{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,5,11]],"date-time":"2026-05-11T18:44:28Z","timestamp":1778525068722,"version":"3.51.4"},"reference-count":48,"publisher":"MDPI AG","issue":"4","license":[{"start":{"date-parts":[[2020,4,21]],"date-time":"2020-04-21T00:00:00Z","timestamp":1587427200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/100009409","name":"Russian Science Support Foundation","doi-asserted-by":"publisher","award":["project #18-19-00307"],"award-info":[{"award-number":["project #18-19-00307"]}],"id":[{"id":"10.13039\/100009409","id-type":"DOI","asserted-by":"publisher"}]},{"DOI":"10.13039\/501100001871","name":"FCT","doi-asserted-by":"publisher","award":["project UID\/FIS\/04564\/2019"],"award-info":[{"award-number":["project UID\/FIS\/04564\/2019"]}],"id":[{"id":"10.13039\/501100001871","id-type":"DOI","asserted-by":"publisher"}]},{"name":"Russian academic excellence project \u201c5-100\u201d","award":["for Sechenov University"],"award-info":[{"award-number":["for Sechenov University"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>Evolution of the crystal structure of ceramics BiFeO3\u2013BaTiO3 across the morphotropic phase boundary was analyzed using the results of macroscopic measuring techniques such as X-ray diffraction, differential scanning calorimetry, and differential thermal analysis, as well as the data obtained by local scale methods of scanning probe microscopy. The obtained results allowed to specify the concentration and temperature regions of the single phase and phase coexistent regions as well as to clarify a modification of the structural parameters across the rhombohedral\u2013cubic phase boundary. The structural data show unexpected strengthening of structural distortion specific for the rhombohedral phase, which occurs upon dopant concentration and temperature-driven phase transitions to the cubic phase. The obtained results point to the non-monotonous character of the phase evolution, which is specific for metastable phases. The compounds with metastable structural state are characterized by enhanced sensitivity to external stimuli, which significantly expands the perspectives of their particular use.<\/jats:p>","DOI":"10.3390\/nano10040801","type":"journal-article","created":{"date-parts":[[2020,4,22]],"date-time":"2020-04-22T04:15:13Z","timestamp":1587528913000},"page":"801","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":80,"title":["Peculiarities of the Crystal Structure Evolution of BiFeO3\u2013BaTiO3 Ceramics across Structural Phase Transitions"],"prefix":"10.3390","volume":"10","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1046-543X","authenticated-orcid":false,"given":"Dmitry V.","family":"Karpinsky","sequence":"first","affiliation":[{"name":"Institute of Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, 124498 Moscow, Russia"},{"name":"Laboratory of Technology and Physics of Crystals Growth, Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Scientific and Educational Center \u201cNanotechnology\u201d, South Ural State University, 454080 Chelyabinsk, Russia"}]},{"given":"Maxim V.","family":"Silibin","sequence":"additional","affiliation":[{"name":"Institute of Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, 124498 Moscow, Russia"},{"name":"Laboratory of Technology and Physics of Crystals Growth, Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Institute for Bionic Technologies and Engineering, I.M. Sechenov First Moscow State Medical University, 119991 Moscow, Russia"},{"name":"Scientific-Manufacturing Complex \u201cTechnological Centre\u201d Shokin Square, House 1, Bld. 7, Zelenograd, 124498 Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2294-4371","authenticated-orcid":false,"given":"Sergei V.","family":"Trukhanov","sequence":"additional","affiliation":[{"name":"Laboratory of Technology and Physics of Crystals Growth, Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Scientific and Educational Center \u201cNanotechnology\u201d, South Ural State University, 454080 Chelyabinsk, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3430-9578","authenticated-orcid":false,"given":"Alex V.","family":"Trukhanov","sequence":"additional","affiliation":[{"name":"Laboratory of Technology and Physics of Crystals Growth, Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Scientific and Educational Center \u201cNanotechnology\u201d, South Ural State University, 454080 Chelyabinsk, Russia"}]},{"given":"Alexander