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Mesoporous silica materials with different particle size, surface area and pore volume were prepared and tailored with different functional groups. These materials were then characterised by solid-state techniques, namely vibrational spectroscopy, elemental analysis, scanning electron microscopy and nitrogen adsorption\u2013desorption isotherms, allowing the successful preparation and structural modifications of the materials to be confirmed. The influence of the physicochemical properties of the adsorbents towards the removal of metal ions (Ni2+, Cu2+ and Fe3+) and organic dyes (methylene blue and methyl green) from aqueous solutions was also investigated. The results reveal that the exceptionally high surface area and suitable \u03b6-potential of the nanosized mesoporous silica nanoparticles (MSNPs) seem to favour the adsorptive capacity of the material for both types of water pollutants. Kinetic studies were performed for the adsorption of organic dyes by MSNPs and large-pore mesoporous silica (LPMS), suggesting that the process follows a pseudo-second-order model. The recyclability along consecutive adsorption cycles and the stability of the adsorbents after use were also investigated, showing that the material can be reused. Current results show the potentialities of novel silica-based material as a suitable adsorbent to remove pollutants from aquatic matrices with an applicability to reduce water pollution.<\/jats:p>","DOI":"10.3390\/molecules28104038","type":"journal-article","created":{"date-parts":[[2023,5,12]],"date-time":"2023-05-12T01:30:29Z","timestamp":1683855029000},"page":"4038","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":28,"title":["Tailoring of Mesoporous Silica-Based Materials for Enhanced Water Pollutants Removal"],"prefix":"10.3390","volume":"28","author":[{"given":"Daniela","family":"Flores","sequence":"first","affiliation":[{"name":"LAQV-REQUIMTE, Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias, Universidade do Porto, Rua do Campo Alegre, s\/n, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6836-0331","authenticated-orcid":false,"given":"C. Marisa R.","family":"Almeida","sequence":"additional","affiliation":[{"name":"Centro Interdisciplinar de Investiga\u00e7\u00e3o Marinha e Ambiental (CIIMAR), Universidade do Porto, Terminal de Cruzeiros do Porto de Leix\u00f5es, Av. General Norton de Matos s\/n, 4450-208 Matosinhos, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-3708-9366","authenticated-orcid":false,"given":"Carlos R.","family":"Gomes","sequence":"additional","affiliation":[{"name":"Centro Interdisciplinar de Investiga\u00e7\u00e3o Marinha e Ambiental (CIIMAR), Universidade do Porto, Terminal de Cruzeiros do Porto de Leix\u00f5es, Av. General Norton de Matos s\/n, 4450-208 Matosinhos, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8984-0473","authenticated-orcid":false,"given":"Salete S.","family":"Balula","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias, Universidade do Porto, Rua do Campo Alegre, s\/n, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0986-6607","authenticated-orcid":false,"given":"Carlos M.","family":"Granadeiro","sequence":"additional","affiliation":[{"name":"LAQV-REQUIMTE, Departamento de Qu\u00edmica e Bioqu\u00edmica, Faculdade de Ci\u00eancias, Universidade do Porto, Rua do Campo Alegre, s\/n, 4169-007 Porto, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2023,5,11]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"7245","DOI":"10.1039\/C5CE01428J","article-title":"Metal\u2013organic frameworks for applications in remediation of oxyanion\/cation-contaminated water","volume":"17","author":"Howarth","year":"2015","journal-title":"CrystEngComm"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"139903","DOI":"10.1016\/j.scitotenv.2020.139903","article-title":"Nanoadsorbents for water and wastewater remediation","volume":"739","year":"2020","journal-title":"Sci. Total Environ."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"17","DOI":"10.1016\/j.ccr.2018.03.015","article-title":"Recent advances about metal\u2013organic frameworks in the removal of pollutants from wastewater","volume":"378","author":"Gao","year":"2019","journal-title":"Coord. Chem. Rev."