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PROTEOMASS","award":["UIDB\/50006\/2020","UIDB\/00100\/2020","UIDP\/00100\/2020","LA\/P\/0056\/2020","PTDC\/QUI-COL\/29379\/2017","EXPL\/QUI-QOR\/0586\/2021","CDL-CTTRI-048-88-ARH\/2018","CDL-CTTRI-62-ARH\/2018","FAPESP-2019\/19448-8","PNPD\/CAPES"],"award-info":[{"award-number":["UIDB\/50006\/2020","UIDB\/00100\/2020","UIDP\/00100\/2020","LA\/P\/0056\/2020","PTDC\/QUI-COL\/29379\/2017","EXPL\/QUI-QOR\/0586\/2021","CDL-CTTRI-048-88-ARH\/2018","CDL-CTTRI-62-ARH\/2018","FAPESP-2019\/19448-8","PNPD\/CAPES"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["IJMS"],"abstract":"<jats:p>An efficient synthetic access to new cationic porphyrin-bipyridine iridium(III) bis-cyclometalated complexes was developed. These porphyrins bearing arylbipyridine moieties at \u03b2-pyrrolic positions coordinated with iridium(III), and the corresponding Zn(II) porphyrin complexes were spectroscopically, electrochemically, and electronically characterized. The features displayed by the new cyclometalated porphyrin-bipyridine iridium(III) complexes, namely photoinduced electron transfer process (PET), and a remarkable efficiency to generate 1O2, allowing us to envisage new challenges and opportunities for their applications in several fields, such as photo(catalysis) and photodynamic therapies.<\/jats:p>","DOI":"10.3390\/ijms23147606","type":"journal-article","created":{"date-parts":[[2022,7,10]],"date-time":"2022-07-10T22:48:00Z","timestamp":1657493280000},"page":"7606","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":2,"title":["New Bis-Cyclometalated Iridium(III) Complexes with \u03b2-Substituted Porphyrin-Arylbipyridine as the Ancillary Ligand: Electrochemical and Photophysical Insights"],"prefix":"10.3390","volume":"23","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-9373-7006","authenticated-orcid":false,"given":"Nuno M. 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