borohydride oxidation at a gold electrode","volume":"157","author":"Santos","year":"2010","journal-title":"J. Electrochem. Soc."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"F67","DOI":"10.1149\/1.3082371","article-title":"Determination of kinetic and diffusional parameters for sodium borohydride oxidation on gold electrodes","volume":"156","author":"Santos","year":"2009","journal-title":"J. Electrochem. Soc."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"2040","DOI":"10.1126\/science.1116275","article-title":"A chromium terephthalate-based solid with unusually large pore volumes and surface area","volume":"309","author":"Serre","year":"2005","journal-title":"Science"},{"key":"ref_40","doi-asserted-by":"crossref","unstructured":"Chen, M.-L., Zhou, S.-Y., Xu, Z., Ding, L., and Cheng, Y.-H. (2019). Metal-organic frameworks of MIL-100(Fe,Cr) and MIL-101(Cr) for aromatic amines adsorption from aqueous solutions. Molecules, 24.","DOI":"10.3390\/molecules24203718"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"236","DOI":"10.1016\/j.saa.2014.08.030","article-title":"Phytosynthesis of stable Au, Ag and Au\u2013Ag alloy nanoparticles using J. Sambac leaves extract","volume":"137","author":"Yallappa","year":"2015","journal-title":"Spectrochim. Acta A Mol. Biomol. Spectrosc."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"102946","DOI":"10.1016\/j.jece.2019.102946","article-title":"Synthesis of a modified HF-free MIL-101(Cr) nanoadsorbent with enhanced gas selectivity","volume":"7","author":"Tehrani","year":"2019","journal-title":"J. Environ. Chem. Eng."},{"key":"ref_43","doi-asserted-by":"crossref","unstructured":"Liu, Q., Ning, L., Zheng, S., Tao, M., Shi, Y., and He, Y. (2013). Adsorption of carbon dioxide by MIL-101(Cr): Regeneration conditions and influence of flue gas contaminants. Sci. Rep., 3.","DOI":"10.1038\/srep02916"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"197","DOI":"10.1016\/j.jpowsour.2008.06.066","article-title":"Effects of operation conditions on direct borohydride fuel cell performance","volume":"185","author":"Celik","year":"2008","journal-title":"J. Power Sources"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"4709","DOI":"10.1016\/j.jpowsour.2010.02.034","article-title":"Direct borohydride fuel cell using Ni-based composite anodes","volume":"195","author":"Ma","year":"2010","journal-title":"J. Power Sources"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"207","DOI":"10.1016\/j.matchemphys.2018.01.018","article-title":"Preparation of Pt\/G and PtNi\/G nanocatalysts for borohydride oxidation","volume":"208","author":"Hosseini","year":"2018","journal-title":"Mater. Chem. Phys."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"36990","DOI":"10.1016\/j.ijhydene.2022.08.229","article-title":"High-Performance Metal (Au,Cu)\u2013Polypyrrole Nanocomposites for Electrochemical Borohydride Oxidation in Fuel Cell Applications","volume":"47","author":"Tapia","year":"2022","journal-title":"Int. J. Hydrogen Energy"},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"849","DOI":"10.1007\/s11581-021-04368-4","article-title":"Study of ZIF-Derived Iron and Nitrogen Co-Doped Porous Carbon Supported Au Nanoparticles as Electrocatalyst for Borohydride Oxidation Reaction","volume":"28","author":"Yi","year":"2022","journal-title":"Ionics"},{"key":"ref_49","doi-asserted-by":"crossref","unstructured":"Miliki\u0107, J., Oliveira, R.C.P., Tapia, A., Santos, D.M.F., Zdol\u0161ek, N., Trti\u0107-Petrovi\u0107, T., Vrane\u0161, M., and \u0160ljuki\u0107, B. (2021). Ionic Liquid-Derived Carbon-Supported Metal Electrocatalysts as Anodes in Direct Borohydride-Peroxide Fuel Cells. Catalysts, 11.","DOI":"10.3390\/catal11050632"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"114551","DOI":"10.1016\/j.inoche.2025.114551","article-title":"Acid-free synthesis of MIL-101(Cr) for enhanced photocatalytic reduction of CO2","volume":"178","author":"Aziz","year":"2025","journal-title":"Inorg. Chem. Commun."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"123716","DOI":"10.1016\/j.jenvman.2024.123716","article-title":"Synergistic and efficient photocatalytic degradation of rhodamine B and tetracycline in wastewater based on novel S-scheme heterojunction phosphotungstic Acid@MIL-101(Cr)","volume":"373","author":"Shi","year":"2025","journal-title":"J. Environ. Manag."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"238","DOI":"10.1016\/j.jclepro.2019.03.236","article-title":"Removal of atrazine from water using titanium dioxide encapsulated in NH2MIL-101 (Cr)","volume":"224","author":"Moeini","year":"2019","journal-title":"J. Clean. Prod."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"156836","DOI":"10.1016\/j.scitotenv.2022.156836","article-title":"Spatial directional separation and synergetic treatment of Cr(VI) and Rhodamine B","volume":"842","author":"Liu","year":"2022","journal-title":"Sci. Total Environ."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"137429","DOI":"10.1016\/j.jcis.2025.137429","article-title":"MIL-101(Fe)-derived nickel\u2013iron quasi-metal organic framework as efficient catalyst","volume":"691","author":"Guo","year":"2025","journal-title":"J. Colloid Interface Sci."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"131024","DOI":"10.1016\/j.jhazmat.2023.131024","article-title":"Enhanced degradation of tetracycline under natural sunlight","volume":"449","author":"Chen","year":"2023","journal-title":"J. Hazard. Mater."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"2101038","DOI":"10.1002\/adma.202101038","article-title":"MIL-101-derived mesoporous carbon supporting highly exposed Fe single-atom sites","volume":"33","author":"Xie","year":"2021","journal-title":"Adv. Mater."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"22","DOI":"10.1016\/j.jcis.2022.03.038","article-title":"Hydrogen bond donor functionalized poly(ionic liquids)@MIL-101 for CO2 capture","volume":"618","author":"Jiang","year":"2022","journal-title":"J. Colloid Interface Sci."}],"container-title":["Energies"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1073\/18\/17\/4503\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,9]],"date-time":"2025-10-09T18:35:38Z","timestamp":1760034938000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1073\/18\/17\/4503"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2025,8,25]]},"references-count":57,"journal-issue":{"issue":"17","published-online":{"date-parts":[[2025,9]]}},"alternative-id":["en18174503"],"URL":"https:\/\/doi.org\/10.3390\/en18174503","relation":{},"ISSN":["1996-1073"],"issn-type":[{"value":"1996-1073","type":"electronic"}],"subject":[],"published":{"date-parts":[[2025,8,25]]}}}