{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,4]],"date-time":"2026-04-04T04:17:35Z","timestamp":1775276255093,"version":"3.50.1"},"reference-count":77,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2022,10,15]],"date-time":"2022-10-15T00:00:00Z","timestamp":1665792000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"national funds (PIDDAC)","award":["UIDB\/500019\/2020"],"award-info":[{"award-number":["UIDB\/500019\/2020"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Minerals"],"abstract":"<jats:p>Chromite oxidation during serpentinization of host peridotites is a well-documented process. Detailed compositional characterization of chromites and Cr-rich spinels from three geotectonic settings provided the basis for this study, focused on the comparison of their oxidation patterns as a means to evaluate the relative mobility of spinel components during serpentinization-related oxidation in those different contexts, namely: (i) tectonic exposures of serpentinized oceanic upper-mantle in the Azores sector of the Mid-Atlantic Ridge (MAR); (ii) serpentinized peridotites from Cabe\u00e7o de Vide (CV, Alter do Ch\u00e3o Massif, Portugal); and (iii) serpentinized subcontinental mantle peridotites from the Ronda Massif (Spain). Electron microprobe data show that: (i) irrespective of geotectonic setting and original composition, Cr-spinels follow similar oxidation trends; (ii) early Cr-spinel oxidation, involving significant Mg- and Al-depletion leading to the formation of ferritchromit rims, has been more intense in the CV serpentinites than in the more recent MAR and Ronda serpentinites; (iii) with the possible exception of Zn, trace components (Mn, Ti, V, Ni and Co) seem to be relatively immobile during spinel oxidation, thus becoming slightly enriched in ferritchromit rims; (iv) extreme Cr-spinel oxidation is responsible for incomplete outer rims of magnetite on several grains. Time, fluid pH, and fluid\/rock ratios seem to be the main factors controlling the intensity and extension of chromite oxidation.<\/jats:p>","DOI":"10.3390\/min12101300","type":"journal-article","created":{"date-parts":[[2022,10,17]],"date-time":"2022-10-17T03:43:58Z","timestamp":1665978238000},"page":"1300","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Chromite Oxidation Patterns Associated to Serpentinization: Case Studies from the Mid-Atlantic Ridge, the Alter do Ch\u00e3o Massif (NE Alentejo, Portugal) and the Ronda Massif (Spain)"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-3604-6073","authenticated-orcid":false,"given":"Isabel","family":"Ribeiro da Costa","sequence":"first","affiliation":[{"name":"Departamento de Geologia, Faculdade de Ci\u00eancias, Universidade de Lisboa, 1749-016 Lisbon, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2750-3356","authenticated-orcid":false,"given":"Fernando","family":"Barriga","sequence":"additional","affiliation":[{"name":"Departamento de Geologia, Faculdade de Ci\u00eancias, Universidade de Lisboa, 1749-016 Lisbon, Portugal"},{"name":"Instituto Dom Luiz (IDL), Faculdade de Ci\u00eancias da Universidade de Lisboa, 1749-016 Lisbon, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,10,15]]},"reference":[{"key":"ref_1","unstructured":"Deer, W.A., Howie, R.A., and Zussman, J. (1992). An Introduction to Rock-Forming Minerals, Longman. [2nd ed.]."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"183","DOI":"10.1127\/ejm\/2019\/0031-2788","article-title":"Nomenclature and classification of the spinel supergroup","volume":"31","author":"Bosi","year":"2019","journal-title":"Eur. J. Mineral."},{"key":"ref_3","first-page":"1084","article-title":"Chemical composition of altered chromites from the Stillwater Complex, Montana","volume":"54","author":"Beeson","year":"1969","journal-title":"Amer. Min."},{"key":"ref_4","first-page":"1236","article-title":"Alteration of chromite during serpentinization in the Pennsylvania-Maryland District","volume":"59","author":"Ulmer","year":"1974","journal-title":"Amer. Min."},{"key":"ref_5","first-page":"608","article-title":"Alteration of chromite from the Twin Sisters dunite, Washington","volume":"59","author":"Onyeagocha","year":"1974","journal-title":"Amer. Min."