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The EuW10@ZIF-8 composite was obtained through an impregnation procedure, and its successful preparation was confirmed by various characterization techniques (FT-IR, XRD, SEM\/EDS, ICP-OES). The catalytic activity of the composite and the isolated EuW10 was evaluated in the desulfurization of a multicomponent model fuel containing dibenzothiophene derivatives (DBT, 4-MDBT and 4,6-DMDBT) with a total sulfur concentration of 1500 ppm. Oxidative desulfurization was performed using an ionic liquid as extraction solvent and aqueous hydrogen peroxide as oxidant. The catalytic results showed a remarkable desulfurization performance, with 99.5 and 94.7% sulfur removal in the first 180 min, for the homogeneous active center EuW10 and the heterogeneous EuW10@ZIF-8 catalysts, respectively. Furthermore, the stability of the nanocomposite catalyst was investigated by reusing and recycling processes. A superior retention of catalyst activity in consecutive desulfurization cycles was observed in the recycling studies when compared with the reusing experiments. Nevertheless, the nanostructure of ZIF-8 incorporating the active POM (polyoxometalate) was shown to be highly suitable for guaranteeing the absence of POM leaching, although structural modification was found for ZIF-8 after catalytic use that did not influenced catalytic performance.<\/jats:p>","DOI":"10.3390\/nano12162887","type":"journal-article","created":{"date-parts":[[2022,8,22]],"date-time":"2022-08-22T21:30:34Z","timestamp":1661203834000},"page":"2887","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":12,"title":["Lindqvist@Nanoporous MOF-Based Catalyst for Effective Desulfurization of Fuels"],"prefix":"10.3390","volume":"12","author":[{"ORCID":"https:\/\/orcid.org\/0000-0003-0684-2287","authenticated-orcid":false,"given":"Simone","family":"Fernandes","sequence":"first","affiliation":[{"name":"LAQV\/REQUIMTE & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"given":"Daniela","family":"Flores","sequence":"additional","affiliation":[{"name":"LAQV\/REQUIMTE & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6431-862X","authenticated-orcid":false,"given":"Daniel","family":"Silva","sequence":"additional","affiliation":[{"name":"LAQV\/REQUIMTE & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-8607-4323","authenticated-orcid":false,"given":"Isabel","family":"Santos-Vieira","sequence":"additional","affiliation":[{"name":"CICECO\u2014Aveiro Institute of Materials, Department of Chemistry, University of Aveiro, 3810-193 Aveiro, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1952-8214","authenticated-orcid":false,"given":"F\u00e1tima","family":"Mirante","sequence":"additional","affiliation":[{"name":"LAQV\/REQUIMTE & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-0986-6607","authenticated-orcid":false,"given":"Carlos M.","family":"Granadeiro","sequence":"additional","affiliation":[{"name":"LAQV\/REQUIMTE & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-8984-0473","authenticated-orcid":false,"given":"Salete S.","family":"Balula","sequence":"additional","affiliation":[{"name":"LAQV\/REQUIMTE & Department of Chemistry and Biochemistry, Faculty of Sciences, University of Porto, 4169-007 Porto, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,8,22]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","unstructured":"Gao, Y., Mirante, F., de Castro, B., Zhao, J., Cunha-Silva, L., and Balula, S.S. (2020). An Effective Hybrid Heterogeneous Catalyst to Desulfurize Diesel: Peroxotungstate@Metal\u2013Organic Framework. Molecules, 25.","DOI":"10.3390\/molecules25235494"},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"13009","DOI":"10.1021\/acs.inorgchem.8b02272","article-title":"Encapsulation of Phosphotungstic Acid into Metal\u2013Organic Frameworks with Tunable Window Sizes: Screening of PTA@MOF Catalysts for Efficient Oxidative Desulfurization","volume":"57","author":"Lin","year":"2018","journal-title":"Inorg. Chem."