{"status":"ok","message-type":"work","message-version":"1.0.0","message":{"indexed":{"date-parts":[[2026,3,31]],"date-time":"2026-03-31T06:19:42Z","timestamp":1774937982987,"version":"3.50.1"},"reference-count":32,"publisher":"MDPI AG","issue":"6","license":[{"start":{"date-parts":[[2022,3,12]],"date-time":"2022-03-12T00:00:00Z","timestamp":1647043200000},"content-version":"vor","delay-in-days":0,"URL":"https:\/\/creativecommons.org\/licenses\/by\/4.0\/"}],"content-domain":{"domain":[],"crossmark-restriction":false},"short-container-title":["Polymers"],"abstract":"<jats:p>The main by-product generated in the wine industry are the grape canes, derived from the pruning process. In order to increase the valorisation possibilities of this highly polyphenolic lignocellulosic material, this work focuses on its applicability in the materials industry. As a first step, we demonstrate the viability of using grape cane particles as raw material for particleboard production, combined with a melamine formaldehyde urea (MFU) binder. In addition, looking for the application of these particleboards in the food packaging industry, particleboards based on grape canes were also produced using a new bioadhesive, obtained from the grape cane extract and citric acid. The self-condensation reaction of the grape cane extracts, and the curing reaction with citric acid, were studied by FTIR-ATR and ABES showing the feasibility of this new bioadhesive formulation. Looking for a zero-waste process, the effect of the type of raw material (fresh grape cane, solid by-product of the extraction) and of the extract used on the properties of particleboard were also studied. Citric acid was demonstrated to be a good crosslinking agent for grape cane extract. This work shows that it is possible to produce a new lignocellulosic product based only on grape cane particles using a binder based on grape cane extracts and citric acid. The implemented methodology allowed producing particleboards with applicability in the food-packaging industry, minimizing the waste generated in the process.<\/jats:p>","DOI":"10.3390\/polym14061137","type":"journal-article","created":{"date-parts":[[2022,3,13]],"date-time":"2022-03-13T21:44:17Z","timestamp":1647207857000},"page":"1137","update-policy":"https:\/\/doi.org\/10.3390\/mdpi_crossmark_policy","source":"Crossref","is-referenced-by-count":21,"title":["Grape Canes (Vitis vinifera L.) Applications on Packaging and Particleboard Industry: New Bioadhesive Based on Grape Extracts and Citric Acid"],"prefix":"10.3390","volume":"14","author":[{"given":"Jorge","family":"Santos","sequence":"first","affiliation":[{"name":"ARCP\u2014Associa\u00e7\u00e3o Rede de Compet\u00eancia em Pol\u00edmeros, 4200-355 Porto, Portugal"},{"name":"LEPABE\u2014Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, s\/n, 4200-465 Porto, Portugal"}]},{"given":"Jo\u00e3o","family":"Pereira","sequence":"additional","affiliation":[{"name":"ARCP\u2014Associa\u00e7\u00e3o Rede de Compet\u00eancia em Pol\u00edmeros, 4200-355 Porto, Portugal"},{"name":"LEPABE\u2014Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, s\/n, 4200-465 Porto, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-6205-9011","authenticated-orcid":false,"given":"Danilo","family":"Escobar-Avello","sequence":"additional","affiliation":[{"name":"Unidad de Desarrollo Tecnol\u00f3gico, Universidad de Concepci\u00f3n, Coronel 4191996, Chile"},{"name":"Centro Nacional de Excelencia para la Industria de la Madera (CENAMAD), Pontificia Universidad Cat\u00f3lica de Chile, Av. Vicu\u00f1a Mackena 4860, Santiago 7820436, Chile"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4366-9025","authenticated-orcid":false,"given":"Irene","family":"Ferreira","sequence":"additional","affiliation":[{"name":"FWFI\u2014Freshwood Forms Industry, 2430-600 Vieira de Leiria, Portugal"}]},{"given":"Carlos","family":"Vieira","sequence":"additional","affiliation":[{"name":"FWFI\u2014Freshwood Forms Industry, 2430-600 Vieira de Leiria, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0002-4447-4473","authenticated-orcid":false,"given":"Fern\u00e3o D.","family":"Magalh\u00e3es","sequence":"additional","affiliation":[{"name":"LEPABE\u2014Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, s\/n, 4200-465 Porto, Portugal"}]},{"given":"Jorge Manuel","family":"Martins","sequence":"additional","affiliation":[{"name":"LEPABE\u2014Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, s\/n, 4200-465 Porto, Portugal"},{"name":"DEMad\u2014Department of Wood Engineering, Instituto Polit\u00e9cnico de Viseu, Campus Polit\u00e9cnico de Repeses, 3504-510 Viseu, Portugal"}]},{"ORCID":"https:\/\/orcid.org\/0000-0003-4557-7113","authenticated-orcid":false,"given":"Lu\u00edsa H.","family":"Carvalho","sequence":"additional","affiliation":[{"name":"LEPABE\u2014Faculty of Engineering, University of Porto, Rua Dr. Roberto Frias, s\/n, 4200-465 Porto, Portugal"},{"name":"DEMad\u2014Department of Wood Engineering, Instituto Polit\u00e9cnico de Viseu, Campus Polit\u00e9cnico de Repeses, 3504-510 Viseu, Portugal"}]}],"member":"1968","published-online":{"date-parts":[[2022,3,12]]},"reference":[{"key":"ref_1","doi-asserted-by":"crossref","first-page":"730","DOI":"10.1016\/j.indcrop.2017.09.037","article-title":"Effect of post-pruning vine-shoots storage on the evolution of high-value compounds","volume":"109","author":"Salinas","year":"2017","journal-title":"Ind. 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