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"4667","DOI":"10.1038\/s41467-021-25026-3","article-title":"Bryan, Future global urban water scarcity and potential solutions","volume":"12","author":"He","year":"2021","journal-title":"Nat. Commun."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"213180","DOI":"10.1016\/j.ccr.2020.213180","article-title":"Nanocatalysts and other nanomaterials for water remediation from organic pollutants","volume":"408","author":"Lu","year":"2020","journal-title":"Coord. Chem. Rev."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"15292","DOI":"10.1039\/C5TA03201F","article-title":"Functionalized metal\u2013organic framework as a new platform for efficient and selective removal of cadmium(ii) from aqueous solution","volume":"3","author":"Wang","year":"2015","journal-title":"J. Mater. Chem. A"},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"2322","DOI":"10.1039\/C7CS00543A","article-title":"Metal\u2013organic framework-based materials: Superior adsorbents for the capture of toxic and radioactive metal ions","volume":"47","author":"Li","year":"2018","journal-title":"Chem. Soc. Rev."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"213096","DOI":"10.1016\/j.ccr.2019.213096","article-title":"Insight on water remediation application using magnetic nanomaterials and biosorbents","volume":"403","author":"Maksoud","year":"2020","journal-title":"Coord. Chem. Rev."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"126050","DOI":"10.1016\/j.colsurfa.2020.126050","article-title":"Highly efficient and rapid adsorption of methylene blue dye onto vinyl hybrid silica nano-cross-linked nanocomposite hydrogel","volume":"613","author":"Chen","year":"2021","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"13096","DOI":"10.1039\/C8TA02560F","article-title":"An efficient hybrid adsorbent based on silica-supported amino penta-carboxylic acid for water purification","volume":"6","author":"Radi","year":"2018","journal-title":"J. Mater. Chem. A"},{"key":"ref_11","doi-asserted-by":"crossref","unstructured":"Guerra, F.D., Attia, M.F., Whitehead, D.C., and Alexis, F. (2018). Nanotechnology for Environmental Remediation: Materials and Applications. Molecules, 23.","DOI":"10.3390\/molecules23071760"},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"783","DOI":"10.1016\/j.chemosphere.2018.06.114","article-title":"Water-stable metal-organic frameworks for aqueous removal of heavy metals and radionuclides: A review","volume":"209","author":"Feng","year":"2018","journal-title":"Chemosphere"},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"7433","DOI":"10.1039\/c3ta10639j","article-title":"Mechanically strong graphene oxide\/sodium alginate\/polyacrylamide nanocomposite hydrogel with improved dye adsorption capacity","volume":"1","author":"Fan","year":"2013","journal-title":"J. Mater. Chem. A"},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"783","DOI":"10.1016\/j.jclepro.2019.05.154","article-title":"Review on heavy metal adsorption processes by carbon nanotubes","volume":"230","author":"Fiyadh","year":"2019","journal-title":"J. Clean. Prod."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"5251","DOI":"10.1021\/acs.cgd.0c00437","article-title":"Highly Efficient and Facile Removal of Pb2+ from Water by Using a Negatively Charged Azoxy-Functionalized Metal\u2013Organic Framework","volume":"20","author":"Yu","year":"2020","journal-title":"Cryst. Growth Des."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"19577","DOI":"10.1039\/D2NJ03419K","article-title":"Recent advances in Al(iii)\/In(iii)-based MOFs for the detection of pollutants","volume":"46","author":"Li","year":"2022","journal-title":"New J. Chem."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"103514","DOI":"10.1016\/j.mtcomm.2022.103514","article-title":"Metal organic frameworks as efficient adsorbents for drugs from wastewater","volume":"31","author":"Zheng","year":"2022","journal-title":"Mater. Today Commun."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"133857","DOI":"10.1016\/j.cej.2021.133857","article-title":"Cobalt-seamed C-methylpyrogallol[4]arene nanocapsules-derived magnetic carbon cubes as advanced adsorbent toward drug contaminant removal","volume":"433","author":"Pan","year":"2022","journal-title":"Chem. Eng. J."