},{"key":"ref_3","doi-asserted-by":"crossref","first-page":"759","DOI":"10.1039\/C1RA00309G","article-title":"An evaluation of desulfurization technologies for sulfur removal from liquid fuels","volume":"2","author":"Srivastava","year":"2012","journal-title":"RSC Adv."},{"key":"ref_4","doi-asserted-by":"crossref","first-page":"359","DOI":"10.1016\/j.apcata.2017.05.032","article-title":"Desulfurization process conciliating heterogeneous oxidation and liquid extraction: Organic solvent or centrifugation water?","volume":"542","author":"Ribeiro","year":"2017","journal-title":"Appl. Catal. A Gen."},{"key":"ref_5","doi-asserted-by":"crossref","first-page":"366","DOI":"10.1016\/j.apcata.2007.10.024","article-title":"Ultra-deep oxidative desulfurization of diesel fuel by the Mo\/Al2O3-H2O2 system: The effect of system parameters on catalytic","volume":"334","author":"Fuentes","year":"2008","journal-title":"Act. Appl. Catal. A Gen."},{"key":"ref_6","doi-asserted-by":"crossref","first-page":"35071","DOI":"10.1039\/C6RA00996D","article-title":"Extractive and oxidative desulfurization of model oil in polyethylene glycol","volume":"6","author":"Wang","year":"2016","journal-title":"RSC Adv."},{"key":"ref_7","doi-asserted-by":"crossref","first-page":"607","DOI":"10.1016\/S0016-2361(02)00324-1","article-title":"Science and technology of novel processes for deep desulfurization of oil refinery streams: A review","volume":"82","author":"Babich","year":"2003","journal-title":"Fuel"},{"key":"ref_8","doi-asserted-by":"crossref","first-page":"337","DOI":"10.1515\/revce-2014-0001","article-title":"Deep oxidative desulfurization of liquid fuels","volume":"30","author":"Mjalli","year":"2014","journal-title":"Rev. Chem. Eng."},{"key":"ref_9","doi-asserted-by":"crossref","first-page":"4775","DOI":"10.1002\/chem.201102754","article-title":"Highly Efficient Extraction and Oxidative Desulfurization System Using Na7H2LaW10O36\u22c532\u2009H2O in [bmim]BF4 at Room Temperature","volume":"18","author":"Xu","year":"2012","journal-title":"Chem. A Eur. J."},{"key":"ref_10","doi-asserted-by":"crossref","first-page":"243","DOI":"10.1016\/j.cej.2016.11.137","article-title":"Synthesis and characterization of new nanocomposite CTAB-PTA@CS as an efficient heterogeneous catalyst for oxidative desulphurization of gasoline","volume":"312","author":"Rezvani","year":"2017","journal-title":"Chem. Eng. J."},{"key":"ref_11","doi-asserted-by":"crossref","first-page":"709","DOI":"10.1002\/chem.201202595","article-title":"Deep Desulfurization by Amphiphilic Lanthanide-Containing Polyoxometalates in Ionic-Liquid Emulsion Systems under Mild Conditions","volume":"19","author":"Xu","year":"2013","journal-title":"Chem. A Eur. J."},{"key":"ref_12","doi-asserted-by":"crossref","first-page":"1386","DOI":"10.1016\/j.fuproc.2010.05.010","article-title":"Liquid\u2013liquid extraction of oxidized sulfur-containing compounds of non-hydrotreated kerosene","volume":"91","author":"Sobati","year":"2010","journal-title":"Fuel Process. Technol."},{"key":"ref_13","doi-asserted-by":"crossref","first-page":"84","DOI":"10.1016\/j.jtice.2016.01.014","article-title":"Oxidative desulfurization of fuel oils using ionic liquids: A review","volume":"62","author":"Bhutto","year":"2016","journal-title":"J. Taiwan Inst. Chem. Eng."