{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,18]],"date-time":"2026-01-18T02:10:43Z","timestamp":1768702243679,"version":"3.49.0"},"reference-count":38,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2016,10,12]],"date-time":"2016-10-12T00:00:00Z","timestamp":1476230400000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["POCI-01-0145-FEDER-007679\u00a0(FCT Ref. UID\/CTM\/50011\/2013)"],"award-info":[{"award-number":["POCI-01-0145-FEDER-007679\u00a0(FCT Ref. UID\/CTM\/50011\/2013)"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["FCT UID\/QUI\/00062\/2013"],"award-info":[{"award-number":["FCT UID\/QUI\/00062\/2013"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["FCT UID\/QUI\/0100\/2013"],"award-info":[{"award-number":["FCT UID\/QUI\/0100\/2013"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["FCOMP-01-0124-FEDER-041282 (Ref. FCT EXPL\/CTM-NAN\/0013\/2013)"],"award-info":[{"award-number":["FCOMP-01-0124-FEDER-041282 (Ref. FCT EXPL\/CTM-NAN\/0013\/2013)"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"Funda\u00e7\u00e3o para a Ci\u00eancia e a Tecnologia","doi-asserted-by":"publisher","award":["SFRH\/BD\/86303\/2012"],"award-info":[{"award-number":["SFRH\/BD\/86303\/2012"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>Porphyrin-based Metal-Organic Frameworks (Por-MOFs) constitute a special branch of the wide MOF family that has proven its own value and high potential in different applications. In this mini-review the application of these materials as catalysts in oxidation reactions is highlighted.<\/jats:p>","DOI":"10.3390\/molecules21101348","type":"journal-article","created":{"date-parts":[[2016,10,12]],"date-time":"2016-10-12T10:18:49Z","timestamp":1476267529000},"page":"1348","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":92,"title":["Porphyrin-Based Metal-Organic Frameworks as Heterogeneous Catalysts in Oxidation Reactions"],"prefix":"10.3390","volume":"21","author":[{"given":"Carla","family":"Pereira","sequence":"first","affiliation":[{"name":"Department of Chemistry & CICECO\u2013Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"},{"name":"Department of Chemistry & QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9071-2252","authenticated-orcid":false,"given":"M\u00e1rio","family":"Sim\u00f5es","sequence":"additional","affiliation":[{"name":"Department of Chemistry & QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"given":"Jo\u00e3o","family":"Tom\u00e9","sequence":"additional","affiliation":[{"name":"Department of Chemistry & QOPNA, University of Aveiro, 3810-193 Aveiro, Portugal"},{"name":"CQE, Instituto Superior T\u00e9cnico, Universidade de Lisboa, Av. Rovisco Pais, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2051-5645","authenticated-orcid":false,"given":"Filipe","family":"Almeida Paz","sequence":"additional","affiliation":[{"name":"Department of Chemistry & CICECO\u2013Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2016,10,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"1546","DOI":"10.1021\/ja00160a038","article-title":"Design and construction of a new class of scaffolding-like materials comprising infinite polymeric frameworks of 3-D-linked molecular rods. A reappraisal of the Zn(CN)2 and Cd(CN)2 structures and the synthesis and structure of the diamond-related frameworks [N(CH3)4] [CuIZnII(CN)4] and CuI[4,4\u2032,4\u2032\u2032,4\u2032\u2032\u2032-tetracyanotetraphenylmethane]BF4.xC6H5NO2","volume":"112","author":"Hoskins","year":"1990","journal-title":"J. Am. Chem. Soc."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"703","DOI":"10.1038\/378703a0","article-title":"Selective binding and removal of guests in a microporous metal-organic framework","volume":"378","author":"Yaghi","year":"1995","journal-title":"Nature"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"734","DOI":"10.1021\/cr3002824","article-title":"Metal-organic frameworks and self-assembled supramolecular coordination complexes: Comparing and contrasting the design, synthesis, and functionality of metal-organic materials","volume":"113","author":"Cook","year":"2013","journal-title":"Chem. Rev."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"727","DOI":"10.1038\/369727a0","article-title":"Assembly of porphyrin building-blocks into network structures with large channels","volume":"369","author":"Abrahams","year":"1994","journal-title":"Nature"},{"key":"ref_5","doi-asserted-by":"crossref","unstructured":"Kadish, K.M., Smith, K.M., and Guilard, R. (2010\u20132014). Handbook of Porphyrin Science, World Scientific Publisher.","DOI":"10.1142\/8560-vol34"},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"3947","DOI":"10.1021\/cr020443g","article-title":"Mechanism of oxidation reactions catalyzed by cytochrome P-450 enzymes","volume":"104","author":"Meunier","year":"2004","journal-title":"Chem. Rev."