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This, thereby, provides a route to more environmentally friendly energy storage and generation systems. Carbon-supported trimetallic catalysts were herein prepared by three different routes: using a NaBH4-ethylene glycol complex (PdAuNi\/CSBEG), a NaBH4-2-propanol complex (PdAuNi\/CSBIPA), and a three-step route (PdAuNi\/C3-step). Notably, PdAuNi\/CSBIPA yielded highly dispersed trimetallic alloy particles, as determined by XRD, EDX, ICP-OES, XPS, and TEM. The activity of the catalysts for borohydride oxidation reaction was assessed by cyclic voltammetry and RDE-based procedures, with results referenced to a Pd\/C catalyst. A number of exchanged electrons close to eight was obtained for PdAuNi\/C3-step and PdAuNi\/CSBIPA (7.4 and 7.1, respectively), while the others, PdAuNi\/CSBEG and Pd\/CSBIPA, presented lower values, 2.8 and 1.2, respectively. A direct borohydride-peroxide fuel cell employing PdAuNi\/CSBIPA catalyst in the anode attained a power density of 47.5 mW cm\u22122 at room temperature, while the elevation of temperature to 75 \u00b0C led to an approximately four-fold increase in power density to 175 mW cm\u22122. Trimetallic catalysts prepared via this synthesis route have significant potential for future development.<\/jats:p>","DOI":"10.3390\/nano11061441","type":"journal-article","created":{"date-parts":[[2021,5,31]],"date-time":"2021-05-31T01:51:37Z","timestamp":1622425897000},"page":"1441","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":13,"title":["Carbon-Supported Trimetallic Catalysts (PdAuNi\/C) for Borohydride Oxidation Reaction"],"prefix":"10.3390","volume":"11","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-7062-9117","authenticated-orcid":false,"given":"Ahmed","family":"ElSheikh","sequence":"first","affiliation":[{"name":"Mechanical Engineering Department, South Valley University, AlShobaan AlMoslemeen Street, Qena 83521, Egypt"},{"name":"Department of Chemical and Biological Engineering, University of Sheffield, Sheffield S1 3JD, UK"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4259-7477","authenticated-orcid":false,"given":"Gordana","family":"Backovi\u0107","sequence":"additional","affiliation":[{"name":"Center of Physics and Engineering of Advanced Materials (CeFEMA), Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8060-0668","authenticated-orcid":false,"given":"Raisa","family":"Oliveira","sequence":"additional","affiliation":[{"name":"Center of Physics and Engineering of Advanced Materials (CeFEMA), Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-7556-2858","authenticated-orcid":false,"given":"C\u00e9sar","family":"Sequeira","sequence":"additional","affiliation":[{"name":"Center of Physics and Engineering of Advanced Materials (CeFEMA), Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-6813-306X","authenticated-orcid":false,"given":"James","family":"McGregor","sequence":"additional","affiliation":[{"name":"Department of Chemical and Biological Engineering, University of Sheffield, Sheffield S1 3JD, UK"}]},{"given":"Biljana","family":"\u0160ljuki\u0107","sequence":"additional","affiliation":[{"name":"Center of Physics and Engineering of Advanced Materials (CeFEMA), Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-7920-2638","authenticated-orcid":false,"given":"Diogo","family":"Santos","sequence":"additional","affiliation":[{"name":"Center of Physics and Engineering of Advanced Materials (CeFEMA), Instituto Superior T\u00e9cnico, Universidade de Lisboa, 1049-001 Lisboa, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2021,5,29]]},"reference":[{"key":"ref_1","unstructured":"Larminie, J., and Dicks, A. 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