L.","family":"Zhaludkevich","sequence":"additional","affiliation":[{"name":"Laboratory of Technology and Physics of Crystals Growth, Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"}]},{"given":"Siarhei I.","family":"Latushka","sequence":"additional","affiliation":[{"name":"Laboratory of Technology and Physics of Crystals Growth, Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"}]},{"given":"Dmitry V.","family":"Zhaludkevich","sequence":"additional","affiliation":[{"name":"Laboratory of Technology and Physics of Crystals Growth, Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-5867-3297","authenticated-orcid":false,"given":"Vladimir A.","family":"Khomchenko","sequence":"additional","affiliation":[{"name":"Center for Physics of the University of Coimbra, Department of Physics, University of Coimbra, 3004-516 Coimbra, Portugal"}]},{"given":"Denis O.","family":"Alikin","sequence":"additional","affiliation":[{"name":"School of Natural Sciences and Mathematics, Ural Federal University, 620026 Ekaterinburg, Russia"}]},{"given":"Alexander S.","family":"Abramov","sequence":"additional","affiliation":[{"name":"School of Natural Sciences and Mathematics, Ural Federal University, 620026 Ekaterinburg, Russia"}]},{"given":"Tomasz","family":"Maniecki","sequence":"additional","affiliation":[{"name":"Institute of General and Ecological Chemistry, Lodz University of Technology, 90-924 Lodz, Poland"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6094-0748","authenticated-orcid":false,"given":"Waldemar","family":"Maniukiewicz","sequence":"additional","affiliation":[{"name":"Institute of General and Ecological Chemistry, Lodz University of Technology, 90-924 Lodz, Poland"}]},{"given":"Martin","family":"Wolff","sequence":"additional","affiliation":[{"name":"Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Zentrum f\u00fcr Material- und K\u00fcstenforschung GmbH, DE-21502 Geesthacht, Germany"}]},{"given":"Volker","family":"Heitmann","sequence":"additional","affiliation":[{"name":"Institute of Materials Research, Helmholtz-Zentrum Geesthacht, Zentrum f\u00fcr Material- und K\u00fcstenforschung GmbH, DE-21502 Geesthacht, Germany"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3432-7610","authenticated-orcid":false,"given":"Andrei L.","family":"Kholkin","sequence":"additional","affiliation":[{"name":"School of Natural Sciences and Mathematics, Ural Federal University, 620026 Ekaterinburg, Russia"},{"name":"Department of Physics &amp; CICECO\u2014Aveiro Institute of Materials, University of Aveiro, 3810-193 Aveiro, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2020,4,21]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"2237","DOI":"10.1021\/jz300688b","article-title":"Multiferroic and magnetoelectric oxides: The emerging scenario","volume":"3","author":"Rao","year":"2012","journal-title":"J. Phys. Chem. Lett."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"6694","DOI":"10.1021\/jp000114x","article-title":"Why are there so few magnetic ferroelectrics?","volume":"104","author":"Hill","year":"2000","journal-title":"J. Phys. Chem. B"},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"203","DOI":"10.1038\/s41563-018-0275-2","article-title":"Advances in magnetoelectric multiferroics","volume":"18","author":"Spaldin","year":"2019","journal-title":"Nat. Mater."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"253","DOI":"10.1016\/j.jmmm.2015.05.076","article-title":"Crystal structure and magnetic properties of the BaFe12\u2212xAlxO19 (x = 0.1\u20131.2) solid solutions","volume":"393","author":"Trukhanov","year":"2015","journal-title":"J. Magn. Magn. Mater."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"247","DOI":"10.1016\/j.jallcom.2018.04.150","article-title":"Control of electromagnetic properties in substituted M-type hexagonal ferrites","volume":"754","author":"Trukhanov","year":"2018","journal-title":"J. Alloy Compd."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"290","DOI":"10.1016\/j.ceramint.2017.09.172","article-title":"Polarization origin and iron positions in indium doped barium hexaferrites","volume":"44","author":"Trukhanov","year":"2018","journal-title":"Ceram. Int."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"5345","DOI":"10.1007\/s10853-017-0776-4","article-title":"Magnetic anisotropy of the graphite nanoplatelet\u2013epoxy and MWCNT\u2013epoxy composites with aligned barium ferrite filler","volume":"52","author":"Yakovenko","year":"2017","journal-title":"J. Mater. Sci."