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"18016","DOI":"10.1039\/D1DT03020E","article-title":"A new magnetic adsorbent of eggshell-zeolitic imidazolate framework for highly efficient removal of norfloxacin","volume":"50","author":"Zhong","year":"2021","journal-title":"Dalton Trans."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"4912","DOI":"10.1039\/C8TA00264A","article-title":"Metal\u2013organic framework technologies for water remediation: Towards a sustainable ecosystem","volume":"6","author":"Mon","year":"2018","journal-title":"J. Mater. Chem. A"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"8466","DOI":"10.1021\/ja1025744","article-title":"Multifunctional Mesoporous Composite Microspheres with Well-Designed Nanostructure: A Highly Integrated Catalyst System","volume":"132","author":"Deng","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"163","DOI":"10.1016\/j.micromeso.2018.07.036","article-title":"Mesoporous nanosilica-supported polyoxomolybdate as catalysts for sustainable desulfurization","volume":"275","author":"Mirante","year":"2019","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"4478","DOI":"10.1039\/b924316j","article-title":"Mesoporous organosilica adsorbents: Nanoengineered materials for removal of organic and inorganic pollutants","volume":"20","author":"Walcarius","year":"2010","journal-title":"J. Mater. Chem."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"2013","DOI":"10.1039\/b818740a","article-title":"Novel mesoporous silica spheres with ultra-large pore sizes and their application in protein separation","volume":"19","author":"Chen","year":"2009","journal-title":"J. Mater. Chem."},{"key":"ref_25","doi-asserted-by":"crossref","unstructured":"Cecilia, J.A., Tost, R.M., and Mill\u00e1n, M.R. (2019). Mesoporous Materials: From Synthesis to Applications. Int. J. Mol. Sci., 20.","DOI":"10.3390\/ijms20133213"},{"key":"ref_26","doi-asserted-by":"crossref","unstructured":"Ruiz-Ca\u00f1as, M.C., Corredor, L.M., Quintero, H.I., Manrique, E., and Boh\u00f3rquez, A.R. (2020). Morphological and Structural Properties of Amino-Functionalized Fumed Nanosilica and Its Comparison with Nanoparticles Obtained by Modified St\u00f6ber Method. Molecules, 25.","DOI":"10.3390\/molecules25122868"},{"key":"ref_27","doi-asserted-by":"crossref","unstructured":"Wieszczycka, K., Filipowiak, K., Dudzinska, P., Nowicki, M., Siwi\u0144ska-Ciesielczyk, K., and Jesionowski, T. (2022). Novel Mesoporous Organosilicas with Task Ionic Liquids: Properties and High Adsorption Performance for Pb(II). Molecules, 27.","DOI":"10.3390\/molecules27041405"},{"key":"ref_28","doi-asserted-by":"crossref","unstructured":"Putz, A.-M., Ciopec, M., Negrea, A., Grad, O., Ian\u0103\u015fi, C., Ivankov, O.I., Milanovi\u0107, M., Stijepovi\u0107, I., and Alm\u00e1sy, L. (2021). Comparison of Structure and Adsorption Properties of Mesoporous Silica Functionalized with Aminopropyl Groups by the Co-Condensation and the Post Grafting Methods. Materials, 14.","DOI":"10.3390\/ma14030628"},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"145","DOI":"10.1016\/j.micromeso.2017.03.050","article-title":"Adsorption of heavy metals on functionalized-mesoporous silica: A review","volume":"247","year":"2017","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"455","DOI":"10.1016\/j.seppur.2016.10.048","article-title":"Preparation of amidoxime functionalized SBA-15 with platelet shape and adsorption property of U(VI)","volume":"174","author":"Ji","year":"2017","journal-title":"Sep. Purif. Technol."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"65","DOI":"10.1007\/s13762-015-0841-y","article-title":"Adsorption of Pb(II) and Cu(II) metal ions on functionalized large-pore mesoporous silica","volume":"13","author":"Lee","year":"2016","journal-title":"Int. J. Environ. Sci. Technol."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"2278","DOI":"10.1080\/09593330.2021.1871662","article-title":"Spherical mesoporous silica designed for the removal of methylene blue from water under strong acidic conditions","volume":"43","author":"Effting","year":"2022","journal-title":"Environ. Technol."