{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,10]],"date-time":"2026-03-10T23:58:20Z","timestamp":1773187100206,"version":"3.50.1"},"reference-count":71,"publisher":"MDPI AG","issue":"13","license":[{"start":{"date-parts":[[2021,6,25]],"date-time":"2021-06-25T00:00:00Z","timestamp":1624579200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Two coordination polymers, [Co(\u00b54-L)(H2O)2]n (1) and [Ni(\u00b5-L)(H2O)4]n (2), were solvothermally assembled from the corresponding metal(II) chlorides and biphenyl-4,4-dioxydiacetic acid (H2L) as a flexible dicarboxylate linker. The cobalt(II) compound 1 featured a layer-pillared 3D metal-organic network with a cds topology, while the nickel(II) derivative 2 represented a linear chain 1D coordination polymer with a 2C1 topology. The \u00b54\u2212 and \u00b5-L2\u2212 linkers exhibited different denticity and coordination modes in the synthesized compounds, thus contributing to their structural diversity. The dimensionality of 1 and 2 had an influence on their thermal stability and decomposition processes, which were investigated in detail by TG-DSC and TG-FTIR methods. Thermal decomposition products of coordination polymers were also analyzed by PXRD, confirming the formation of Co3O4\/CoO and NiO as final materials. The obtained compounds broaden a family of coordination polymers assembled from flexible dicarboxylate linkers.<\/jats:p>","DOI":"10.3390\/ma14133545","type":"journal-article","created":{"date-parts":[[2021,6,25]],"date-time":"2021-06-25T04:46:57Z","timestamp":1624596417000},"page":"3545","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":7,"title":["Structural and Thermal Investigations of Co(II) and Ni(II) Coordination Polymers Based on biphenyl-4,4\u2032-dioxydiacetate Linker"],"prefix":"10.3390","volume":"14","author":[{"given":"Halina","family":"G\u0142uchowska","sequence":"first","affiliation":[{"name":"Department of General and Coordination Chemistry and Crystallography, Faculty of Chemistry, Institute of Chemical Sciences, Maria Curie-Sk\u0142odowska University in Lublin, M.C. Sk\u0142odowskiej Sq. 2, 20-031 Lublin, Poland"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4420-1122","authenticated-orcid":false,"given":"Renata","family":"\u0141yszczek","sequence":"additional","affiliation":[{"name":"Department of General and Coordination Chemistry and Crystallography, Faculty of Chemistry, Institute of Chemical Sciences, Maria Curie-Sk\u0142odowska University in Lublin, M.C. Sk\u0142odowskiej Sq. 2, 20-031 Lublin, Poland"}]},{"given":"Liliana","family":"Mazur","sequence":"additional","affiliation":[{"name":"Department of General and Coordination Chemistry and Crystallography, Faculty of Chemistry, Institute of Chemical Sciences, Maria Curie-Sk\u0142odowska University in Lublin, M.C. Sk\u0142odowskiej Sq. 2, 20-031 Lublin, Poland"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-2052-5280","authenticated-orcid":false,"given":"Alexander M.","family":"Kirillov","sequence":"additional","affiliation":[{"name":"Centro de Qu\u00edmica Estrutural, Departamento de Engenharia Qu\u00edmica, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisbon, Portugal"},{"name":"Research Institute of Chemistry, Peoples\u2019 Friendship University of Russia (RUDN University), 6 Miklukho-Maklaya st., 117198 Moscow, Russia"}]}],"member":"1968","published-online":{"date-parts":[[2021,6,25]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2127","DOI":"10.1016\/j.ccr.2006.02.013","article-title":"Coordination polymer networks with O-and N-donors: What they are, why and how they are made?","volume":"250","author":"Robin","year":"2006","journal-title":"Coord. Chem. 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