},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"21295","DOI":"10.1016\/j.ceramint.2018.08.180","article-title":"Preparation and investigation of structure, magnetic and dielectric properties of (BaFe11.9Al0.1O19)1-x\u2014(BaTiO3)x bicomponent ceramics","volume":"44","author":"Trukhanov","year":"2018","journal-title":"Ceram. Int."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"107054","DOI":"10.1016\/j.compositesb.2019.107054","article-title":"Structural, electric and magnetic properties of (BaFe11.9Al0.1O19)1-x\u2013(BaTiO3)x composites","volume":"174","author":"Salem","year":"2019","journal-title":"Compos. Part B Eng."},{"key":"ref_10","doi-asserted-by":"crossref","unstructured":"Almessiere, M.A., Slimani, Y., G\u00fcng\u00fcne, H., Baykal, A., Trukhanov, S.V., and Trukhanov, A.V. (2019). Manganese\/Yttrium codoped strontium nanohexaferrites: Evaluation of magnetic susceptibility and M\u00f6ssbauer spectra. Nanomaterials, 9.","DOI":"10.3390\/nano9010024"},{"key":"ref_11","doi-asserted-by":"crossref","unstructured":"Almessiere, M.A., Trukhanov, A.V., Slimani, Y., You, K.Y., Trukhanov, S.V., Trukhanova, E.L., Esa, F., Sadaqat, A., Chaudhary, K., and Zdorovets, M. (2019). Correlation between composition and electrodynamics properties in nanocomposites based on hard\/soft ferrimagnetics with strong exchange coupling. Nanomaterials, 9.","DOI":"10.3390\/nano9020202"},{"key":"ref_12","doi-asserted-by":"crossref","unstructured":"Dukenbayev, K., Korolkov, I.V., Tishkevich, D.I., Kozlovskiy, A.L., Trukhanov, S.V., Gorin, Y.G., Shumskaya, E.E., Kaniukov, E.Y., Vinnik, D.A., and Zdorovets, M.V. (2019). Fe3O4 nanoparticles for complex targeted delivery and boron neutron capture therapy. Nanomaterials, 9.","DOI":"10.3390\/nano9040494"},{"key":"ref_13","doi-asserted-by":"crossref","unstructured":"Matzui, L.Y., Trukhanov, A.V., Yakovenko, O.S., Vovchenko, L.L., Zagorodnii, V.V., Oliynyk, V.V., Borovoy, M.O., Trukhanova, E.L., Astapovich, K.A., and Karpinsky, D.V. (2019). Functional magnetic composites based on hexaferrites: Correlation of the composition, magnetic and high-frequency properties. Nanomaterials, 9.","DOI":"10.3390\/nano9121720"},{"key":"ref_14","doi-asserted-by":"crossref","unstructured":"Darwish, M.A., Trukhanov, A.V., Senatov, O.S., Morchenko, A.T., Saafan, S.A., Astapovich, K.A., Trukhanov, S.V., Trukhanova, E.L., Pilyushkin, A.A., and Sombra, A.S.B. (2020). Investigation of AC-measurements of epoxy\/ferrite composites. Nanomaterials, 10.","DOI":"10.3390\/nano10030492"},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"3692","DOI":"10.1002\/adma.200800218","article-title":"The ferroic phase transitions of BiFeO3","volume":"20","author":"Selbach","year":"2008","journal-title":"Adv. Mater."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"2463","DOI":"10.1002\/adma.200802849","article-title":"Physics and applications of bismuth ferrite","volume":"21","author":"Catalan","year":"2009","journal-title":"Adv. Mater."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"2019","DOI":"10.1088\/0022-3727\/39\/10\/006","article-title":"Electrical and magnetic properties of single-phased and highly resistive ferroelectromagnet BiFeO3 ceramic","volume":"39","author":"Wang","year":"2006","journal-title":"J. Phys. D Appl. Phys."},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"164","DOI":"10.1016\/j.jpcs.2018.11.006","article-title":"A correlation between crystal structure and magnetic properties in co-doped BiFeO3 ceramics","volume":"126","author":"Karpinsky","year":"2019","journal-title":"J. Phys. Chem. Solids"},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"1830004","DOI":"10.1142\/S2010135X18300049","article-title":"BiFeO3-BaTiO3: A new generation of lead-free electroceramics","volume":"8","author":"Wang","year":"2018","journal-title":"J. Adv. Dielect."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"134115","DOI":"10.1103\/PhysRevB.97.134115","article-title":"Rotomagnetic coupling in fine-grained multiferroic BiFeO3: Theory and experiment","volume":"97","author":"Morozovska","year":"2018","journal-title":"Phys. Rev. B"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"3623","DOI":"10.1039\/C7TC00833C","article-title":"Magnetostructural correlations in BiFeO3-based multiferroics","volume":"5","author":"Khomchenko","year":"2017","journal-title":"J. Mater. Chem. C"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1038\/s41524-017-0021-3","article-title":"Thermodynamic potential and phase diagram for multiferroic bismuth ferrite (BiFeO3)","volume":"3","author":"Karpinsky","year":"2017","journal-title":"NPJ Comput. Mater."