{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,24]],"date-time":"2026-02-24T05:24:06Z","timestamp":1771910646837,"version":"3.50.1"},"reference-count":46,"publisher":"MDPI AG","issue":"11","license":[{"start":{"date-parts":[[2021,11,16]],"date-time":"2021-11-16T00:00:00Z","timestamp":1637020800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100005357","name":"Slovak Research and Development Agency","doi-asserted-by":"publisher","award":["APVV SK-BY-RD-19-0008"],"award-info":[{"award-number":["APVV SK-BY-RD-19-0008"]}],"id":[{"id":"10.13039\/501100005357","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/100007595","name":"Belarusian Republican Foundation for Fundamental Research","doi-asserted-by":"publisher","award":["T20SLKG-001"],"award-info":[{"award-number":["T20SLKG-001"]}],"id":[{"id":"10.13039\/100007595","id-type":"DOI","asserted-by":"publisher"}]},{"name":"FCT \u2013 the Portuguese Foundation for Science and Technology","award":["SFRH\/BD\/145281\/2019"],"award-info":[{"award-number":["SFRH\/BD\/145281\/2019"]}]},{"name":"FCT \u2013 the Portuguese Foundation for Science and Technology","award":["the framework contract foreseen in the numbers 4, 5, and 6 of the article 23, of the Decree-Law 57\/2016, of August 29, changed by Law 57\/2017, of July 19"],"award-info":[{"award-number":["the framework contract foreseen in the numbers 4, 5, and 6 of the article 23, of the Decree-Law 57\/2016, of August 29, changed by Law 57\/2017, of July 19"]}]},{"name":"FCT \u2013 the Portuguese Foundation for Science and Technology","award":["UIDB\/50011\/2020 & UIDP\/50011\/2020"],"award-info":[{"award-number":["UIDB\/50011\/2020 & UIDP\/50011\/2020"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Magnetochemistry"],"abstract":"<jats:p>The phase content and sequence, the crystal structure, and the magnetic properties of perovskite solid solutions of the (1\u2212y)BiFeO3\u2013yBiZn0.5Ti0.5O3 series (0.05 \u2264 y \u2264 0.90) synthesized under high pressure have been studied. Two perovskite phases, namely the rhombohedral R3c and the tetragonal P4mm, which correspond to the structural types of the end members, BiFeO3 and BiZn0.5Ti0.5O3, respectively, were revealed in the as-synthesized samples. The rhombohedral and the tetragonal phases were found to coexist in the compositional range of 0.30 \u2264 y \u2264 0.90. Magnetic properties of the BiFe1\u2212y[Zn0.5Ti0.5]yO3 ceramics with y &lt; 0.30 were measured as a function of temperature. The obtained compositional variations of the normalized unit-cell volume and the N\u00e9el temperature of the BiFe1\u2212y[Zn0.5Ti0.5]yO3 perovskites in the range of their rhombohedral phase were compared with the respective dependences for the BiFe1\u2212yB3+yO3 perovskites (where B3+ = Ga, Co, Mn, Cr, and Sc). The role of the high-pressure synthesis in the formation of the antiferromagnetic states different from the modulated cycloidal one characteristic of the parent BiFeO3 is discussed.<\/jats:p>","DOI":"10.3390\/magnetochemistry7110151","type":"journal-article","created":{"date-parts":[[2021,11,17]],"date-time":"2021-11-17T02:42:28Z","timestamp":1637116948000},"page":"151","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":5,"title":["Magnetic Behaviour of Perovskite Compositions Derived from BiFeO3"],"prefix":"10.3390","volume":"7","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-5386-0280","authenticated-orcid":false,"given":"Andrei N.","family":"Salak","sequence":"first","affiliation":[{"name":"Department of Materials and Ceramics Engineering\/CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"given":"Jo\u00e3o Pedro V.","family":"Cardoso","sequence":"additional","affiliation":[{"name":"Department of Materials and Ceramics Engineering\/CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"given":"Joaquim M.","family":"Vieira","sequence":"additional","affiliation":[{"name":"Department of Materials and Ceramics Engineering\/CICECO-Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7155-2473","authenticated-orcid":false,"given":"Vladimir V.","family":"Shvartsman","sequence":"additional","affiliation":[{"name":"Institute for Materials Science and CENIDE-Center for Nanointegration Duisburg-Essen, University of Duisburg-Essen, 45141 Essen, Germany"}]},{"given":"Dmitry D.","family":"Khalyavin","sequence":"additional","affiliation":[{"name":"ISIS Facility, Rutherford Appleton Laboratory, Chilton, Didcot, Oxfordshire OX11 0QX, UK"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0454-2240","authenticated-orcid":false,"given":"Elena L.","family":"Fertman","sequence":"additional","affiliation":[{"name":"B. Verkin Institute for Low Temperature Physics and Engineering, National Academy of Sciences of Ukraine, Nauky 47, 61103 Kharkiv, Ukraine"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7768-8032","authenticated-orcid":false,"given":"Alexey V.","family":"Fedorchenko","sequence":"additional","affiliation":[{"name":"B. Verkin Institute for Low Temperature Physics and Engineering, National Academy of Sciences of Ukraine, Nauky 47, 61103 Kharkiv, Ukraine"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9253-1436","authenticated-orcid":false,"given":"Anatoli V.","family":"Pushkarev","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre, National Academy of Sciences of Belarus, P. Brovka 19, 220072 Minsk, Belarus"}]},{"given":"Yury V.","family":"Radyush","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre, National Academy of Sciences of Belarus, P. Brovka 19, 220072 Minsk, Belarus"}]},{"given":"Nikolai M.","family":"Olekhnovich","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre, National Academy of Sciences of Belarus, P. Brovka 19, 220072 Minsk, Belarus"}]},{"given":"R\u00f3bert","family":"Tarasenko","sequence":"additional","affiliation":[{"name":"Institute of Physics, Faculty of Science, Pavol Jozef \u0160af\u00e1rik University, Park Angelinum 9, 041 54 Ko\u0161ice, Slovakia"}]},{"given":"Alexander","family":"Feher","sequence":"additional","affiliation":[{"name":"Institute of Physics, Faculty of Science, Pavol Jozef \u0160af\u00e1rik University, Park Angelinum 9, 041 54 Ko\u0161ice, Slovakia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6289-110X","authenticated-orcid":false,"given":"Erik","family":"\u010ci\u017em\u00e1r","sequence":"additional","affiliation":[{"name":"Institute of Physics, Faculty of Science, Pavol Jozef \u0160af\u00e1rik University, Park Angelinum 9, 041 54 Ko\u0161ice, Slovakia"}]}],"member":"1968","published-online":{"date-parts":[[2021,11,16]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"20","DOI":"10.1103\/Physics.2.20","article-title":"Classifying multiferroics: Mechanisms and effects","volume":"2","author":"Khomskii","year":"2009","journal-title":"Physics"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"2463","DOI":"10.1002\/adma.200802849","article-title":"Physics and applications of bismuth ferrite","volume":"21","author":"Catalan","year":"2009","journal-title":"Adv. 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