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"699","DOI":"10.1130\/0016-7606(1978)89<699:TACVOO>2.0.CO;2","article-title":"Textural and chemical variations of olivine and chrome spinel in the East Dover ultramafic bodies, south-central Vermont","volume":"89","author":"Hoffman","year":"1978","journal-title":"Geol. Soc. Am. Bull."},{"key":"ref_7","unstructured":"Georgiou, E., and Xenophontos, C. (1990). Chromite occurrences and associated plutonic rocks in the Akapnou Forest. Ophiolites Oceanic Crustal Analogues: Proceedings of the Symposium \u201cTroodos 1987\u201d, Geological Survey Dept."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"337","DOI":"10.1007\/BF00306543","article-title":"Effects of hydrothermal alteration on the compositions of chromian spinels","volume":"105","author":"Kimball","year":"1990","journal-title":"Contrib. Mineral. Petrol."},{"key":"ref_9","first-page":"729","article-title":"Chromite: From the fiery rain of chondrules to the Kilauea Iki lava lake","volume":"32","author":"Roeder","year":"1994","journal-title":"Can. Min."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"655","DOI":"10.1093\/petrology\/42.4.655","article-title":"Factors controlling chemistry of magmatic spinel: An empirical study of associated olivine, Cr-spinel and melt inclusions from primitive rocks","volume":"42","author":"Kamenetsky","year":"2001","journal-title":"J. Petrol."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"266","DOI":"10.1007\/s00410-005-0654-y","article-title":"Hydrothermally reset magmatic spinels in retrograde serpentinites: Formation of \u00abferritchromit\u00bb rims and chlorite aureoles","volume":"149","author":"Mellini","year":"2005","journal-title":"Contrib. Mineral. Petrol."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1007\/s00410-019-1605-3","article-title":"Diffusion pathways of Fe2+ and Fe3+ during the formation of ferrian chromite: A \u00b5Xanes study","volume":"174","author":"Gervilla","year":"2019","journal-title":"Contrib. Mineral. Petrol."},{"key":"ref_13","unstructured":"Ribeiro da Costa, I. (2005). Serpentinization on the Mid-Atlantic Ridge: The Rainbow, Saldanha and Menez Hom Sites. [PhD Thesis, Lisbon University]."},{"key":"ref_14","first-page":"23","article-title":"The upper mantle beneath the Mid-Atlantic Ridge in the Azores sector","volume":"97","author":"Barriga","year":"2010","journal-title":"Comun. Geol."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"677","DOI":"10.3749\/canmin.1900010","article-title":"Serpentinization at the Rainbow and Saldanha sites, Mid-Atlantic Ridge: Mineralogical, geochemical and isotopic features","volume":"57","author":"Wicks","year":"2019","journal-title":"Can. Min."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"439","DOI":"10.1029\/93RG01952","article-title":"Crustal structure of North Atlantic fracture zones","volume":"31","author":"Detrick","year":"1993","journal-title":"Rev. Geophys."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"93","DOI":"10.1016\/0012-821X(95)00224-Z","article-title":"The HEAT Scientific Team. Hydrothermal exploration at the Azores Triple Junction: Tectonic control of venting at slow spreading ridges?","volume":"138","author":"German","year":"1996","journal-title":"Earth Planet. Sci. Lett."},{"key":"ref_18","first-page":"F832","article-title":"The FLORES Scientific Party. The Rainbow serpentinites and serpentinite-sulphide stockwork (Mid-Atlantic Ridge, AMAR segment): A preliminary report of the FLORES results","volume":"78","author":"Barriga","year":"1997","journal-title":"Eos Trans. Am. Geophys. Union"},{"key":"ref_19","first-page":"F832","article-title":"Discovery and first submersible investigations on the Rainbow hydrothermal field on the MAR (36\u00b014\u2019 N)","volume":"78","author":"Fouquet","year":"1997","journal-title":"EOS Trans. Am. Geophys. Union"},{"key":"ref_20","unstructured":"Barriga, F.J.A.S., Fouquet, Y., Almeida, A., Biscoito, M., Charlou, J.L., Costa, R.L.P., Dias, A., Marques, A., Miranda, J.M., and Olu, K. (1999). Preliminary results of the Saldanha mission (FAMOUS segment of the MAR 36\u00b030\u2019 N). Geophys. Res. Abstr., 1."