{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,11,11]],"date-time":"2025-11-11T12:53:05Z","timestamp":1762865585584,"version":"build-2065373602"},"reference-count":35,"publisher":"MDPI AG","issue":"9","license":[{"start":{"date-parts":[[2009,9,16]],"date-time":"2009-09-16T00:00:00Z","timestamp":1253059200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/3.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The oxodiperoxo complex MoO(O2)2(tbbpy) (tbbpy = 4,4'-di-tert-butyl-2,2'- bipyridine) was isolated from the reaction of MoO2Cl2(tbbpy) in water under microwaveassisted heating at 120 \u00baC for 4 h. The structure of the oxodiperoxo complex was determined by single crystal X-ray diffraction. The MoVI centre is seven-coordinated with a geometry which strongly resembles a highly distorted bipyramid. Individual MoO(O2)2(tbbpy) complexes are interdigitated along the [010] direction to form a column. The crystal structure is formed by the close packing of the columnar-stacked complexes. Interactions between neighbouring columns are essentially of van der Waals type mediated by the need to effectively fill the available space.<\/jats:p>","DOI":"10.3390\/molecules14093610","type":"journal-article","created":{"date-parts":[[2009,9,16]],"date-time":"2009-09-16T12:07:21Z","timestamp":1253102841000},"page":"3610-3620","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Microwave-Assisted Synthesis and Crystal Structure of Oxo(diperoxo)(4,4'-di-tert-butyl-2,2'-bipyridine)-molybdenum(VI)"],"prefix":"10.3390","volume":"14","author":[{"given":"Tatiana  R.","family":"Amarante","sequence":"first","affiliation":[{"name":"Department of Chemistry, CICECO, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"given":"Filipe  A.","family":"Almeida Paz","sequence":"additional","affiliation":[{"name":"Department of Chemistry, CICECO, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"given":"Sandra","family":"Gago","sequence":"additional","affiliation":[{"name":"Department of Chemistry, CICECO, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"given":"Isabel  S.","family":"Gon\u00e7alves","sequence":"additional","affiliation":[{"name":"Department of Chemistry, CICECO, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"given":"Martyn","family":"Pillinger","sequence":"additional","affiliation":[{"name":"Department of Chemistry, CICECO, University of Aveiro, 3810\u2013193 Aveiro, Portugal"}]},{"given":"Al\u00edrio  E.","family":"Rodrigues","sequence":"additional","affiliation":[{"name":"Laboratory of Separation and Reaction Engineering, Associate Laboratory LSRE\/LCM, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, 4200\u2013465, Porto, Portugal"}]},{"given":"Marta","family":"Abrantes","sequence":"additional","affiliation":[{"name":"Laboratory of Separation and Reaction Engineering, Associate Laboratory LSRE\/LCM, Faculdade de Engenharia da Universidade do Porto, Rua Dr. Roberto Frias, 4200\u2013465, Porto, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2009,9,16]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"569","DOI":"10.1021\/cr00027a002","article-title":"Peroxo and superoxo complexes of chromium, molybdenum, and tungsten","volume":"94","author":"Dickman","year":"1994","journal-title":"Chem. 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