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Tunisia","award":["CEECIND\/02322\/2020"],"award-info":[{"award-number":["CEECIND\/02322\/2020"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Molecules"],"abstract":"<jats:p>The continuous search for novel biobased polymers with high-performance properties has highlighted the role of monofuranic-based polyesters as some of the most promising for future plastic industry but has neglected the huge potential for the polymers\u2019 innovation, relatively low cost, and synthesis easiness of 5,5\u2032-isopropylidene bis-(ethyl 2-furoate) (DEbF), obtained from the platform chemical, worldwide-produced furfural. In this vein, poly(1,12-dodecylene 5,5\u2032-isopropylidene -bis(ethyl 2-furoate)) (PDDbF) was introduced, for the first time, as a biobased bisfuranic long-chain aliphatic polyester with an extreme flexibility function, competing with fossil-based polyethylene. This new polyester in-depth characterization confirmed its expected structure (FTIR, 1H, and 13C NMR) and relevant thermal features (DSC, TGA, and DMTA), notably, an essentially amorphous character with a glass transition temperature of \u22126 \u00b0C and main maximum decomposition temperature of 340 \u00b0C. Furthermore, PDDbF displayed an elongation at break as high as 732%, around five times higher than that of the 2,5-furandicarboxylic acid counterpart, stressing the unique features of the bisfuranic class of polymers compared to monofuranic ones. The enhanced ductility combined with the relevant thermal properties makes PDDbF a highly promising material for flexible packaging.<\/jats:p>","DOI":"10.3390\/molecules28104124","type":"journal-article","created":{"date-parts":[[2023,5,17]],"date-time":"2023-05-17T01:58:06Z","timestamp":1684288686000},"page":"4124","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":9,"title":["Highly Flexible Poly(1,12-dodecylene 5,5\u2032-isopropylidene-bis(ethyl 2-furoate)): A Promising Biobased Polyester Derived from a Renewable Cost-Effective Bisfuranic Precursor and a Long-Chain Aliphatic Spacer"],"prefix":"10.3390","volume":"28","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-3100-7777","authenticated-orcid":false,"given":"Sami","family":"Zaidi","sequence":"first","affiliation":[{"name":"CICECO\u2013Aveiro Institute of Materials and Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal"},{"name":"Faculty des Sciences, Laboratory de Chimie Appliqu\u00e9e HCGP, Universit\u00e9 de Sfax, Sfax 3038, Tunisia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4574-3786","authenticated-orcid":false,"given":"Abdelkader","family":"Bougarech","sequence":"additional","affiliation":[{"name":"Faculty des Sciences, Laboratory de Chimie Appliqu\u00e9e HCGP, Universit\u00e9 de Sfax, Sfax 3038, Tunisia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0456-0876","authenticated-orcid":false,"given":"Majdi","family":"Abid","sequence":"additional","affiliation":[{"name":"Chemistry Department, College of Science and Arts in Al-Qurayyat, Jouf University, Al-Qurayyat P.O. Box 756, Al Jouf, Saudi Arabia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8646-7696","authenticated-orcid":false,"given":"Souhir","family":"Abid","sequence":"additional","affiliation":[{"name":"Faculty des Sciences, Laboratory de Chimie Appliqu\u00e9e HCGP, Universit\u00e9 de Sfax, Sfax 3038, Tunisia"},{"name":"Chemistry Department, College of Science and Arts in Al-Qurayyat, Jouf University, Al-Qurayyat P.O. Box 756, Al Jouf, Saudi Arabia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5403-8416","authenticated-orcid":false,"given":"Armando J. 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