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"231","DOI":"10.1016\/S0012-821X(00)00090-X","article-title":"Second-order segmentation; the relationship between volcanism and tectonism at the MAR, 38\u00b0 N\u201335\u00b040\u2019 N","volume":"178","author":"Parson","year":"2000","journal-title":"Earth Planet. Sci. Lett."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1016\/S0012-821X(00)00034-0","article-title":"Non-transform offsets along the Mid-Atlantic Ridge south of the Azores (38\u00b0 N\u201334\u00b0 N): Ultramafic exposures and hosting of hydrothermal events","volume":"177","author":"Charlou","year":"2000","journal-title":"Earth Planet. Sci. Lett."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"299","DOI":"10.1023\/A:1025711502122","article-title":"Study of the Saldanha massif (MAR, 36\u00b034\u2019 N): Constraints from rock magnetic and geophysical data","volume":"23","author":"Miranda","year":"2003","journal-title":"Mar. Geophys. Res."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"11616","DOI":"10.1029\/JB086iB12p11616","article-title":"Serpentinization faults and their role in the tectonics of slow spreading ridges","volume":"86","author":"Francis","year":"1981","journal-title":"J. Geophys. Res."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1016\/0040-1951(91)90353-T","article-title":"Emplacement of deep crustal and mantle rocks on the west median valley wall of the MARK area (MAR, 23\u00b0 N)","volume":"190","author":"Cannat","year":"1991","journal-title":"Tectonophysics"},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"3767","DOI":"10.1029\/94JB02649","article-title":"Gravity anomalies and crustal thickness variations along the Mid-Atlantic Ridge betweeen 33\u00b0 N and 40\u00b0 N","volume":"100","author":"Detrick","year":"1995","journal-title":"J. Geophys. Res."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"11937","DOI":"10.1029\/94JB00338","article-title":"A geological model for the structure of ridge segments in slow-spreading ocean crust","volume":"99-B","author":"Tucholke","year":"1994","journal-title":"J. Geophys. Res."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1130\/0091-7613(1995)023<0049:TCUEAR>2.3.CO;2","article-title":"Thin crust, ultramafic exposures, and rugged faulting patterns at the Mid-Atlantic Ridge (22\u00b0\u201324\u00b0 N)","volume":"23","author":"Cannat","year":"1995","journal-title":"Geology"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"181","DOI":"10.1016\/S0012-821X(97)81847-X","article-title":"Effects of serpentinization on the lithosphere strength and the style of normal faulting at slow-spreading ridges","volume":"151","author":"Hirth","year":"1997","journal-title":"Earth Planet. Sci. Lett."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"1171","DOI":"10.1093\/petrology\/42.6.1171","article-title":"Melt generation at very slow-spreading oceanic ridges: Constraints from geochemical and geophysical data","volume":"42","author":"White","year":"2001","journal-title":"J. Petrol."},{"key":"ref_31","unstructured":"Gon\u00e7alves, F., and Fernandes, A.P. (1973). Not\u00edcia Explicativa da Folha 32B: Portalegre, Carta Geol\u00f3gica de Portugal 1\/50,000, Servi\u00e7os Geol\u00f3gicos de Portugal."},{"key":"ref_32","first-page":"155","article-title":"Complexo plut\u00f3nico b\u00e1sico e ultrab\u00e1sico de Alter do Ch\u00e3o","volume":"18","author":"Canilho","year":"1973","journal-title":"Bol. Soc. Geol. Port."},{"key":"ref_33","unstructured":"Ribeiro da Costa, I. (1985). Estudo do Processo de Rodingitiza\u00e7\u00e3o das Rochas Gabr\u00f3icas de Cabe\u00e7o de Vide Associado \u00e0 Serpentiniza\u00e7\u00e3o dos Ultrabasitos Encaixantes. [Graduation Thesis, Lisbon University]."},{"key":"ref_34","unstructured":"Lopes, J.M.C.C.A. (2004). Petrologia e Geoqu\u00edmica de Complexos Plut\u00f3nicosdo NE Alentejano (ZOM), Portugal Central: Prov\u00edncia Alcalina e Maci\u00e7o de Campo Maior. [Ph.D. Thesis, University of \u00c9vora]."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"163","DOI":"10.1016\/0012-821X(92)90046-X","article-title":"Mantle lithosphere bodies in the Alboran crustal domain (Ronda peridotites Betic-Rif orogenic belt)","volume":"110","author":"Banda","year":"1992","journal-title":"Earth Planet. Sci. Lett."