},{"key":"ref_14","doi-asserted-by":"crossref","first-page":"1419","DOI":"10.1021\/acs.est.0c05855","article-title":"Metal-Based Ionic Liquids in Oxidative Desulfurization: A Critical Review","volume":"55","author":"Liu","year":"2021","journal-title":"Environ. Sci. Technol."},{"key":"ref_15","doi-asserted-by":"crossref","first-page":"775","DOI":"10.1134\/S0023158420050018","article-title":"Heterogeneous Catalysts SILP with Phosphotungstic Acid for Oxidative Desulfurization: Effect of Ionic Liquid","volume":"61","author":"Bryzhin","year":"2020","journal-title":"Kinet. Catal."},{"key":"ref_16","doi-asserted-by":"crossref","first-page":"1989","DOI":"10.1007\/s11696-021-02038-3","article-title":"Effectiveness of ionic liquids in extractive-oxidative desulfurization of liquid fuels: A review","volume":"76","author":"Desai","year":"2022","journal-title":"Chem. Pap."},{"key":"ref_17","doi-asserted-by":"crossref","first-page":"762","DOI":"10.1016\/j.poly.2019.06.019","article-title":"Polyoxomolybdate based ionic-liquids as active catalysts for oxidative desulfurization of simulated diesel","volume":"170","author":"Mirante","year":"2019","journal-title":"Polyhedron"},{"key":"ref_18","doi-asserted-by":"crossref","first-page":"113059","DOI":"10.1016\/j.molliq.2020.113059","article-title":"Synthesis of carbon nitride supported amphiphilic phosphotungstic acid based ionic liquid for deep oxidative desulfurization of fuels","volume":"308","author":"Yu","year":"2020","journal-title":"J. Mol. Liq."},{"key":"ref_19","doi-asserted-by":"crossref","first-page":"118936","DOI":"10.1016\/j.apcatb.2020.118936","article-title":"Tuning the electrophilicity of vanadium-substituted polyoxometalate based ionic liquids for high-efficiency aerobic oxidative desulfurization","volume":"271","author":"Zhang","year":"2020","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_20","doi-asserted-by":"crossref","first-page":"10347","DOI":"10.1021\/acs.energyfuels.1c00862","article-title":"Oxidative Desulfurization of Liquid Fuels Using Polyoxometalate-Based Catalysts: A Review","volume":"35","author":"Ahmadian","year":"2021","journal-title":"Energy Fuels"},{"key":"ref_21","doi-asserted-by":"crossref","first-page":"98","DOI":"10.1021\/acs.energyfuels.1c03396","article-title":"Key Factors Affecting the Development of Oxidative Desulfurization of Liquid Fuels: A Critical Review","volume":"36","author":"Boshagh","year":"2022","journal-title":"Energy Fuels"},{"key":"ref_22","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1016\/j.jiec.2019.10.020","article-title":"Review on oxidative desulfurization of fuel by supported heteropolyacid catalysts","volume":"82","author":"Li","year":"2020","journal-title":"J. Ind. Eng. Chem."},{"key":"ref_23","doi-asserted-by":"crossref","first-page":"2246","DOI":"10.1039\/C9TA12555H","article-title":"A comprehensive review on oxidative desulfurization catalysts targeting clean energy and environment","volume":"8","author":"Rajendran","year":"2020","journal-title":"J. Mater. Chem. A"},{"key":"ref_24","doi-asserted-by":"crossref","first-page":"831","DOI":"10.1515\/revce-2018-0058","article-title":"Polyoxometalate as an effective catalyst for the oxidative desulfurization of liquid fuels: A critical review","volume":"36","author":"Taghizadeh","year":"2020","journal-title":"Rev. Chem. Eng."},{"key":"ref_25","doi-asserted-by":"crossref","first-page":"111515","DOI":"10.1016\/j.mcat.2021.111515","article-title":"A simple desulfurization process to achieve high efficiency, sustainability and cost-effectivity via peroxotungstate catalyst","volume":"505","author":"Gao","year":"2021","journal-title":"Mol. Catal."