{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,4,1]],"date-time":"2026-04-01T12:47:31Z","timestamp":1775047651254,"version":"3.50.1"},"reference-count":25,"publisher":"MDPI AG","issue":"9","license":[{"start":{"date-parts":[[2022,5,5]],"date-time":"2022-05-05T00:00:00Z","timestamp":1651708800000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"name":"Russian Federation","award":["075-15-2021-1350"],"award-info":[{"award-number":["075-15-2021-1350"]}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>The crystal structure and magnetic state of the (1 \u2212 x)BiFeO3-(x)BiMnO3 solid solution has been analyzed by X-ray diffraction using lab-based and synchrotron radiation facilities, magnetization measurements, differential thermal analysis, and differential scanning calorimetry. Dopant concentration increases lead to the room-temperature structural transitions from the polar-active rhombohedral phase to the antipolar orthorhombic phase, and then to the monoclinic phase accompanied by the formation of two-phase regions consisting of the adjacent structural phases in the concentration ranges 0.25 &lt; x1 &lt; 0.30 and 0.50 \u2264 x2 &lt; 0.65, respectively. The accompanied changes in the magnetic structure refer to the magnetic transitions from the modulated antiferromagnetic structure to the non-colinear antiferromagnetic structure, and then to the orbitally ordered ferromagnetic structure. The compounds with a two-phase structural state at room temperature are characterized by irreversible temperature-driven structural transitions, which favor the stabilization of high-temperature structural phases. The magnetic structure of the compounds also exhibits an irreversible temperature-induced transition, resulting in an increase of the contribution from the magnetic phase associated with the high-temperature structural phase. The relationship between the structural parameters and the magnetic state of the compounds with a metastable structure is studied and discussed depending on the chemical composition and heating prehistory.<\/jats:p>","DOI":"10.3390\/nano12091565","type":"journal-article","created":{"date-parts":[[2022,5,6]],"date-time":"2022-05-06T02:46:39Z","timestamp":1651805199000},"page":"1565","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":10,"title":["Structural and Magnetic Phase Transitions in BiFe1 \u2212 xMnxO3 Solid Solution Driven by Temperature"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1046-543X","authenticated-orcid":false,"given":"Dmitry V.","family":"Karpinsky","sequence":"first","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Institute of Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, Zelenograd, 124498 Moscow, Russia"}]},{"given":"Maxim V.","family":"Silibin","sequence":"additional","affiliation":[{"name":"Institute of Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, Zelenograd, 124498 Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0008-0525","authenticated-orcid":false,"given":"Siarhei I.","family":"Latushka","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Institute of Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, Zelenograd, 124498 Moscow, Russia"}]},{"given":"Dmitry V.","family":"Zhaludkevich","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Institute of Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, Zelenograd, 124498 Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5252-6870","authenticated-orcid":false,"given":"Vadim V.","family":"Sikolenko","sequence":"additional","affiliation":[{"name":"Institute of Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, Zelenograd, 124498 Moscow, Russia"},{"name":"Frank Laboratory of Neutron Physics, Joint Institute for Nuclear Research, 141980 Dubna, Russia"},{"name":"Division Technical Petrophysics, Institute of Applied Geosciences, Karlsruhe Institute of Technology, 76131 Karlsruhe, Germany"}]},{"given":"Hanan","family":"Al-Ghamdi","sequence":"additional","affiliation":[{"name":"Department of Physics, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia"}]},{"given":"Aljawhara H.","family":"Almuqrin","sequence":"additional","affiliation":[{"name":"Department of Physics, College of Science, Princess Nourah Bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3040-8878","authenticated-orcid":false,"given":"M. I.","family":"Sayyed","sequence":"additional","affiliation":[{"name":"Department of Physics, Faculty of Science, Isra University, Amman 11622, Jordan"},{"name":"Department of Nuclear Medicine Research, Institute for Research and Medical Consultations (IRMC), Imam Abdulrahman Bin Faisal University (IAU), Dammam 31441, Saudi Arabia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9031-2355","authenticated-orcid":false,"given":"Alexei A.","family":"Belik","sequence":"additional","affiliation":[{"name":"International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba, Ibaraki 305-0044, Japan"}]}],"member":"1968","published-online":{"date-parts":[[2022,5,5]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"060401","DOI":"10.1103\/PhysRevB.71.060401","article-title":"Weak ferromagnetism and magnetoelectric coupling in bismuth ferrite","volume":"71","author":"Ederer","year":"2005","journal-title":"Phys. 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