{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,10,12]],"date-time":"2025-10-12T04:03:33Z","timestamp":1760241813821,"version":"build-2065373602"},"reference-count":36,"publisher":"MDPI AG","issue":"3","license":[{"start":{"date-parts":[[2018,8,22]],"date-time":"2018-08-22T00:00:00Z","timestamp":1534896000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["QOPNA Pest-C\/QUI\/UI0062\/2011; CICECO POCI-01-0145-FEDER-007679 (Ref. UID\/CTM\/50011\/2013)"],"award-info":[{"award-number":["QOPNA Pest-C\/QUI\/UI0062\/2011; CICECO POCI-01-0145-FEDER-007679 (Ref. UID\/CTM\/50011\/2013)"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Funda\u00e7\u00e3o para a Ci\u00eancia e Tecnologia","award":["SFRH\/BPD\/63237\/2009"],"award-info":[{"award-number":["SFRH\/BPD\/63237\/2009"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Magnetochemistry"],"abstract":"<jats:p>This study describes the first example of a hybrid material comprising corrole- and silica-coated magnetite nanoparticles. Firstly, cuboid and spheroid magnetite nanoparticles were prepared using a simple hydrothermal route, followed by a silica coating. The hybrid nanoparticles were obtained by promoting a covalent link between a gallium (III)(pyridine) complex of 5,10,15-tris(pentafluorophenyl)corrole (GaPFC) and the surface of magnetite\u2013silica core\/shell nanoparticles (Fe3O4@SiO2), shaped both as cuboids and spheroids. The hybrids were characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), ultraviolet-visible spectrophotometry (UV-Vis) and transmission electron microscopy (TEM). Preliminary studies on the capacity of singlet oxygen generation of the hybrid nanoparticles showed that these have lower efficiency values when compared to the pure corrole compound.<\/jats:p>","DOI":"10.3390\/magnetochemistry4030037","type":"journal-article","created":{"date-parts":[[2018,8,23]],"date-time":"2018-08-23T03:00:46Z","timestamp":1534993246000},"page":"37","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":3,"title":["Magnetite\u2013Corrole Hybrid Nanoparticles"],"prefix":"10.3390","volume":"4","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-4661-7407","authenticated-orcid":false,"given":"Rute","family":"Pereira","sequence":"first","affiliation":[{"name":"Department of Chemistry and CICECO, University of Aveiro, 3800-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5456-7243","authenticated-orcid":false,"given":"Tito","family":"Trindade","sequence":"additional","affiliation":[{"name":"Department of Chemistry and CICECO, University of Aveiro, 3800-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0794-144X","authenticated-orcid":false,"given":"Joana","family":"Barata","sequence":"additional","affiliation":[{"name":"Department of Chemistry and CICECO, University of Aveiro, 3800-193 Aveiro, Portugal"},{"name":"Department of Chemistry and QOPNA, University of Aveiro, 3800-193 Aveiro, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2018,8,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"3192","DOI":"10.1021\/acs.chemrev.6b00476","article-title":"Strategies for corrole functionalization","volume":"117","author":"Barata","year":"2017","journal-title":"Chem. 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