},{"key":"ref_26","doi-asserted-by":"crossref","first-page":"113093","DOI":"10.1016\/j.molliq.2020.113093","article-title":"Desulfurization of diesel by extraction coupled with Mo-catalyzed sulfoxidation in polyethylene glycol-based deep eutectic solvents","volume":"309","author":"Juliao","year":"2020","journal-title":"J. Mol. Liq."},{"key":"ref_27","doi-asserted-by":"crossref","first-page":"177","DOI":"10.1016\/j.apcatb.2018.02.036","article-title":"Desulfurization of liquid fuels by extraction and sulfoxidation using H2O2 and CpMo(CO)(3)R as catalysts","volume":"230","author":"Juliao","year":"2018","journal-title":"Appl. Catal. B-Environ."},{"key":"ref_28","doi-asserted-by":"crossref","first-page":"616","DOI":"10.1016\/j.fuel.2018.11.095","article-title":"Deep oxidative desulfurization of diesel fuels using homogeneous and SBA-15-supported peroxophosphotungstate catalysts","volume":"241","author":"Juliao","year":"2019","journal-title":"Fuel"},{"key":"ref_29","doi-asserted-by":"crossref","unstructured":"Mirante, F., Mendes, R.F., Faria, R.G., Cunha-Silva, L., Paz, F.A.A., and Balula, S.S. (2021). Membrane-Supported Layered Coordination Polymer as an Advanced Sustainable Catalyst for Desulfurization. Molecules, 26.","DOI":"10.3390\/molecules26092404"},{"key":"ref_30","doi-asserted-by":"crossref","first-page":"350","DOI":"10.1016\/j.fuproc.2013.07.011","article-title":"Catalytic oxidative desulfurization systems based on Keggin phosphotungstate and metal-organic framework MIL-101","volume":"116","author":"Ribeiro","year":"2013","journal-title":"Fuel Process. Technol."},{"key":"ref_31","doi-asserted-by":"crossref","first-page":"110193","DOI":"10.1016\/j.micromeso.2020.110193","article-title":"Polyoxometalate@Periodic mesoporous organosilicas as active materials for oxidative desulfurization of diesels","volume":"302","author":"Ribeiro","year":"2020","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_32","doi-asserted-by":"crossref","first-page":"268","DOI":"10.1016\/j.fuel.2015.10.095","article-title":"Catalytic oxidative\/extractive desulfurization of model and untreated diesel using hybrid based zinc-substituted polyoxometalates","volume":"166","author":"Ribeiro","year":"2016","journal-title":"Fuel"},{"key":"ref_33","doi-asserted-by":"crossref","unstructured":"Silva, D.F., Viana, A.M., Santos-Vieira, I., Balula, S.S., and Cunha-Silva, L. (2022). Ionic Liquid-Based Polyoxometalate Incorporated at ZIF-8: A Sustainable Catalyst to Combine Desulfurization and Denitrogenation Processes. Molecules, 27.","DOI":"10.3390\/molecules27051711"},{"key":"ref_34","doi-asserted-by":"crossref","first-page":"1","DOI":"10.1080\/00958972.2011.645812","article-title":"Review: The chirality and bionic studies of polyoxometalates: The synthetic strategy and structural chemistry","volume":"65","author":"Chen","year":"2012","journal-title":"J. Coord. Chem."},{"key":"ref_35","doi-asserted-by":"crossref","first-page":"34","DOI":"10.1002\/anie.199100341","article-title":"Polyoxometalate Chemistry: An Old Field with New Dimensions in Several Disciplines","volume":"30","author":"Pope","year":"1991","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_36","doi-asserted-by":"crossref","first-page":"4893","DOI":"10.1021\/cr500390v","article-title":"Recent Advances in Polyoxometalate-Catalyzed Reactions","volume":"115","author":"Wang","year":"2015","journal-title":"Chem. Rev."