{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T04:43:17Z","timestamp":1760244197392,"version":"build-2065373602"},"reference-count":30,"publisher":"MDPI AG","issue":"19","license":[{"start":{"date-parts":[[2022,10,9]],"date-time":"2022-10-09T00:00:00Z","timestamp":1665273600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"bilateral Slovakia-Belarus project","award":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"],"award-info":[{"award-number":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"]}]},{"DOI":"10.13039\/501100001871","name":"bilateral Portugal-Germany (FCT-DAAD) project PZT-FREE","doi-asserted-by":"publisher","award":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"],"award-info":[{"award-number":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT\u2014Portuguese Foundation for Science and Technology","doi-asserted-by":"publisher","award":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"],"award-info":[{"award-number":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"CICECO-Aveiro Institute of Materials","doi-asserted-by":"publisher","award":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"],"award-info":[{"award-number":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"name":"national funds through the FCT\/MEC (PIDDAC)","award":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"],"award-info":[{"award-number":["APVV-SK-BY-RD-19-0008","T20SLKG-001","2021.09702.CBM","57610755","SFRH\/BD\/145281\/2019","UIDB\/50011\/2020","UIDP\/50011\/2020","LA\/P\/0006\/2020"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>The annealing behavior of (1-x)BiMg0.5Ti0.5O3\u2013xBiZn0.5Ti0.5O3 [(1-x)BMT\u2013xBZT] perovskite solid solutions synthesized under high pressure was studied in situ via X-ray diffraction and piezoresponse force microscopy. The as prepared ceramics show a morphotropic phase boundary (MPB) between the non-polar orthorhombic and ferroelectric tetragonal states at 75 mol. % BZT. It is shown that annealing above 573 K results in irreversible changes in the phase diagram. Namely, for compositions with 0.2 &lt; x &lt; 0.6, the initial orthorhombic phase transforms into a ferroelectric rhombohedral phase. The new MPB between the rhombohedral and tetragonal phases lies at a lower BZT content of 60 mol. %. The phase diagram of the BMT\u2013BZT annealed ceramics is formally analogous to that of the commercial piezoelectric material lead zirconate titanate. This makes the BMT\u2013BZT system promising for the development of environmentally friendly piezoelectric ceramics.<\/jats:p>","DOI":"10.3390\/ma15196998","type":"journal-article","created":{"date-parts":[[2022,10,9]],"date-time":"2022-10-09T20:49:31Z","timestamp":1665348571000},"page":"6998","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["Annealing-Dependent Morphotropic Phase Boundary in the BiMg0.5Ti0.5O3\u2013BiZn0.5Ti0.5O3 Perovskite System"],"prefix":"10.3390","volume":"15","author":[{"given":"Jo\u00e3o Pedro V.","family":"Cardoso","sequence":"first","affiliation":[{"name":"Department of Materials and Ceramics Engineering and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7155-2473","authenticated-orcid":false,"given":"Vladimir V.","family":"Shvartsman","sequence":"additional","affiliation":[{"name":"Institute for Materials Science and CENIDE\u2014Centre for Nanointegration Duisburg-Essen, University of Duisburg-Essen, 45141 Essen, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9253-1436","authenticated-orcid":false,"given":"Anatoli V.","family":"Pushkarev","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NASB, 220072 Minsk, Belarus"}]},{"given":"Yuriy V.","family":"Radyush","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NASB, 220072 Minsk, Belarus"}]},{"given":"Nikolai M.","family":"Olekhnovich","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NASB, 220072 Minsk, Belarus"}]},{"given":"Dmitry D.","family":"Khalyavin","sequence":"additional","affiliation":[{"name":"ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX, UK"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6289-110X","authenticated-orcid":false,"given":"Erik","family":"\u010ci\u017em\u00e1r","sequence":"additional","affiliation":[{"name":"Institute of Physics, Faculty of Science, Pavol Jozef \u0160af\u00e1rik University, 041 54 Ko\u0161ice, Slovakia"}]},{"given":"Alexander","family":"Feher","sequence":"additional","affiliation":[{"name":"Institute of Physics, Faculty of Science, Pavol Jozef \u0160af\u00e1rik University, 041 54 Ko\u0161ice, Slovakia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5386-0280","authenticated-orcid":false,"given":"Andrei N.","family":"Salak","sequence":"additional","affiliation":[{"name":"Department of Materials and Ceramics Engineering and CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,10,9]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"333","DOI":"10.1143\/JPSJ.7.333","article-title":"Crystal structure of Pb(Zr-Ti)O3","volume":"7","author":"Shirane","year":"1952","journal-title":"J. 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