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"573","DOI":"10.1557\/adv.2016.155","article-title":"Crystallographic features in the vicinity of the morphotropic phase boundary in the multiferroic material Bi1\u2212xSmxFeO3","volume":"1","author":"Nomoto","year":"2016","journal-title":"MRS Adv."},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"27","DOI":"10.1021\/nl502471a","article-title":"Multiferroic grain boundaries in oxygen-deficient ferroelectric lead titanate","volume":"15","author":"Shimada","year":"2015","journal-title":"Nano Lett."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1038\/s41598-019-46834-0","article-title":"Ferromagnetic-like behavior of Bi0.9La0.1FeO3\u2013KBr nanocomposites","volume":"9","author":"Karpinsky","year":"2019","journal-title":"Sci. Rep."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"330","DOI":"10.1016\/j.jallcom.2019.01.363","article-title":"Effect of nickel content on structural, morphological and magnetic properties of NixCo1\u2212xFe2O4\/SiO2 nanocomposites","volume":"786","author":"Dippong","year":"2019","journal-title":"J. Alloys Compd."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"62","DOI":"10.1109\/TUFFC.2014.006668","article-title":"Composition-driven structural phase transitions in rare-earth-doped BiFeO3 ceramics: A review","volume":"62","author":"Arnold","year":"2015","journal-title":"IEEE Trans. Ultrason. Ferroelectr. Freq. Control."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"2631","DOI":"10.1111\/jace.12978","article-title":"Temperature and composition-induced structural transitions in Bi1\u2212xLa(Pr)xFeO3 ceramics","volume":"97","author":"Karpinsky","year":"2014","journal-title":"J. Am. Ceram. Soc."},{"key":"ref_29","doi-asserted-by":"crossref","first-page":"958","DOI":"10.1007\/s40195-015-0279-8","article-title":"Structural, dielectric, and magnetic properties of Ba-doped multiferroic bismuth ferrite","volume":"28","author":"Mahbub","year":"2015","journal-title":"Acta Metall. Sin."},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"054109","DOI":"10.1103\/PhysRevB.83.054109","article-title":"Isothermal structural transitions, magnetization and large piezoelectric response in Bi1-xLaxFeO3 perovskites","volume":"83","author":"Troyanchuk","year":"2011","journal-title":"Phys. Rev. B"},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"062906","DOI":"10.1063\/1.3479479","article-title":"A morphotropic phase boundary system based on polarization rotation and polarization extension","volume":"97","author":"Damjanovic","year":"2010","journal-title":"Appl. Phys. Lett."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"106","DOI":"10.1016\/j.matchemphys.2015.05.017","article-title":"Synthesis of nano-structured Bi1\u2212xBaxFeO3 ceramics with enhanced magnetic and electrical properties","volume":"162","author":"Mostafavi","year":"2015","journal-title":"Mater. Chem. Phys."},{"key":"ref_33","doi-asserted-by":"crossref","first-page":"375","DOI":"10.1140\/epjb\/e2010-00004-y","article-title":"Structural and magnetic phases of Bi1\u2212xAxFeO3\u2212\u03b4 (A = Sr, Pb) perovskites","volume":"73","author":"Troyanchuk","year":"2010","journal-title":"Eur. Phys. J. B"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"1750169","DOI":"10.1142\/S021798491750169X","article-title":"The synthesis of Ba2+-doped multiferroic BiFeO3 nanoparticles using co-precipitation method in the presence of various surfactants and the investigation of structural and magnetic features","volume":"31","author":"Mardani","year":"2017","journal-title":"Mod. Phys. Lett. B"},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"135902","DOI":"10.1088\/0953-8984\/25\/13\/135902","article-title":"Composition- and temperature-driven structural transitions in Bi1-xCaxFeO3 multiferroics: A neutron diffraction study","volume":"25","author":"Khomchenko","year":"2013","journal-title":"J. Phys. Condens. Matter"},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"392","DOI":"10.1016\/j.jallcom.2015.12.241","article-title":"Bi1-xCaxFeO3-\u03b4 (0\u2264x\u22641) ceramics: Crystal structure, phase and elemental composition, and chemical bonding from X-ray diffraction, Raman scattering, M\u00f6ssbauer, and X-ray photoelectron spectra","volume":"664","author":"Kozakov","year":"2016","journal-title":"J. Alloys Compd."