},{"key":"ref_37","doi-asserted-by":"crossref","first-page":"5088","DOI":"10.1002\/ejic.200900615","article-title":"Lanthanopolyoxometalates as Building Blocks for Multiwavelength Photoluminescent Organic\u2013Inorganic Hybrid Materials","volume":"2009","author":"Granadeiro","year":"2009","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_38","doi-asserted-by":"crossref","first-page":"307","DOI":"10.1016\/j.apcata.2013.06.030","article-title":"An efficient heterogeneous catalyst based on highly dispersed Na(7)H(2)LaW(10)O(36 center dot)32H(2)O nanoparticles on mesoporous silica for deep desulfurization","volume":"466","author":"Chen","year":"2013","journal-title":"Appl. Catal. A-Gen."},{"key":"ref_39","doi-asserted-by":"crossref","first-page":"2404","DOI":"10.1039\/c3cy00287j","article-title":"An efficient oxidative desulfurization process using terbium-polyoxometalate@MIL-101(Cr)","volume":"3","author":"Ribeiro","year":"2013","journal-title":"Catal. Sci. Technol."},{"key":"ref_40","doi-asserted-by":"crossref","first-page":"2027","DOI":"10.1007\/s10562-020-03432-4","article-title":"The Ultra-Deep Desulfurization of Model Oil Using Amphipathic Lindqvist-Type Polyoxometalate-Based TiO2 Nanofibres as Catalysts","volume":"151","author":"Fu","year":"2021","journal-title":"Catal. Lett."},{"key":"ref_41","doi-asserted-by":"crossref","first-page":"2205","DOI":"10.1039\/C8QI00248G","article-title":"One-pot synthesis of polyoxomolybdate anion intercalated layered double hydroxides and their application in ultra-deep desulfurization of fuels under mild conditions","volume":"5","author":"Guo","year":"2018","journal-title":"Inorg. Chem. Front."},{"key":"ref_42","doi-asserted-by":"crossref","first-page":"5748","DOI":"10.1021\/acs.inorgchem.7b00366","article-title":"Controllable Synthesis of Lindqvist Alkoxopolyoxovanadate Clusters as Heterogeneous Catalysts for Sulfoxidation of Sulfides","volume":"56","author":"Li","year":"2017","journal-title":"Inorg. Chem."},{"key":"ref_43","doi-asserted-by":"crossref","unstructured":"Fernandes, S., Mirante, F., Castro, B.d., Granadeiro, C.M., and Balula, S.S. (2022). Lindqvist versus Keggin-Type Polyoxometalates as Catalysts for Effective Desulfurization of Fuels. Catalysts, 12.","DOI":"10.3390\/catal12060581"},{"key":"ref_44","doi-asserted-by":"crossref","first-page":"4615","DOI":"10.1039\/C3CS60404G","article-title":"Recent advances in porous polyoxometalate-based metal-organic framework materials","volume":"43","author":"Du","year":"2014","journal-title":"Chem. Soc. Rev."},{"key":"ref_45","doi-asserted-by":"crossref","first-page":"1865","DOI":"10.1039\/D0QI01407A","article-title":"Polyoxometalate-based metal-organic frameworks for heterogeneous catalysis","volume":"8","author":"Zhang","year":"2021","journal-title":"Inorg. Chem. Front."},{"key":"ref_46","doi-asserted-by":"crossref","first-page":"4721","DOI":"10.1002\/cctc.202000688","article-title":"Metal-Organic Framework-Based Catalysts for Oxidative Desulfurization","volume":"12","author":"Piscopo","year":"2020","journal-title":"Chemcatchem"},{"key":"ref_47","doi-asserted-by":"crossref","first-page":"18030","DOI":"10.1021\/ja109268m","article-title":"Structural Evolution of Zeolitic Imidazolate Framework-8","volume":"132","author":"Venna","year":"2010","journal-title":"J. Am. Chem. Soc."},{"key":"ref_48","doi-asserted-by":"crossref","first-page":"10186","DOI":"10.1073\/pnas.0602439103","article-title":"Exceptional chemical and thermal stability of zeolitic imidazolate frameworks","volume":"103","author":"Park","year":"2006","journal-title":"Proc. Natl. Acad. Sci. USA"},{"key":"ref_49","first-page":"1395","article-title":"Incorporation of Isopolyoxometalate into the Crystal and Membrane of ZIF-8","volume":"39","author":"Liang","year":"2020","journal-title":"Chin. J. Struct. Chem."},{"key":"ref_50","doi-asserted-by":"crossref","first-page":"165","DOI":"10.1039\/D1QI01255J","article-title":"Phosphomolybdic acid encapsulated in ZIF-8-based porous ionic liquids for reactive extraction desulfurization of fuels","volume":"9","author":"Yang","year":"2022","journal-title":"Inorg. Chem. Front."