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"116213","DOI":"10.1016\/j.fuel.2019.116213","article-title":"Large-pore silica spheres as support for samarium-coordinated undecamolybdophosphate: Oxidative desulfurization of diesels","volume":"259","author":"Mirante","year":"2020","journal-title":"Fuel"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"9518","DOI":"10.1039\/C3DT53444H","article-title":"Novel polyoxometalate silica nano-sized spheres: Efficient catalysts for olefin oxidation and the deep desulfurization process","volume":"43","author":"Nogueira","year":"2014","journal-title":"Dalton Trans."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"10898","DOI":"10.1021\/jp803915g","article-title":"Lanthanide (Eu3+, Tb3+) Centered Hybrid Materials using Modified Functional Bridge Chemical Bonded with Silica: Molecular Design, Physical Characterization, and Photophysical Properties","volume":"112","author":"Liu","year":"2008","journal-title":"J. Phys. Chem. B"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"388","DOI":"10.1016\/j.apsusc.2015.01.107","article-title":"Progress of porous silicon APTES-functionalization by FTIR investigations","volume":"331","author":"Majoul","year":"2015","journal-title":"Appl. Surf. Sci."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"685","DOI":"10.1177\/0144598717716281","article-title":"Surface functionalization of silica nanoparticles to improve the performance of water flooding in oil wet reservoirs","volume":"35","author":"Azarshin","year":"2017","journal-title":"Energy Explor. Exploit."},{"key":"ref_38","doi-asserted-by":"crossref","unstructured":"Ribeiro, S.O., Duarte, B., De Castro, B., Granadeiro, C.M., and Balula, S.S. (2018). Improving the Catalytic Performance of Keggin [PW12O40]3\u2212 for Oxidative Desulfurization: Ionic Liquids versus SBA-15 Composite. Materials, 11.","DOI":"10.3390\/ma11071196"},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"5220","DOI":"10.1039\/c0jm00588f","article-title":"Highly efficient visible light sensitized red emission from europium tris[1-(4-biphenoyl)-3-(2-fluoroyl)propanedione](1,10-phenanthroline) complex grafted on silica nanoparticles","volume":"20","author":"Divya","year":"2010","journal-title":"J. Mater. Chem."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"4243","DOI":"10.1021\/acs.chemmater.6b00877","article-title":"Size-Controlled Functionalized Mesoporous Silica Nanoparticles for Tunable Drug Release and Enhanced Anti-Tumoral Activity","volume":"28","author":"Bouchoucha","year":"2016","journal-title":"Chem. Mater."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"838","DOI":"10.1016\/j.jhazmat.2007.07.092","article-title":"A study on removal characteristics of copper from aqueous solution by sewage sludge and pomace ashes","volume":"152","author":"Bouzid","year":"2008","journal-title":"J. Hazard. Mater."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"105995","DOI":"10.1016\/j.ijthermalsci.2019.105995","article-title":"Design and thermal insulation performance analysis of endothermic opacifiers doped silica aerogels","volume":"145","author":"Zhu","year":"2019","journal-title":"Int. J. Therm. Sci."},{"key":"ref_43","doi-asserted-by":"crossref","first-page":"49787","DOI":"10.1039\/C7RA09834K","article-title":"Functionalization of silica particles to tune the impact resistance of shear thickening fluid treated aramid fabrics","volume":"7","author":"Talreja","year":"2017","journal-title":"RSC Adv."},{"key":"ref_44","doi-asserted-by":"crossref","unstructured":"Bondarenko, L., Ill\u00e9s, E., Tomb\u00e1cz, E., Dzhardimalieva, G., Golubeva, N., Tushavina, O., Adachi, Y., and Kydralieva, K. (2021). Fabrication, Microstructure and Colloidal Stability of Humic Acids Loaded Fe3O4\/APTES Nanosorbents for Environmental Applications. Nanomaterials, 11.","DOI":"10.3390\/nano11061418"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"1201","DOI":"10.1016\/j.scitotenv.2018.08.210","article-title":"Bioadsorptive removal of Pb(II) from aqueous solution by the biorefinery waste of Fucus spiralis","volume":"648","author":"Filote","year":"2019","journal-title":"Sci. Total Environ."