{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,2,28]],"date-time":"2026-02-28T21:16:23Z","timestamp":1772313383384,"version":"3.50.1"},"reference-count":40,"publisher":"MDPI AG","issue":"16","license":[{"start":{"date-parts":[[2022,8,16]],"date-time":"2022-08-16T00:00:00Z","timestamp":1660608000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"funder":[{"DOI":"10.13039\/501100006769","name":"RSF","doi-asserted-by":"publisher","award":["21-19-00386"],"award-info":[{"award-number":["21-19-00386"]}],"id":[{"id":"10.13039\/501100006769","id-type":"DOI","asserted-by":"publisher"}]}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>The compound BiFe0.7Mn0.3O3 consisting at room temperature of coexistent anti-polar orthorhombic and polar rhombohedral phases has a metastable structural state, which has been studied by laboratory X-ray, synchrotron and neutron diffraction, magnetometry, differential thermal analysis, and differential scanning calorimetry. Thermal annealing of the sample at temperatures above the temperature-driven phase transition into the single phase rhombohedral structure (~700 K) causes an increase of the volume fraction of the rhombohedral phase at room temperature from ~10% up to ~30%, which is accompanied by the modification of the magnetic state, leading to strengthening of a ferromagnetic component. A strong external magnetic field (~5 T) applied to the sample notably changes its magnetic properties, as well as provides a reinforcement of the ferromagnetic component, thus leading to an interaction between two magnetic subsystems formed by the antiferromagnetic matrix with non-collinear alignment of magnetic moments and the nanoscale ferromagnetic clusters coexisting within it. The modification of the structural state and magnetic properties of the compounds and a correlation between different structural and magnetic phases are discussed focusing on the effect of thermal annealing and the impact of an external magnetic field.<\/jats:p>","DOI":"10.3390\/nano12162813","type":"journal-article","created":{"date-parts":[[2022,8,17]],"date-time":"2022-08-17T03:15:27Z","timestamp":1660706127000},"page":"2813","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":38,"title":["Temperature-Driven Transformation of the Crystal and Magnetic Structures of BiFe0.7Mn0.3O3 Ceramics"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1046-543X","authenticated-orcid":false,"given":"Dmitry V.","family":"Karpinsky","sequence":"first","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Institute for Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, 124498 Zelenograd, Moscow, Russia"}]},{"given":"Maxim V.","family":"Silibin","sequence":"additional","affiliation":[{"name":"Institute for Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, 124498 Zelenograd, Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0008-0525","authenticated-orcid":false,"given":"Siarhei I.","family":"Latushka","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Institute for Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, 124498 Zelenograd, Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9748-3939","authenticated-orcid":false,"given":"Dmitry V.","family":"Zhaludkevich","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Institute for Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, 124498 Zelenograd, Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5252-6870","authenticated-orcid":false,"given":"Vadim V.","family":"Sikolenko","sequence":"additional","affiliation":[{"name":"Institute for Advanced Materials and Technologies, National Research University of Electronic Technology \u201cMIET\u201d, 124498 Zelenograd, Moscow, Russia"},{"name":"Joint Institute for Nuclear Research, 141980 Dubna, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-0360-1023","authenticated-orcid":false,"given":"Roman","family":"Svetogorov","sequence":"additional","affiliation":[{"name":"NRC \u201cKurchatov Institute\u201d, Acad. Kurchatov Sq. 1, 123182 Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3040-8878","authenticated-orcid":false,"given":"M. I.","family":"Sayyed","sequence":"additional","affiliation":[{"name":"Department of Physics, Faculty of Science, Isra University, Amman 1162, Jordan"}]},{"given":"Nouf","family":"Almousa","sequence":"additional","affiliation":[{"name":"Department of Physics, College of Science, Princess Nourah bint Abdulrahman University, P.O. Box 84428, Riyadh 11671, Saudi Arabia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3430-9578","authenticated-orcid":false,"given":"Alex","family":"Trukhanov","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"},{"name":"Smart Sensors Laboratory, National University of Science and Technology MISiS, 119049 Moscow, Russia"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-2294-4371","authenticated-orcid":false,"given":"Sergei","family":"Trukhanov","sequence":"additional","affiliation":[{"name":"Scientific-Practical Materials Research Centre of NAS of Belarus, 220072 Minsk, Belarus"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-9031-2355","authenticated-orcid":false,"given":"Alexei \u0410.","family":"Belik","sequence":"additional","affiliation":[{"name":"International Center for Materials Nanoarchitectonics (WPI-MANA), National Institute for Materials Science (NIMS), Namiki 1-1, Tsukuba 305-0044, Ibaraki, Japan"}]}],"member":"1968","published-online":{"date-parts":[[2022,8,16]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"203","DOI":"10.1038\/s41563-018-0275-2","article-title":"Advances in magnetoelectric multiferroics","volume":"18","author":"Spaldin","year":"2019","journal-title":"Nat. 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