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"949","DOI":"10.1021\/cr900121s","article-title":"P-450 Enzymes: Their structure, reactivity, and selectivity-modeled by QM\/MM calculations","volume":"110","author":"Shaik","year":"2010","journal-title":"Chem. Rev."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"737","DOI":"10.1351\/pac199466040737","article-title":"Cytochromes P-450 and model systems: Great diversity of catalyzed reactions","volume":"66","author":"Mansuy","year":"1994","journal-title":"Pure Appl. Chem."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"3569","DOI":"10.1073\/pnas.0830019100","article-title":"The bioinorganic chemistry of iron in oxygenases and supramolecular assemblies","volume":"100","author":"Groves","year":"2003","journal-title":"Proc. Natl. Acad. Sci. USA"},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"392","DOI":"10.1016\/j.crci.2006.11.001","article-title":"A brief history of the contribution of metalloporphyrin models to cytochrome P-450 chemistry and oxidation catalysis","volume":"10","author":"Mansuy","year":"2007","journal-title":"C. R. Chim."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"48","DOI":"10.3390\/molecules17010048","article-title":"Influence of halogen substituents on the catalytic oxidation of 2,4,6-halogenated phenols by Fe(III)-tetrakis(p-hydroxyphenyl) porphyrins and potassium monopersulfate","volume":"17","author":"Fukushima","year":"2012","journal-title":"Molecules"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"884","DOI":"10.1126\/science.234.4778.884.a","article-title":"Cytochrome P-450 - structure, mechanism, and biochemistry","volume":"234","author":"White","year":"1986","journal-title":"Science"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"386","DOI":"10.1021\/bm060829r","article-title":"Role of humic acid fraction with higher aromaticity in enhancing the activity of a biomimetic catalyst, tetra(p-sulfonatophenyl)porphineiron(III)","volume":"8","author":"Fukushima","year":"2007","journal-title":"Biomacromolecules"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"89","DOI":"10.1038\/nchem.1855","article-title":"Enzymatic C-H bond activation using push to get pull","volume":"6","author":"Groves","year":"2014","journal-title":"Nat. Chem."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"129","DOI":"10.1016\/0010-8545(93)85013-T","article-title":"Activation of alkanes - the biomimetic approach","volume":"125","author":"Mansuy","year":"1993","journal-title":"Coord. Chem. Rev."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"31","DOI":"10.1039\/a827031z","article-title":"Nonplanar porphyrins and their significance in proteins","volume":"27","author":"Shelnutt","year":"1998","journal-title":"Chem. Soc. Rev."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"1400","DOI":"10.1039\/b807086p","article-title":"Design and synthesis of metal-organic frameworks using metal-organic polyhedra as supermolecular building blocks","volume":"38","author":"Perry","year":"2009","journal-title":"Chem. Soc. Rev."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"3879","DOI":"10.1039\/c2dt11989g","article-title":"Functional porphyrinic metal-organic frameworks: Crystal engineering and applications","volume":"41","author":"Zou","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"5841","DOI":"10.1039\/C4CS00001C","article-title":"Metal-metalloporphyrin frameworks: A resurging class of functional materials","volume":"43","author":"Gao","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"14574","DOI":"10.1039\/C5DT02170G","article-title":"Recent developments in metal-metalloporphyrin frameworks","volume":"44","author":"Guo","year":"2015","journal-title":"Dalton Trans."},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"345","DOI":"10.1039\/C5CE02106E","article-title":"Porphyrinic metal-organic frameworks from custom-designed porphyrins","volume":"18","author":"Huh","year":"2016","journal-title":"Cryst. Eng. Comm."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"3606","DOI":"10.1021\/ja00009a065","article-title":"A new type of infinite 3D Polymeric network containing 4-connected, peripherally linked metalloporphyrin building-blocks","volume":"113","author":"Abrahams","year":"1991","journal-title":"J. Am. Chem. Soc."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"283","DOI":"10.1021\/ar040173j","article-title":"Microporous porphyrin solids","volume":"38","author":"Suslick","year":"2005","journal-title":"Acc. Chem. Res."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"5652","DOI":"10.1021\/ja111042f","article-title":"Active-site-accessible, porphyrinic metal-organic framework materials","volume":"133","author":"Farha","year":"2011","journal-title":"J. Am. Chem. Soc."