{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,1,15]],"date-time":"2026-01-15T13:53:42Z","timestamp":1768485222794,"version":"3.49.0"},"reference-count":49,"publisher":"MDPI AG","issue":"10","license":[{"start":{"date-parts":[[2018,10,10]],"date-time":"2018-10-10T00:00:00Z","timestamp":1539129600000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100003593","name":"Conselho Nacional de Desenvolvimento Cient\u00edfico e Tecnol\u00f3gico","doi-asserted-by":"publisher","award":["Ed. Universal 400791\/2016-1"],"award-info":[{"award-number":["Ed. 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The compounds were prepared from different disulfides employing NaBH4 as a reducing agent. The methodology allowed the preparation of four different thioaryl-porphyrins in very-good to excellent yields under soft conditions, such as short reaction times and smooth heating. Additionally, the photophysical properties of new compounds were determined and experimental and theoretical DNA interactions were assessed.<\/jats:p>","DOI":"10.3390\/molecules23102588","type":"journal-article","created":{"date-parts":[[2018,10,10]],"date-time":"2018-10-10T11:53:13Z","timestamp":1539172393000},"page":"2588","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":19,"title":["A New Protocol for the Synthesis of New Thioaryl-Porphyrins Derived from 5,10,15,20-Tetrakis(pentafluorophenyl)porphyrin: Photophysical Evaluation and DNA-Binding Interactive Studies"],"prefix":"10.3390","volume":"23","author":[{"given":"Patr\u00edcia","family":"Foletto","sequence":"first","affiliation":[{"name":"Departamento de Qu\u00edmica, Universidade Federal de Santa Maria, Santa Maria-RS 97105-900, Brazil"}]},{"given":"Fabiula","family":"Correa","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica, Universidade Federal de Santa Maria, Santa Maria-RS 97105-900, Brazil"}]},{"given":"Luciano","family":"Dornelles","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica, Universidade Federal de Santa Maria, Santa Maria-RS 97105-900, Brazil"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4039-6316","authenticated-orcid":false,"given":"Bernardo","family":"A. Iglesias","sequence":"additional","affiliation":[{"name":"Laborat\u00f3rio de Bioinorg\u00e2nica e Materiais Porfir\u00ednicos, Departamento de Qu\u00edmica, Universidade Federal de Santa Maria\u2013UFSM, Santa Maria\u2013RS 97105-900, Brazil"}]},{"given":"Carolina","family":"H. da Silveira","sequence":"additional","affiliation":[{"name":"Laborat\u00f3rio de Bioinorg\u00e2nica e Materiais Porfir\u00ednicos, Departamento de Qu\u00edmica, Universidade Federal de Santa Maria\u2013UFSM, Santa Maria\u2013RS 97105-900, Brazil"}]},{"given":"Pablo","family":"A. Nogara","sequence":"additional","affiliation":[{"name":"Laborat\u00f3rio de Bioqu\u00edmica Toxicol\u00f3gica, Departamento de Bioqu\u00edmica e Biologia Molecular, Univerisidade Federal de Santa Maria, Santa Maria\u2013RS 97105-900, Brazil"}]},{"given":"Jo\u00e3o B.","family":"T. da Rocha","sequence":"additional","affiliation":[{"name":"Laborat\u00f3rio de Bioqu\u00edmica Toxicol\u00f3gica, Departamento de Bioqu\u00edmica e Biologia Molecular, Univerisidade Federal de Santa Maria, Santa Maria\u2013RS 97105-900, Brazil"}]},{"given":"Maria A.","family":"F. Faustino","sequence":"additional","affiliation":[{"name":"QOPNA and Department of Chemistry, University of Aveiro, Aveiro 3810-193, Portugal"}]},{"given":"Oscar E.","family":"D. Rodrigues","sequence":"additional","affiliation":[{"name":"Departamento de Qu\u00edmica, Universidade Federal de Santa Maria, Santa Maria-RS 97105-900, Brazil"}]}],"member":"1968","published-online":{"date-parts":[[2018,10,10]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"156","DOI":"10.1016\/j.bmcl.2016.11.094","article-title":"Photodynamic effect of meso-(aryl)porphyrins and meso-(1-methyl-4-pyridinium)porphyrins on HaCaT keratinocytes","volume":"27","author":"Slomp","year":"2017","journal-title":"Bioorg. Med. Chem. Lett."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"2737","DOI":"10.1002\/adma.200601850","article-title":"Nonlinear optical properties of porphyrins","volume":"19","author":"Senge","year":"2007","journal-title":"Adv. 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