},{"key":"ref_51","doi-asserted-by":"crossref","first-page":"4032","DOI":"10.1039\/D1SE00522G","article-title":"Synergistic combination of the nanoporous system of MOF-808 with a polyoxomolybdate to design an effective catalyst: Simultaneous oxidative desulfurization and denitrogenation processes","volume":"5","author":"Fernandes","year":"2021","journal-title":"Sustain. Energy Fuels"},{"key":"ref_52","doi-asserted-by":"crossref","unstructured":"Granadeiro, C.M., Ferreira, P.M.C., Juliao, D., Ribeiro, L.A., Valenca, R., Ribeiro, J.C., Goncalves, I.S., de Castro, B., Pillinger, M., and Cunha-Silva, L. (2018). Efficient Oxidative Desulfurization Processes Using Polyoxomolybdate Based Catalysts. Energies, 11.","DOI":"10.3390\/en11071696"},{"key":"ref_53","doi-asserted-by":"crossref","first-page":"1515","DOI":"10.1039\/C5CY01110H","article-title":"Influence of a porous MOF support on the catalytic performance of Eu-polyoxometalate based materials: Desulfurization of a model diesel","volume":"6","author":"Granadeiro","year":"2016","journal-title":"Catal. Sci. Technol."},{"key":"ref_54","doi-asserted-by":"crossref","first-page":"78","DOI":"10.1016\/j.fuproc.2014.10.030","article-title":"Desulfurization of model diesel by extraction\/oxidation using a zinc-substituted polyoxometalate as catalyst under homogeneous and heterogeneous (MIL-101 (Cr) encapsulated) conditions","volume":"131","author":"Juliao","year":"2015","journal-title":"Fuel Process. Technol."},{"key":"ref_55","doi-asserted-by":"crossref","first-page":"5114","DOI":"10.1002\/ejic.201600442","article-title":"Zinc-Substituted Polyoxotungstate@amino-MIL-101(Al)\u2014An Efficient Catalyst for the Sustainable Desulfurization of Model and Real Diesels","volume":"2016","author":"Juliao","year":"2016","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_56","doi-asserted-by":"crossref","first-page":"1416","DOI":"10.1039\/c3cy00853c","article-title":"Oxidative catalytic versatility of a trivacant polyoxotungstate incorporated into MIL-101(Cr)","volume":"4","author":"Granadeiro","year":"2014","journal-title":"Catal. Sci. Technol."},{"key":"ref_57","doi-asserted-by":"crossref","first-page":"316","DOI":"10.1016\/j.apcata.2012.12.039","article-title":"Monovacant polyoxometalates incorporated into MIL-101(Cr): Novel heterogeneous catalysts for liquid phase oxidation","volume":"453","author":"Granadeiro","year":"2013","journal-title":"Appl. Catal. A-Gen."},{"key":"ref_58","doi-asserted-by":"crossref","first-page":"35","DOI":"10.1016\/j.cattod.2013.03.042","article-title":"Novel heterogeneous catalysts based on lanthanopolyoxometalates supported on MIL-101(Cr)","volume":"218","author":"Granadeiro","year":"2013","journal-title":"Catal. Today"},{"key":"ref_59","doi-asserted-by":"crossref","unstructured":"Peacock, R.D., and Weakley, T.J.R. (1971). Heteropolytungstate complexes of the lanthanide elements. Part I. Preparation and reactions. J. Chem. Soc. A: Inorg. Phys. Theor., 1836\u20131839.","DOI":"10.1039\/j19710001836"},{"key":"ref_60","doi-asserted-by":"crossref","first-page":"248","DOI":"10.1016\/j.micromeso.2016.07.023","article-title":"A novel red emitting material based on polyoxometalate@periodic mesoporous organosilica","volume":"234","author":"Granadeiro","year":"2016","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_61","doi-asserted-by":"crossref","first-page":"10251","DOI":"10.1039\/C9DT01610D","article-title":"Magnetic Co-based carbon materials derived from core\u2013shell metal\u2013organic frameworks for organic contaminant elimination with peroxymonosulfates","volume":"48","author":"Xia","year":"2019","journal-title":"Dalton Trans."