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"1824","DOI":"10.1021\/acs.cgd.5b00950","article-title":"Continuous Precipitation of Nickel Hydroxide by Addition of Ammonium Ions","volume":"16","author":"Funakoshi","year":"2016","journal-title":"Cryst. Growth Des."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"49","DOI":"10.1016\/j.jhazmat.2010.08.114","article-title":"Biosorption of heavy metals from aqueous solutions by chemically modified orange peel","volume":"185","author":"Feng","year":"2011","journal-title":"J. Hazard. Mater."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"121029","DOI":"10.1016\/j.jssc.2019.121029","article-title":"Removal of fluoroquinolone drug, levofloxacin, from aqueous phase over iron based MOFs, MIL-100(Fe)","volume":"281","author":"Chaturvedi","year":"2020","journal-title":"J. Solid State Chem."},{"key":"ref_49","doi-asserted-by":"crossref","first-page":"585","DOI":"10.1016\/j.protcy.2016.05.127","article-title":"A study on Effects of pH, Adsorbent Dosage, Time, Initial Concentration and Adsorption Isotherm Study for the Removal of Hexavalent Chromium (Cr (VI)) from Wastewater by Magnetite Nanoparticles","volume":"24","author":"Padmavathy","year":"2016","journal-title":"Procedia Technol."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"113248","DOI":"10.1016\/j.envres.2022.113248","article-title":"Adsorption of pollutants in wastewater via biosorbents, nanoparticles and magnetic biosorbents: A review","volume":"212","author":"Tee","year":"2022","journal-title":"Environ. Res."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"100116","DOI":"10.1016\/j.crgsc.2021.100116","article-title":"Synthesis of mesoporous silica nanoparticles derived from rice husk and surface-controlled amine functionalization for efficient adsorption of methylene blue from aqueous solution","volume":"4","author":"Usgodaarachchi","year":"2021","journal-title":"Curr. Res. Green Sustain. Chem."},{"key":"ref_52","doi-asserted-by":"crossref","first-page":"681","DOI":"10.1016\/j.jhazmat.2005.12.043","article-title":"Review of second-order models for adsorption systems","volume":"136","author":"Ho","year":"2006","journal-title":"J. Hazard. Mater."},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"110","DOI":"10.1016\/j.jcis.2018.03.057","article-title":"Enhanced Cr(VI) removal by polyethylenimine- and phosphorus-codoped hierarchical porous carbons","volume":"523","author":"Chen","year":"2018","journal-title":"J. Colloid Interface Sci."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"172","DOI":"10.1016\/j.cis.2014.04.002","article-title":"Dye and its removal from aqueous solution by adsorption: A review","volume":"209","author":"Yagub","year":"2014","journal-title":"Adv. Colloid Interface Sci."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"43599","DOI":"10.1038\/srep43599","article-title":"Superior Adsorption and Regenerable Dye Adsorbent Based on Flower-Like Molybdenum Disulfide Nanostructure","volume":"7","author":"Han","year":"2017","journal-title":"Sci. Rep."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1186\/2193-8865-3-55","article-title":"Pseudo-second-order kinetic equations for modeling adsorption systems for removal of lead ions using multi-walled carbon nanotube","volume":"3","author":"Robati","year":"2013","journal-title":"J. Nanostructure Chem."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"143","DOI":"10.1016\/j.dyepig.2006.05.039","article-title":"Adsorption of basic dye (methylene blue) onto activated carbon prepared from rattan sawdust","volume":"75","author":"Hameed","year":"2007","journal-title":"Dye. Pigment."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"37976","DOI":"10.1039\/C8RA06287K","article-title":"K6P2W18O62 encapsulated into magnetic Fe3O4\/MIL-101 (Cr) metal\u2013organic framework: A novel magnetically recoverable nanoporous adsorbent for ultrafast treatment of aqueous organic pollutants solutions","volume":"8","author":"Jarrah","year":"2018","journal-title":"RSC Adv."