{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2025,12,13]],"date-time":"2025-12-13T06:51:38Z","timestamp":1765608698505,"version":"build-2065373602"},"reference-count":63,"publisher":"MDPI AG","issue":"7","license":[{"start":{"date-parts":[[2019,7,18]],"date-time":"2019-07-18T00:00:00Z","timestamp":1563408000000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Nanomaterials"],"abstract":"<jats:p>The interaction between gold sub-nanometer clusters composed of ten atoms (Au10) and tetrakis(4-sulfonatophenyl)porphyrin (TPPS) was investigated through various spectroscopic techniques. Under mild acidic conditions, the formation, in aqueous solutions, of nanohybrid assemblies of porphyrin J-aggregates and Au10 cluster nanoparticles was observed. This supramolecular system tends to spontaneously cover glass substrates with a co-deposit of gold nanoclusters and porphyrin nanoaggregates, which exhibit circular dichroism (CD) spectra reflecting the enantiomorphism of histidine used as capping and reducing agent. The morphology of nanohybrid assemblies onto a glass surface was revealed by atomic force microscopy (AFM), and showed the concomitant presence of gold nanoparticles with an average size of 130 nm and porphyrin J-aggregates with lengths spanning from 100 to 1000 nm. Surface-enhanced Raman scattering (SERS) was observed for the nanohybrid assemblies.<\/jats:p>","DOI":"10.3390\/nano9071026","type":"journal-article","created":{"date-parts":[[2019,7,19]],"date-time":"2019-07-19T03:14:41Z","timestamp":1563506081000},"page":"1026","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":20,"title":["Nanohybrid Assemblies of Porphyrin and Au10 Cluster Nanoparticles"],"prefix":"10.3390","volume":"9","author":[{"ORCID":"https:\/\/orcid.org\/0000-0002-1960-0909","authenticated-orcid":false,"given":"Mariachiara","family":"Trapani","sequence":"first","affiliation":[{"name":"CNR-ISMN, Istituto per lo Studio dei Materiali Nanostrutturati c\/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali, University of Messina V. le F. Stagno D\u2019Alcontres, 3198166 Messina, Italy"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-1514-8820","authenticated-orcid":false,"given":"Maria Angela","family":"Castriciano","sequence":"additional","affiliation":[{"name":"CNR-ISMN, Istituto per lo Studio dei Materiali Nanostrutturati c\/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali, University of Messina V. le F. Stagno D\u2019Alcontres, 3198166 Messina, Italy"}]},{"ORCID":"https:\/\/orcid.org\/0000-0001-5370-9329","authenticated-orcid":false,"given":"Andrea","family":"Romeo","sequence":"additional","affiliation":[{"name":"CNR-ISMN, Istituto per lo Studio dei Materiali Nanostrutturati c\/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali, University of Messina V. le F. Stagno D\u2019Alcontres, 3198166 Messina, Italy"},{"name":"Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali and C.I.R.C.M.S.B., University of Messina V. le F. Stagno D\u2019Alcontres, 3198166 Messina, Italy"}]},{"given":"Giovanna","family":"De Luca","sequence":"additional","affiliation":[{"name":"Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali and C.I.R.C.M.S.B., University of Messina V. le F. Stagno D\u2019Alcontres, 3198166 Messina, Italy"}]},{"given":"Nelson","family":"Machado","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica \u201cUgo Schiff\u201d, Universit\u00e0 di Firenze, Via della Lastruccia 3-13, 50019 Sesto Fiorentino (Fi), Italy"}]},{"given":"Barry D.","family":"Howes","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica \u201cUgo Schiff\u201d, Universit\u00e0 di Firenze, Via della Lastruccia 3-13, 50019 Sesto Fiorentino (Fi), Italy"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-3021-8919","authenticated-orcid":false,"given":"Giulietta","family":"Smulevich","sequence":"additional","affiliation":[{"name":"Dipartimento di Chimica \u201cUgo Schiff\u201d, Universit\u00e0 di Firenze, Via della Lastruccia 3-13, 50019 Sesto Fiorentino (Fi), Italy"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-9742-9190","authenticated-orcid":false,"given":"Luigi Mons\u00f9","family":"Scolaro","sequence":"additional","affiliation":[{"name":"CNR-ISMN, Istituto per lo Studio dei Materiali Nanostrutturati c\/o Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali, University of Messina V. le F. Stagno D\u2019Alcontres, 3198166 Messina, Italy"},{"name":"Dipartimento di Scienze Chimiche, Biologiche, Farmaceutiche ed Ambientali and C.I.R.C.M.S.B., University of Messina V. le F. Stagno D\u2019Alcontres, 3198166 Messina, Italy"}]}],"member":"1968","published-online":{"date-parts":[[2019,7,18]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"10346","DOI":"10.1021\/acs.chemrev.5b00703","article-title":"Atomically Precise Colloidal Metal Nanoclusters and Nanoparticles: Fundamentals and Opportunities","volume":"116","author":"Jin","year":"2016","journal-title":"Chem. Rev."},{"key":"ref_2","doi-asserted-by":"crossref","first-page":"1909","DOI":"10.1039\/b713631p","article-title":"The relevance of shape and size of Au55 clusters","volume":"37","author":"Schmid","year":"2008","journal-title":"Chem. Soc. 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