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"193","DOI":"10.1016\/0191-8141(92)90056-3","article-title":"Tectonic evolution of the Alpuj\u00e1rride Complex (Betic Cordilleras, southern Spain)","volume":"14","author":"Cuevas","year":"1992","journal-title":"J. Struct. Geol."},{"key":"ref_37","doi-asserted-by":"crossref","unstructured":"Menzies, A.M., and Dupuy, C. (1991). Orogenic massifs: Protolith, process and provenance. J. Petrol., 1\u201316.","DOI":"10.1093\/petrology\/Special_Volume.2.1"},{"key":"ref_38","first-page":"247","article-title":"Some critical differences between alpine-type and stratiform peridotite-gabbro complexes","volume":"13","author":"Thayer","year":"1960","journal-title":"Int. Geol. Congr. 21th Sess. Cph."},{"key":"ref_39","first-page":"397","article-title":"R\u00e9partition en deux provinces des p\u00e9ridotites des cha\u00eenes alpines longeant la M\u00e9diterran\u00e9e","volume":"52","author":"Nicolas","year":"1972","journal-title":"Bull. Suisse Miner. Petrol."},{"key":"ref_40","first-page":"257","article-title":"The origin of mafic layers in the Ronda high-temperature peridotite intrusion, S. Sain: An evidence of partial fusion and fractional crystallization in the upper mantle","volume":"275","author":"Obata","year":"1980","journal-title":"Colloq. Int. CNRS"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"227","DOI":"10.1016\/S0040-1951(97)00124-8","article-title":"Sequential development of the metamorphic aureole beneath the Ronda peridotites and its bearing on the tectonic evolution of the Betic Cordillera","volume":"279","author":"Cuevas","year":"1997","journal-title":"Tectonophysics"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"533","DOI":"10.1093\/petrology\/21.3.533","article-title":"The Ronda peridotite: Granet-, spinel- and plagioclase-lherzolite facies and the P-T trajectories of a high-temperature mantle intrusion","volume":"21","author":"Obata","year":"1980","journal-title":"J. Petrol."},{"key":"ref_43","first-page":"1673","article-title":"Cin\u00e9matique de l\u2019extrusion, \u00e0 partir du manteaux, des p\u00e9ridotites de la Sierra Bermeja (Seran\u00eda de Ronda, Espagne)","volume":"278","author":"Darot","year":"1974","journal-title":"C. Rend. Acad. Sc. Paris"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"172","DOI":"10.1130\/0016-7606(1978)89<172:EOTRPS>2.0.CO;2","article-title":"Emplacement of the Ronda peridotite, Sierra Bermeja, Spain","volume":"89","author":"Lundeen","year":"1978","journal-title":"Bull. Geol. Soc. Am."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"655","DOI":"10.1144\/0016-764902-108","article-title":"Exhumation of the Ronda peridotite and its crustal envelope: Constraints from thermal modeling of a P-T-time array","volume":"160","author":"Platt","year":"2003","journal-title":"J. Geol. Soc. London"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"137","DOI":"10.1016\/0264-3707(90)90003-D","article-title":"Deep structure of the Betic Cordillera derived from the interpretatin of a complete Bouger anomaly map","volume":"12","author":"Casas","year":"1990","journal-title":"J. Geod."},{"key":"ref_47","unstructured":"Balany\u00e1, J.C. (1991). Estructura del Dom\u00ednio de Albor\u00e1n en la del Arco de Gibraltar. [Ph.D. Thesis, Granada University]."},{"key":"ref_48","unstructured":"Van der Wal, D. (1993). Deformation processes in mantle peridotites with emphasis on the Ronda peridotite of SW Spain. [Ph.D. Thesis, Utrecht Universit]."},{"key":"ref_49","first-page":"381","article-title":"The Ronda peridotites (Los Reales nappe): An example of the relationship between lithospheric thickening by oblique tectonics and late extensional deformation within the Betic Cordillera (Spain)","volume":"138","year":"1994","journal-title":"Tectonophysics"},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"981","DOI":"10.1130\/G22801A.1","article-title":"Early Miocene continental subduction and rapid exhumation in the western Mediterranean","volume":"34","author":"Platt","year":"2006","journal-title":"Geology"},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1144\/jgs2011-151","article-title":"Backarc basin inversion and subcontinental mantle emplacement in the crust: Kilometre-scale folding and shearing at the base of the proto-Albor\u00e1n lithospheric mantle (Betic Cordillera, southern Spain)","volume":"170","author":"Hidas","year":"2013","journal-title":"J. Geol. Soc."