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The relevance of this work stems from the lack of research on this specific alloy and the absence of reports in the literature with molybdenum percentages above 2 at.%. Ti50Ni50\u2212XMox alloys were produced by the plasma arc melting method, with six different compositions (x = 0, 0.5, 1, 2, 3, and 4 at.% Mo), and a comprehensive analysis of microstructure, chemical composition, thermal, mechanical, and electrochemical properties was carried out. The results demonstrated significant alterations in the microstructure of the Ni\u2013Ti alloy with the addition of molybdenum presenting several phases, precipitates (TiNi, Ti2Ni), and oxides (Ti4Ni2O, TiO, and TiO3). The stability of the B2 phase increased with molybdenum content, and the monoclinic martensite (B19\u2032) phase was identified only in the Ni\u2013Ti sample. Introducing molybdenum into the Ni\u2013Ti alloy generated the R-phase and shifted the phase transformation peaks to lower temperatures, as differential scanning calorimetry (DSC) indicated. Microhardness and elastic modulus decreased with increasing Mo content, ranging from 494 HV to 272 HV and 74 GPa to 63 GPa, respectively. Corrosion tests revealed increased corrosion resistance with increasing Mo content, reaching a polarization resistance of 2710 k\u03a9\u00b7cm2 and corrosion current of 11.3 \u00b5A. Therefore, this study points to Ti\u2013Ni\u2013Mo alloys as potential candidates to increase the range of Ni\u2013Ti alloy applications, mainly in biomaterials, reinforcing its relevance and need in current alloy research.<\/jats:p>","DOI":"10.3390\/met13101637","type":"journal-article","created":{"date-parts":[[2023,9,24]],"date-time":"2023-09-24T10:40:22Z","timestamp":1695552022000},"page":"1637","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":1,"title":["Thermal, Mechanical, and Electrochemical Characterization of Ti50Ni50\u2212XMox Alloys Obtained by Plasma Arc Melting"],"prefix":"10.3390","volume":"13","author":[{"ORCID":"https:\/\/orcid.org\/0000-0001-9835-8016","authenticated-orcid":false,"given":"Josiane D.","family":"Costa","sequence":"first","affiliation":[{"name":"Department of Chemical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]},{"given":"Mikarla B.","family":"Sousa","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9641-5037","authenticated-orcid":false,"given":"Arthur F.","family":"Almeida","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0473-8443","authenticated-orcid":false,"given":"Jos\u00e9 A. M.","family":"Oliveira","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0138-3643","authenticated-orcid":false,"given":"Paulo C. S.","family":"Silva","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3299-405X","authenticated-orcid":false,"given":"Jos\u00e9 J. N.","family":"Alves","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9029-6922","authenticated-orcid":false,"given":"Ana R. N.","family":"Campos","sequence":"additional","affiliation":[{"name":"Department of Chemical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8939-0946","authenticated-orcid":false,"given":"Carlos J.","family":"Ara\u00fajo","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7075-7709","authenticated-orcid":false,"given":"Renato A. C.","family":"Santana","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1026-4523","authenticated-orcid":false,"given":"Jo\u00e3o M. P. Q.","family":"Delgado","sequence":"additional","affiliation":[{"name":"Construct-LFC, Civil Engineering Department, Faculty of Engineering, University of Porto, 4200-465 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-1691-1872","authenticated-orcid":false,"given":"Antonio G. B.","family":"Lima","sequence":"additional","affiliation":[{"name":"Department of Mechanical Engineering, Federal University of Campina Grande, Avenida Apr\u00edgio Veloso 882, Campina Grande 58429-970, Brazil"}]}],"member":"1968","published-online":{"date-parts":[[2023,9,23]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"109593","DOI":"10.1016\/j.matdes.2021.109593","article-title":"Experimentally Validated Constitutive Model for NiTi-Based Shape Memory Alloys Featuring Intermediate R-Phase Transformation: A Case Study of Ni48Ti49Fe3","volume":"203","author":"Frost","year":"2021","journal-title":"Mater. 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