},{"key":"ref_62","doi-asserted-by":"crossref","first-page":"110992","DOI":"10.1016\/j.micromeso.2021.110992","article-title":"An Effective Magnetic Catalyst for Oxidative Desulfurization of Model and Real Fuels: Fe3O4\/ZIF-8\/TiO\u2082","volume":"317","author":"Kargar","year":"2021","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_63","doi-asserted-by":"crossref","first-page":"31471","DOI":"10.1039\/C8RA06414H","article-title":"Synthesis of zeolitic imidazolate framework-8 on polyester fiber for PM2.5","volume":"8","author":"Zhang","year":"2018","journal-title":"Remov. RSC Adv."},{"key":"ref_64","doi-asserted-by":"crossref","first-page":"952","DOI":"10.1039\/C6TA07860E","article-title":"Characterization and properties of Zn\/Co zeolitic imidazolate frameworks vs. ZIF-8 and ZIF-67","volume":"5","author":"Zhou","year":"2017","journal-title":"J. Mater. Chem. A"},{"key":"ref_65","doi-asserted-by":"crossref","first-page":"2779","DOI":"10.1002\/ejic.201400122","article-title":"Directional Self-Assembly of Exfoliated Layered Europium Hydroxide Nanosheets and Na9EuW10O36\u00b732H2O for Application in Desulfurization","volume":"2014","author":"Wang","year":"2014","journal-title":"Eur. J. Inorg. Chem."},{"key":"ref_66","doi-asserted-by":"crossref","first-page":"6322","DOI":"10.1039\/C5TC00421G","article-title":"Moisture-responsive films consisting of luminescent polyoxometalates and agarose","volume":"3","author":"Qiu","year":"2015","journal-title":"J. Mater. Chem. C"},{"key":"ref_67","doi-asserted-by":"crossref","first-page":"3313","DOI":"10.1039\/b919691a","article-title":"Lanthanopolyoxotungstates in silica nanoparticles: Multi-wavelength photoluminescent core\/shell materials","volume":"20","author":"Granadeiro","year":"2010","journal-title":"J. Mater. Chem."},{"key":"ref_68","doi-asserted-by":"crossref","first-page":"52","DOI":"10.1016\/j.jallcom.2018.05.144","article-title":"Synthesis and photophysical properties of crystalline [EuW10O36]9--based polyoxometalates with lanthanide ions as counter cations","volume":"761","author":"Liu","year":"2018","journal-title":"J. Alloys Compd."},{"key":"ref_69","doi-asserted-by":"crossref","first-page":"9383","DOI":"10.1039\/C7TC01263B","article-title":"A solar ultraviolet sensor based on fluorescent polyoxometalate and viologen","volume":"5","author":"Liu","year":"2017","journal-title":"J. Mater. Chem. C"},{"key":"ref_70","doi-asserted-by":"crossref","first-page":"2713","DOI":"10.1080\/01496395.2019.1655056","article-title":"Study on the performance of Cd2+ sorption using dimethylethylenediamine-modified zinc-based MOF (ZIF-8-mmen): Optimization of the process by RSM technique","volume":"55","author":"Binaeian","year":"2020","journal-title":"Sep. Sci. Technol."},{"key":"ref_71","doi-asserted-by":"crossref","first-page":"5458","DOI":"10.1039\/c2dt30174a","article-title":"Aqueous room temperature synthesis of cobalt and zinc sodalite zeolitic imidizolate frameworks","volume":"41","author":"Gross","year":"2012","journal-title":"Dalton Trans."},{"key":"ref_72","doi-asserted-by":"crossref","first-page":"10447","DOI":"10.1007\/s10570-020-03483-1","article-title":"One-step in-situ growth of zeolitic imidazole frameworks-8 on cotton fabrics for photocatalysis and antimicrobial activity","volume":"27","author":"Ran","year":"2020","journal-title":"Cellulose"},{"key":"ref_73","doi-asserted-by":"crossref","first-page":"82127","DOI":"10.1039\/C5RA15497A","article-title":"Zeolitic imidazolate metal organic framework ZIF-8 with ultra-high adsorption capacity bound tetracycline in aqueous solution","volume":"5","author":"Wu","year":"2015","journal-title":"RSC Adv."