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"105215","DOI":"10.1016\/j.lithos.2019.105215","article-title":"Geochemistry and mineralogy of serpentinization-driven hyperalkaline springs in the Ronda peridotites","volume":"350\u2013351","author":"Giampouras","year":"2019","journal-title":"Lithos"},{"key":"ref_53","unstructured":"Figueiras, J., and Mateus, A. Personal Communication."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"437","DOI":"10.1127\/0935-1221\/2002\/0014-0437","article-title":"57Fe M\u00f6ssbauer spectroscopy study of the correlation between Fe3+ contente and the magnetic properties of natural Cr-spinels","volume":"14","author":"Waerenborgh","year":"2002","journal-title":"Eur. J. Mineral."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"47","DOI":"10.1016\/0009-2541(67)90004-6","article-title":"Composition\u2014volume relationships of metasomatism","volume":"2","author":"Gresens","year":"1967","journal-title":"Chem. Geol."},{"key":"ref_56","first-page":"A124","article-title":"Oxygen barometry of upper mantle beneath the Azores sector of the Mid-Atlantic Ridge","volume":"70 (18S)","author":"Jesus","year":"2006","journal-title":"Geochim. Cosmochim. Acta"},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"54","DOI":"10.1007\/BF00373711","article-title":"Chromian spinel as a petrogenetic indicator in abyssal and alpine-type peridotites and spatially associated lavas","volume":"86","author":"Dick","year":"1984","journal-title":"Contrib. Mineral. Petrol."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"179","DOI":"10.1016\/j.chemgeo.2006.04.011","article-title":"Geochemistry of abyssal peridotites (Mid-Atlantic Ridge, 15\u00b020\u2032 N, ODP Leg 209): Implications for fluid\/rock interaction in slow spreading environments","volume":"234","author":"Paulick","year":"2006","journal-title":"Chem. Geol."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"13591412","DOI":"10.1016\/S0016-7037(97)00009-4","article-title":"Prediction of the thermodynamic properties of aqueous metal complexes to 1000 \u00b0C and 5 kb","volume":"61","author":"Sverjensky","year":"1997","journal-title":"Geochim. Cosmochim. Acta"},{"key":"ref_60","first-page":"775","article-title":"Lizardite and its parent enstatite: A study by X-ray diffraction and transmission electron microscopy","volume":"24","author":"Wicks","year":"1986","journal-title":"Can. Min."},{"key":"ref_61","first-page":"B04102","article-title":"Serpentinization of oceanic peridotites: 2. Kinetics and processes of San Carlos olivine hydrothermal alteration","volume":"117","author":"Malvoisin","year":"2012","journal-title":"J. Geophys. Res."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"135","DOI":"10.1130\/G35068.1","article-title":"Magnetite in seafloor serpentinite\u2014Some like it hot","volume":"42","author":"Klein","year":"2014","journal-title":"Geology"},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"207","DOI":"10.2475\/ajs.273.3.207","article-title":"Oxygen and hydrogen isotope studies of serpentinization of ultramafic rocks on oceanic environments and continental ophiolite complexes","volume":"273","author":"Wenner","year":"1973","journal-title":"Am. J. Sci."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"291","DOI":"10.1016\/0012-821X(90)90192-Z","article-title":"Origin of waters responsible for serpentinization of the Izu-Ogasawara-Mariana forearc seamounts in view of hydrogen and oxygen isotope ratios","volume":"100","author":"Sakai","year":"1990","journal-title":"Earth Planet. Sci. Lett."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"1210","DOI":"10.1134\/S0016702907120038","article-title":"Solubility of Minerals of Metamorphic and Metasomatic Rocks in Hydrothermal Solutions of Varying Acidity: Thermodynamic Modeling at 400\u2013800 \u00b0C and 1\u20135 kbar","volume":"45","author":"Azimov","year":"2007","journal-title":"Geochem. Int."