},{"key":"ref_59","doi-asserted-by":"crossref","first-page":"8753","DOI":"10.1021\/acs.langmuir.1c01046","article-title":"Fabrication of a Nanoporous Silica Hydrogel by Cross-Linking of SiO2\u2013H3BO3\u2013Hexadecyltrimethoxysilane for Excellent Adsorption of Azo Dyes from Wastewater","volume":"37","author":"Lahiri","year":"2021","journal-title":"Langmuir"},{"key":"ref_60","doi-asserted-by":"crossref","unstructured":"Almethen, A.A., Alotaibi, K.M., Alhumud, H.S., and Alswieleh, A.M. (2022). Highly Efficient and Rapid Removal of Methylene Blue from Aqueous Solution Using Folic Acid-Conjugated Dendritic Mesoporous Silica Nanoparticles. Processes, 10.","DOI":"10.3390\/pr10040705"},{"key":"ref_61","doi-asserted-by":"crossref","unstructured":"Qin, P., Yang, Y., Zhang, X., Niu, J., Yang, H., Tian, S., Zhu, J., and Lu, M. (2018). Highly Efficient, Rapid, and Simultaneous Removal of Cationic Dyes from Aqueous Solution Using Monodispersed Mesoporous Silica Nanoparticles as the Adsorbent. Nanomaterials, 8.","DOI":"10.3390\/nano8010004"},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"121514","DOI":"10.1016\/j.jhazmat.2019.121514","article-title":"Synthesis of new imine-linked covalent organic framework as high efficient absorbent and monitoring the removal of direct fast scarlet 4BS textile dye based on mobile phone colorimetric platform","volume":"385","author":"Afshari","year":"2020","journal-title":"J. Hazard. Mater."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"122430","DOI":"10.1016\/j.polymer.2020.122430","article-title":"Synthesis and characterization of a novel fluorene-based covalent triazine framework as a chemical adsorbent for highly efficient dye removal","volume":"195","author":"Mokhtari","year":"2020","journal-title":"Polymer"},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"125425","DOI":"10.1016\/j.colsurfa.2020.125425","article-title":"Efficient adsorption of methylene blue by mesoporous silica prepared using sol-gel method employing hydroxyethyl cellulose as a template","volume":"606","author":"Lyu","year":"2020","journal-title":"Colloids Surf. A Physicochem. Eng. Asp."},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"43","DOI":"10.1016\/j.jhazmat.2008.01.031","article-title":"Removal of methylene blue from aqueous solution with silica nano-sheets derived from vermiculite","volume":"158","author":"Zhao","year":"2008","journal-title":"J. Hazard. Mater."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"75","DOI":"10.1007\/s10450-019-00176-5","article-title":"Adsorption of anionic and cationic dyes into shaped MCM-41","volume":"26","author":"Rios","year":"2020","journal-title":"Adsorption"},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"985","DOI":"10.1039\/C4NJ01473A","article-title":"Fabrication of mesoporous Al-SBA-15 as a methylene blue capturer via a spontaneous infiltration route","volume":"39","author":"Wu","year":"2015","journal-title":"New J. Chem."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"21","DOI":"10.1016\/j.micromeso.2006.08.005","article-title":"Structure directed reversible adsorption of organic dye on mesoporous silica in aqueous solution","volume":"97","author":"Wang","year":"2006","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"e03253","DOI":"10.1016\/j.heliyon.2020.e03253","article-title":"Adsorption of the methyl green dye pollutant from aqueous solution using mesoporous materials MCM-41 in a fixed-bed column","volume":"6","author":"Alardhi","year":"2020","journal-title":"Heliyon"},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"5919","DOI":"10.1080\/03067319.2020.1804895","article-title":"Simultaneous removal of crystal violet and methyl green in water samples by functionalised SBA-15","volume":"102","author":"Rofouei","year":"2022","journal-title":"Int. J. Environ. Anal. Chem."}],"container-title":["Molecules"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/10\/4038\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,10]],"date-time":"2025-10-10T19:33:15Z","timestamp":1760124795000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/1420-3049\/28\/10\/4038"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2023,5,11]]},"references-count":70,"journal-issue":{"issue":"10","published-online":{"date-parts":[[2023,5]]}},"alternative-id":["molecules28104038"],"URL":"https:\/\/doi.org\/10.3390\/molecules28104038","relation":{},"ISSN":["1420-3049"],"issn-type":[{"value":"1420-3049","type":"electronic"}],"subject":[],"published":{"date-parts":[[2023,5,11]]}}}