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"164105","DOI":"10.1063\/1.4999375","article-title":"Structural and electrical characteristics of potential candidate lead-free BiFeO3-BaTiO3 piezoelectric ceramics","volume":"122","author":"Kim","year":"2017","journal-title":"J. Appl. Phys."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"1136","DOI":"10.1016\/j.jallcom.2019.06.145","article-title":"Evolution of crystal structure of Ba and Ti co-doped BiFeO3 ceramics at the morphotropic phase boundary","volume":"803","author":"Karpinsky","year":"2019","journal-title":"J. Alloys Compd."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"154632","DOI":"10.1016\/j.jallcom.2020.154632","article-title":"Nanoscale ferroelectricity in pseudo-cubic sol-gel derived barium titanate\u2014Bismuth ferrite (BaTiO3\u2013BiFeO3) solid solutions","volume":"830","author":"Lukowiak","year":"2020","journal-title":"J. Alloys Compd."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"024113","DOI":"10.1103\/PhysRevB.88.024113","article-title":"Evidence for local monoclinic structure, polarization rotation, and morphotropic phase transitions in (1-x)BiFeO3\u2013(x)BaTiO3 solid solutions: A high-energy synchrotron x-ray powder diffraction study","volume":"88","author":"Singh","year":"2013","journal-title":"Phys. Rev. B"},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"054406","DOI":"10.1103\/PhysRevB.83.054406","article-title":"Neutron powder diffraction study of nuclear and magnetic structures of multiferroic Bi0.8Ba0.2Fe0.8Ti0.2O3: Evidence for isostructural phase transition and magnetoelastic and magnetoelectric couplings","volume":"83","author":"Singh","year":"2011","journal-title":"Phys. Rev. B"},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"2957","DOI":"10.1111\/j.1551-2916.2009.03313.x","article-title":"Dielectric and piezoelectric properties in Mn-modified (1\u2212x)BiFeO3\u2013xBaTiO3 ceramics","volume":"92","author":"Leontsev","year":"2009","journal-title":"J. Am. Ceram. Soc."},{"key":"ref_43","doi-asserted-by":"crossref","unstructured":"Lallart, M. (2011). Effects of doping and oxygen nonstoichiometry on the thermodynamic properties of some multiferroic ceramics. Ferroelectrics\u2013Physical Effects, Intech Open 10.","DOI":"10.5772\/942"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"55","DOI":"10.1016\/0921-4526(93)90108-I","article-title":"Recent advances in magnetic structure determination by neutron powder diffraction","volume":"192","year":"1993","journal-title":"Phys. B"},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"425707","DOI":"10.1088\/0957-4484\/27\/42\/425707","article-title":"Quantification of surface displacements and electromechanical phenomena via dynamic atomic force microscopy","volume":"27","author":"Balke","year":"2016","journal-title":"Nanotechnology"},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"6","DOI":"10.1186\/2251-7235-6-6","article-title":"Williamson-Hall analysis in estimation of lattice strain in nanometer-sized ZnO particles","volume":"6","author":"Mote","year":"2012","journal-title":"J. Theor. Appl. Phys."},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.matlet.2018.10.006","article-title":"Weak ferromagnetic state in the polar phase of Bi1-xCaxFe1-x\/2Nbx\/2O3 multiferroics","volume":"235","author":"Khomchenko","year":"2019","journal-title":"Mater. Lett."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"46","DOI":"10.1016\/j.scriptamat.2019.08.001","article-title":"Competition for impurity atoms between defects and solid solution during high pressure torsion","volume":"173","author":"Mazilkin","year":"2019","journal-title":"Scripta Mater."}],"container-title":["Nanomaterials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2079-4991\/10\/4\/801\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,13]],"date-time":"2025-10-13T13:45:07Z","timestamp":1760363107000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2079-4991\/10\/4\/801"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2020,4,21]]},"references-count":48,"journal-issue":{"issue":"4","published-online":{"date-parts":[[2020,4]]}},"alternative-id":["nano10040801"],"URL":"https:\/\/doi.org\/10.3390\/nano10040801","relation":{},"ISSN":["2079-4991"],"issn-type":[{"value":"2079-4991","type":"electronic"}],"subject":[],"published":{"date-parts":[[2020,4,21]]}}}