},{"key":"ref_66","unstructured":"Sec\u00e7\u00e3o de Geologia Econ\u00f3mica e Aplicada (1990). Enquadramento geol\u00f3gico e hidrogeol\u00f3gico das nacentes de \u00e1gua minero-medicinal de Cabe\u00e7o de Vide. Livro de Homenagem a Carlos Romariz, Departamento de Geologia, Universidade de Lisboa."},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"3278","DOI":"10.1016\/j.apgeochem.2008.06.029","article-title":"Origins of high pH mineral waters from ultramafic rocks, Central Portugal","volume":"23","author":"Marques","year":"2008","journal-title":"Appl. Geochem."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"830","DOI":"10.1126\/science.156.3776.830","article-title":"Geochemical evidence of present-day serpentinization","volume":"156","author":"Barnes","year":"1967","journal-title":"Science"},{"key":"ref_69","first-page":"301","article-title":"Serpentinizaci\u00f3n de la peridotita de Ronda (Cordillera B\u00e9tica) por la interacci\u00f3n con fluidos ricos en volatiles: Comportamiento del B","volume":"10","author":"Acosta","year":"1997","journal-title":"Rev. Soc. Geol. Espa\u00f1a"},{"key":"ref_70","unstructured":"Palmer, D.A., Wesolowski, D., and B\u00e9n\u00e9zeth, P. (2022, August 16). The Aqueous Chemistry of Aluminium in a New Approach to High-Temperature Solubility Measurements. Available online: digital.library.unt.edu."},{"key":"ref_71","first-page":"118","article-title":"On the Differential Mobility of Components during Experimental Diffusion Metasomatism","volume":"Volume 2","author":"Zaraiskii","year":"1979","journal-title":"Problems of Physicochemical Petrology (State of Fluid and Solutions, Metasomatism, Ore Formation)"},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"185","DOI":"10.1016\/0009-2541(70)90018-5","article-title":"Some experimental and theoretical observationson the kinetics of hydration reactions with particular reference to serpentinization","volume":"6","author":"Martin","year":"1970","journal-title":"Chem. Geol."},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"123","DOI":"10.1016\/0040-1951(85)90225-2","article-title":"Rate of serpentinization in seafloor environments","volume":"116","author":"Macdonald","year":"1985","journal-title":"Tectonophysics"},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"497","DOI":"10.1016\/0012-821X(87)90144-0","article-title":"Fluids in the lithosphere, 1. Experimentally-determined wetting characteristics of CO2-H2O fluids and their implications for fluid transport, host-rock physical properties, and fluid inclusion formation","volume":"85","author":"Watson","year":"1987","journal-title":"Earth Planet. Sci. Lett."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"409","DOI":"10.1007\/BF01798966","article-title":"The opaque minerals and economic geology of the Nemeiben Ultramafic Complex, Saskatchewan, Canada","volume":"16","author":"Macfarlane","year":"1981","journal-title":"Mineral. Deposita"},{"key":"ref_76","doi-asserted-by":"crossref","first-page":"39","DOI":"10.1016\/S0024-4937(03)00090-2","article-title":"Origin of chromite in mafic-ultramafic-hosted massive sulfides from the Main Uralian Fault, South Urals, Russia","volume":"70","author":"Tesalina","year":"2003","journal-title":"Lithos"},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"343","DOI":"10.2113\/gsecongeo.94.3.343","article-title":"Chrome spinels from the Jinchuan Ni-Cu sulfide deposit, Gansu Province, People\u2019s Republic of China","volume":"94","author":"Barnes","year":"1999","journal-title":"Econ. Geol."}],"container-title":["Minerals"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2075-163X\/12\/10\/1300\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T00:55:01Z","timestamp":1760144101000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2075-163X\/12\/10\/1300"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,10,15]]},"references-count":77,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2022,10]]}},"alternative-id":["min12101300"],"URL":"https:\/\/doi.org\/10.3390\/min12101300","relation":{},"ISSN":["2075-163X"],"issn-type":[{"value":"2075-163X","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,10,15]]}}}