{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T04:51:12Z","timestamp":1760244672896,"version":"build-2065373602"},"reference-count":20,"publisher":"MDPI AG","issue":"1","license":[{"start":{"date-parts":[[2022,12,24]],"date-time":"2022-12-24T00:00:00Z","timestamp":1671840000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"European Regional Development Fund (FEDER)","award":["PTDC\/CTM-CTM\/31953\/2017","UIDB\/50022\/2020"],"award-info":[{"award-number":["PTDC\/CTM-CTM\/31953\/2017","UIDB\/50022\/2020"]}]},{"name":"FCT","award":["PTDC\/CTM-CTM\/31953\/2017","UIDB\/50022\/2020"],"award-info":[{"award-number":["PTDC\/CTM-CTM\/31953\/2017","UIDB\/50022\/2020"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Materials"],"abstract":"<jats:p>Ru attracted considerable attention as a candidate to replace TaN as a diffusion barrier layer for Cu interconnect metallisation. The addition of W improves the diffusion barrier properties of Ru but appears to weaken the adhesion strength between the barrier and Cu and the direct (seedless) electroplatability behaviour. Although Cu can be directly electroplated on near equimolar Ru-W thin films, no complete substrate coverage is obtained. The understanding of Cu electrocrystallisation on Ru\u2013W is essential to develop methods of fabricating thin, continuous, and well adherent films for advanced interconnect metallisation, where Ru\u2013W thin films could be used as diffusion barriers. This work studies the effect of ultrasonic agitation on the growth of Cu films electroplated on Ru\u2013W, namely on the impact on substrate coverage. Film structure, morphology and chemical composition were evaluated by digital and scanning and transmission electron microscopies, and X-ray diffraction. The results show that Cu particles decrease with increasing current density, but when no electrolyte agitation is applied, substrate coverage is incomplete in the central region, with openings around larger Cu particles, regardless of current density. Under ultrasonic agitation, substrate coverage is remarkably improved. An active particle detachment mechanism is proposed as responsible for attaining improved substrate coverage, only possible at intermediate current density. Lower current densities promote growth over nucleation, whereas higher currents result in extensive hydrogen reduction\/formation. Ultrasonic agitation also enhances a preferential Cu growth along &lt;111&gt; direction.<\/jats:p>","DOI":"10.3390\/ma16010167","type":"journal-article","created":{"date-parts":[[2022,12,27]],"date-time":"2022-12-27T02:55:07Z","timestamp":1672109707000},"page":"167","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":0,"title":["The Effect of Ultrasonic Agitation on the Seedless Growth of Cu on Ru-W Thin Films"],"prefix":"10.3390","volume":"16","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5845-5698","authenticated-orcid":false,"given":"R\u00faben F.","family":"Santos","sequence":"first","affiliation":[{"name":"Department of Metallurgical and Materials Engineering, University of Porto, 4200-465 Porto, Portugal"},{"name":"LAETA\/INEGI\u2014Institute of Science and Innovation in Mechanical and Industrial Engineering, 4200-465 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3920-6511","authenticated-orcid":false,"given":"Bruno M. C.","family":"Oliveira","sequence":"additional","affiliation":[{"name":"Department of Metallurgical and Materials Engineering, University of Porto, 4200-465 Porto, Portugal"},{"name":"LAETA\/INEGI\u2014Institute of Science and Innovation in Mechanical and Industrial Engineering, 4200-465 Porto, Portugal"}]},{"given":"Paulo J.","family":"Ferreira","sequence":"additional","affiliation":[{"name":"International Iberian Nanotechnology Laboratory, 4715-330 Braga, Portugal"},{"name":"Materials Science and Engineering Program, University of Texas at Austin, Austin, TX 78712, USA"},{"name":"Mechanical Engineering Department and IDMEC, IST, University of Lisbon, 1749-016 Lisbon, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3667-0562","authenticated-orcid":false,"given":"Manuel F.","family":"Vieira","sequence":"additional","affiliation":[{"name":"Department of Metallurgical and Materials Engineering, University of Porto, 4200-465 Porto, Portugal"},{"name":"LAETA\/INEGI\u2014Institute of Science and Innovation in Mechanical and Industrial Engineering, 4200-465 Porto, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,12,24]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Akolkar, R. 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Growth Des."}],"container-title":["Materials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1996-1944\/16\/1\/167\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T01:50:22Z","timestamp":1760147422000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1996-1944\/16\/1\/167"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,12,24]]},"references-count":20,"journal-issue":{"issue":"1","published-online":{"date-parts":[[2023,1]]}},"alternative-id":["ma16010167"],"URL":"https:\/\/doi.org\/10.3390\/ma16010167","relation":{},"ISSN":["1996-1944"],"issn-type":[{"type":"electronic","value":"1996-1944"}],"subject":[],"published":{"date-parts":[[2022,12,24]]}}}