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"28","DOI":"10.1016\/j.cej.2014.07.045","article-title":"Selective oxidation over a metalloporphyrinic metal-organic framework catalyst and insights into the mechanism of bicarbonate ion as co-catalyst","volume":"257","author":"Zhang","year":"2014","journal-title":"Chem. Eng. J."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"10638","DOI":"10.1021\/ja303728c","article-title":"Porous metalloporphyrinic frameworks constructed from metal 5,10,15,20-tetrakis(3,5-biscarboxylphenyl)porphyrin for highly efficient and selective catalytic oxidation of alkylbenzenes","volume":"134","author":"Yang","year":"2012","journal-title":"J. Am. Chem. Soc."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"1087","DOI":"10.1007\/s10562-016-1729-2","article-title":"Mn-III(porphyrin)-based porous coordination polymers: Synthesis, catalytic activities for the oxidation of ethylbenzene","volume":"146","author":"Sun","year":"2016","journal-title":"Catal. Lett."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"5521","DOI":"10.1039\/C1CC10461F","article-title":"A metalloporphyrin functionalized metal-organic framework for selective oxidization of styrene","volume":"47","author":"Xie","year":"2011","journal-title":"Chem. Comm."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"10082","DOI":"10.1002\/anie.201205603","article-title":"Crystal engineering of a microporous, catalytically active fcu topology mof using a custom-designed metalloporphyrin linker","volume":"51","author":"Meng","year":"2012","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"3297","DOI":"10.1002\/chem.201204358","article-title":"Formation of a metalloporphyrin-based nanoreactor by postsynthetic metalion exchange of a polyhedral-cage containing a metalmetalloporphyrin framework","volume":"19","author":"Wang","year":"2013","journal-title":"Chem. Eur. J."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"3620","DOI":"10.1021\/ic3019502","article-title":"Four metalloporphyrinic frameworks as heterogeneous catalysts for selective oxidation and aldol reaction","volume":"52","author":"Zou","year":"2013","journal-title":"Inorg. Chem."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"14316","DOI":"10.1002\/chem.201302025","article-title":"Highly efficient C-H oxidative activation by a porous Mn-III-porphyrin metal-organic framework under mild conditions","volume":"19","author":"Xie","year":"2013","journal-title":"Chem. Eur. J."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"589","DOI":"10.1007\/s10562-014-1433-z","article-title":"An Efficient catalyst based on a metal metalloporphyrinic framework for highly selective oxidation","volume":"145","author":"Zhang","year":"2015","journal-title":"Catal. Lett."},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"166","DOI":"10.1016\/j.molcata.2014.05.023","article-title":"Synthesis of porphyrin@MOFs type catalysts through \u201cone-pot\u201d self-assembly","volume":"393","author":"Li","year":"2014","journal-title":"J. Mol. Catal. A Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"12600","DOI":"10.1021\/ic301923x","article-title":"Biomimetic catalysis of a porous iron-based metal-metalloporphyrin framework","volume":"51","author":"Chen","year":"2012","journal-title":"Inorg. Chem."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"10307","DOI":"10.1002\/anie.201204475","article-title":"Zirconium-metalloporphyrin PCN-222: Mesoporous metal-organic frameworks with ultrahigh stability as biomimetic catalysts","volume":"51","author":"Feng","year":"2012","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"251","DOI":"10.1021\/ar960126u","article-title":"Polyhaloporphyrins: Unusual ligands for metals and metal-catalyzed oxidations","volume":"30","author":"Dolphin","year":"1997","journal-title":"Acc. Chem. Res."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"16322","DOI":"10.1021\/ja204339e","article-title":"Three-dimensional porous metal-metalloporphyrin framework consisting of nanoscopic polyhedral cages","volume":"133","author":"Wang","year":"2011","journal-title":"J. Am. Chem. Soc."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/21\/10\/1348\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T19:32:48Z","timestamp":1760211168000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/21\/10\/1348"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2016,10,12]]},"references-count":38,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2016,10]]}},"alternative-id":["molecules21101348"],"URL":"https:\/\/doi.org\/10.3390\/molecules21101348","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2016,10,12]]}}}