},{"key":"ref_74","doi-asserted-by":"crossref","first-page":"18540","DOI":"10.1021\/acs.iecr.9b02340","article-title":"Effective Zinc-Substituted Keggin Composite To Catalyze the Removal of Sulfur from Real Diesels under a Solvent-Free System","volume":"58","author":"Ribeiro","year":"2019","journal-title":"Ind. Eng. Chem. Res."},{"key":"ref_75","doi-asserted-by":"crossref","first-page":"163","DOI":"10.1016\/j.micromeso.2018.07.036","article-title":"Mesoporous nanosilica-supported polyoxomolybdate as catalysts for sustainable desulfurization","volume":"275","author":"Mirante","year":"2019","journal-title":"Microporous Mesoporous Mater."},{"key":"ref_76","doi-asserted-by":"crossref","unstructured":"Mirante, F., Mendes, R.F., Paz, F.A.A., and Balula, S.S. (2020). High Catalytic Efficiency of a Layered Coordination Polymer to Remove Simultaneous Sulfur and Nitrogen Compounds from Fuels. Catalysts, 10.","DOI":"10.3390\/catal10070731"},{"key":"ref_77","doi-asserted-by":"crossref","first-page":"411","DOI":"10.1016\/j.fuproc.2008.11.002","article-title":"Oxidative desulfurization of Gas oil by polyoxometalates catalysts","volume":"90","author":"Trakarnpruk","year":"2009","journal-title":"Fuel Process. Technol."},{"key":"ref_78","doi-asserted-by":"crossref","first-page":"1918","DOI":"10.1002\/anie.201711920","article-title":"A Keggin Polyoxometalate Shows Water Oxidation Activity at Neutral pH: POM@ZIF-8, an Efficient and Robust Electrocatalyst","volume":"57","author":"Mukhopadhyay","year":"2018","journal-title":"Angew. Chem. Int. Ed."},{"key":"ref_79","doi-asserted-by":"crossref","first-page":"364","DOI":"10.1016\/j.poly.2019.05.058","article-title":"Boosting oxidative desulfurization of model fuel by POM-grafting ZIF-8 as a novel and efficient catalyst","volume":"170","author":"Ghahramaninezhad","year":"2019","journal-title":"Polyhedron"},{"key":"ref_80","doi-asserted-by":"crossref","first-page":"14015","DOI":"10.1021\/acs.jpcc.6b01208","article-title":"Kinetics of ZIF-8 Thermal Decomposition in Inert, Oxidizing, and Reducing Environments","volume":"120","author":"James","year":"2016","journal-title":"J. Phys. Chem. C"},{"key":"ref_81","doi-asserted-by":"crossref","first-page":"18","DOI":"10.1038\/s42004-021-00613-z","article-title":"Understanding the ZIF-L to ZIF-8 transformation from fundamentals to fully costed kilogram-scale production","volume":"5","author":"Deacon","year":"2022","journal-title":"Commun. Chem."},{"key":"ref_82","doi-asserted-by":"crossref","first-page":"111487","DOI":"10.1016\/j.micromeso.2021.111487","article-title":"Solventless synthesis of ZIF-L and ZIF-8 with hydraulic press and high temperature","volume":"328","author":"Coronas","year":"2021","journal-title":"Microporous Mesoporous Mater."}],"container-title":["Nanomaterials"],"original-title":[],"language":"en","link":[{"URL":"https:\/\/www.mdpi.com\/2079-4991\/12\/16\/2887\/pdf","content-type":"unspecified","content-version":"vor","intended-application":"similarity-checking"}],"deposited":{"date-parts":[[2025,10,11]],"date-time":"2025-10-11T00:13:44Z","timestamp":1760141624000},"score":1,"resource":{"primary":{"URL":"https:\/\/www.mdpi.com\/2079-4991\/12\/16\/2887"}},"subtitle":[],"short-title":[],"issued":{"date-parts":[[2022,8,22]]},"references-count":82,"journal-issue":{"issue":"16","published-online":{"date-parts":[[2022,8]]}},"alternative-id":["nano12162887"],"URL":"https:\/\/doi.org\/10.3390\/nano12162887","relation":{},"ISSN":["2079-4991"],"issn-type":[{"value":"2079-4991","type":"electronic"}],"subject":[],"published":{"date-parts":[[2022,8,22]]}}}